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  • Article
    Citation - WoS: 6
    Citation - Scopus: 6
    Physical Properties of the Bi1.5zn0.92-2x< Solid Solutions
    (Elsevier Sci Ltd, 2016) Al Garni, S. E.; Qasrawi, A. F.; Mergen, A.
    The Hf doping effect on the structural, compositional, optical, electrical and dielectric properties of the bismuth-zinc-niobium oxide pyrochlore ceramics is explored by means of scanning electron microscopy, energy dispersive X-ray spectroscopy, ultraviolet-visible light spectroscopy in the wavelength range of 200-1100 nm, temperature dependent electrical resistivity measurements in the range of 300-460 K and dielectric spectroscopy in the frequency range of 0.1-1.0 GHz. The optimum solubility limit in the Bi1.5Zn0.92-2xHfxNb1.5O6.92 solid solution is observed for the Hf content of 0.06. Increasing the Hf content from 0.03 to 0.06 decreased the room temperature, lattice constant, strain, dislocation density, optical energy band gap and electrical resistivity. It also increased the crystallite size and the dielectric constant. The energy band gap of the pure BZN (3.30 eV) decreased to 2.21 and reached 2.10 eV as the Hf content increased from 0.03 to 0.06. This behavior of the BZN suggests its suitability for optical applications of the visible region of light like photovoltaic devices. In addition, the remarkable increase in the dielectric constant from 258 to 280 and 456 nominates the Hf doped pyrochlore for passive mode operation devices like microwave capacitors. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
  • Article
    Citation - WoS: 19
    Citation - Scopus: 19
    Effect of Indium Nano-Sandwiching on the Structural and Optical Performance of Znse Films
    (Elsevier Science Bv, 2017) Al Garni, S. E.; Qasrawi, A. F.
    In the current study, we attempted to explore the effects of the Indium nanosandwiching on the mechanical and optical properties of the physically evaporated ZnSe thin films by means of X-ray diffractions and ultraviolet spectrophotometry techniques. While the thickness of each layer of ZnSe was fixed at 1.0 mu m, the thickness of the nanosandwiched Indium thin films was varied in the range of 25- 100 nm. It was observed that the as grown ZnSe films exhibits cubic and hexagonal nature of crystallization as those of the ZnSe powders before the film deposition. The cubic phases weighs similar to 70% of the structure. The analysis of this phases revealed that there is a systematic variation process presented by the decreasing of; the lattice constant, compressing strain, stress, stacking faults and dislocation intensity and increasing grain size resulted from increasing the Indium layer thickness in the range of 50-100 nm. In addition, the nanosandwiching of Indium between two layers of ZnSe is observed to enhance the absorbability of the ZnSe. Particularly, at incident photon energy of 2.38 eV the absorbability of the ZnSe films which are sandwiched with 100 nm Indium is increased by 13.8 times. Moreover, increasing the thickness of the Indium layer shrinks the optical energy band gap. These systematic variations in mechanical and optical properties are assigned to the better recrystallization process that is associated with Indium insertion which in turn allows total internal energy redistribution in the ZnSe films through the enlargement of grains. (C) 2017 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license.
  • Article
    Citation - WoS: 14
    Citation - Scopus: 15
    Investigation of the Physical Properties of the Yb Nanosandwiched Cds Films
    (Elsevier Science Sa, 2018) Abed, Tamara Y.; Qasrawi, A. F.; Al Garni, S. E.
    In this study, the effects of the sandwiching of a 70 nm thick ytterbium film between two layers of CdS on the structural, compositional, optical and electrical properties are investigated. The X-ray diffraction, scanning electron microscopy, energy dispersion X-ray, visible light spectroscopy and impedance spectroscopy techniques are employed to achieve these effects. It was observed that, the nanosandwiching of Yb between two 500 nm thick films of CdS enhances the crystalline nature of the films without altering the lattice parameters. Particularly, the grain size is increased by 25%, the strain, the defect density and the stacking faults are reduced by 31.5%, 43.7% and 25%, respectively. Optically, the Yb nanosandwiching is observed to enhance the visible light absorbability by at least 2.7 times of the whole range and by 8 times at 1.64 eV. The enhancement of the absorbability is associated with shrinking in the band gap and more interband states. In addition, an increase in the real part of the dielectric constant by 54% is observed when Yb was nanosandwiched in the CdS structure. The modeling of the imaginary part allowed exploring the electron-plasmon interaction parameters. A remarkable increase in the drift mobility from 281 to 996 cm2/Vs associated with plasmon frequency enhancement from 0.84 to 1.38 GHz was determined upon Yb nanosandwiching. The effectiveness of this modeling was verified from the impedance spectra in the frequency domain of 0.01-1.80 GHz, which revealed wave trapping property of ideal values of return loss at notch frequency of 1.35 GHz. Furthermore, the electrical resistivity measurements on the studied samples have shown that the presence of Yb reduced the electrical resistivity and shifts the donor level closer to the conduction band of CdS. The studies nominate the nanosandwiched CdS for use in optical and microwave technologies as dual devices. (C) 2017 Elsevier B.V. All rights reserved.
  • Article
    Citation - Scopus: 1
    Structural and Electrical Performance of Moo3 Films Designed as Microwave Resonators
    (inst Materials Physics, 2020) Al Garni, S. E.; Qasrawi, A. F.; Alharbi, S. R.; Department of Electrical & Electronics Engineering
    In this work, the effect of the insertion of lithium slabs of thicknesses of 50 nm between stacked layers of MoO3 is considered. Stacked layers of MoO3 comprising lithium slabs are prepared by the thermal evaporation technique onto Au substrates under vacuum pressure of 10(-5) mbar. The effects of Li slabs are explored by the X-ray diffraction, scanning electron microscopy, current-voltage characteristics and impedance spectroscopy techniques in the frequency domain of 0.01-1.80 GHz. While the presence of Li slabs did not alter the amorphous nature of structure, it forced the growth of rod-like grains of diameters of 100-160 nm and lengths of 1.5 mu m. Electrically, the presence of Li in the samples enhanced the rectifying properties of the devices and force reverse to forward current ratios larger than 60 times. Li slabs also controlled the negative capacitance effect and resonance -antiresonance regions in the Au/MoO3/MoO3/C stacked layers. While the Au/MoO3/MoO3/C devices displayed high conductance and low impedance values in the studied frequency domain, the Au/MoO3/Li/MOO3/C devices exhibited low conductance and high impedance mode in the frequency domain of 0.01-0.59 GHz. It is also found that the presence of Li slabs improved the performance of the devices through driving it to exhibit lower reflection coefficient and high return loss values near 0.80 GHz. The features of the devices nominate them for use as RF-Microwave traps or resonators.
  • Article
    Citation - WoS: 3
    Citation - Scopus: 3
    Optical Analysis of Ge/Mgo and Ge/Bn Thin Layers Designed for Terahertz Applications
    (Elsevier Sci Ltd, 2015) Al Garni, S. E.; Qasrawi, A. F.
    In this work, a 200 nm Ge thin film is used as a substrate to design Ge/MgO and Ge/BN layers. The optical dynamics in these devices are investigated by means of the reflectivity and the transmissivity measurements. Particularly, the details of the dielectric spectra and the values of the energy band gaps (E-g) are investigated. Below 350 THz, the construction of Ge/MgO and Ge/BN interfaces decreased the effective dielectric constant of Ge by 39% and by 76%, respectively. It also increased the quality factor of the Ge optical device from 150 to 1400 and to 940 at 300 THz. All the dispersive optical parameters are also evaluated. In addition, the direct/indirect E-g value of Ge which was determined as 1.15/0.72 eV is observed to shift down by a 0.13/0.42 and by a 023/0.54 eV for the Ge/MgO and Ge/BN devices, respectively. The sharp increase in the dielectric constant with decreasing frequency in the range of 353 273 THz, the dispersive optical parameters and the energy band gap attenuations of the optical structures are promising as they indicate the applicability of the Ge, Ge/MgO and Gel BN layers in terahertz sensing. The latter technology has a wide range of applications like medical and telecommunication devices. (C) 2014 Elsevier Ltd. All rights reserved.
  • Article
    Citation - WoS: 8
    Citation - Scopus: 8
    Design and performance of Yb/ZnS/C Schottky barriers
    (Elsevier Science Bv, 2017) Khusayfan, Najla M.; Al Garni, S. E.; Qasrawi, A. F.
    In this work, ZnS thin films are deposited onto glass and transparent ytterbium substrates under vacuum pressure of 10(-5) mbar. The effects of the Yb substrate on the structural, mechanical, optical, dielectric and electrical performance of the ZnS are explored by means of the energy dispersion X-ray analyzer, X-ray diffraction, UVeVIS spectroscopy, current-voltage characteristics and impedance spectroscopy techniques. The techniques allowed determining the lattice parameters, the grain size, the degree of orientation, the microstrain, the dislocation density, the optical and the excitonic gaps, the energy band offsets and the dielectric resonance and dispersion. The (111) oriented planes of glass/ZnS and Yb/ZnS exhibited 2.06% lattice mismatch between Yb and ZnS and degree of orientation values of 63% and 51.6%, respectively. The interfacing of the ZnS with Yb shrunk the energy band gap of ZnS by 0.50 eV. On the other hand, the electrical analysis on the Yb/ZnS/C Schottky device has revealed a rectification ratio of 3.48 x 10(4) at a biasing voltage of 0.30 V. The barrier height and ideality factor was also determined. Moreover, the impedance spectroscopy analysis have shown that the Yb/ZnS/C device is very attractive for use as varactor devices of wide tunability. The device could also be employed as microwave resonator above 1337 MHz. (C) 2016 Elsevier B. V. All rights reserved.
  • Article
    Citation - WoS: 9
    Citation - Scopus: 8
    Exploring the Optical Dynamics in the Ito/As2< Interfaces
    (Springer, 2019) Al Garni, S. E.; Qasrawi, A. F.
    In this work, the effects of indium tin oxide (ITO) substrates on the structural, compositional, optical dielectric and optical conduction properties of arsenic selenide thin films are investigated. The As2Se3 films which are prepared by the thermal deposition technique under vacuum pressure of 10(-5) mbar exhibit an induced crystallization process, improved stoichiometry, increased optical transmittance in the visible range of light and increased dielectric response in the infrared range of light upon replacement of glass substrates by ITO. The ITO/As2Se3 interfaces exhibit conduction and valence band offset values of 0.46 eV and 0.91 eV, respectively. The experimental optical conductivity spectra are theoretically reproduced with the help of the Drude-Lorentz approach for optical conduction. In accordance with this approach, owing to the improved crystallinity of the arsenic selenide, the deposition of As2Se3 onto ITO substrates increases the drift mobility value from similar to 17.6 cm(2)/Vs to 34.6 cm(2)/Vs. It also reduces the density of free carriers by one order of magnitude. The ITO/As2Se3/C heterojunction devices which are tested as band filters which may operate in the frequency domain of 0.01-3.0 GHz revealed low pass filter characteristics below 0.35 GHz and band pass filter characteristics in the remaining spectral range.
  • Article
    Citation - WoS: 11
    Citation - Scopus: 12
    Effect of Au Nanosandwiching on the Structural, Optical and Dielectric Properties of the as Grown and Annealed Inse Thin Films
    (Elsevier Science Bv, 2017) Omareya, Olfat A.; Qasrawi, A. F.; Al Garni, S. E.
    In the current work, the structural, optical and dielectric properties of the InSe/Au/InSe nanosandwiched structures are investigated by means of X-ray diffraction and UV-visible light spectrophotometry techniques. The insertion of a 20 and 100 nm thick Au metal slabs between two InSe layers did not alter the amorphous nature of the as grown InSe films but decreased the energy band gap and the free carrier density. It also increased; the absorption ratio and the values of dielectric constant by similar to 3 times. The insertion of 100 nm Au layers as a nanosandwich enhanced the drift mobility (31.3 cm(2)/V s) and plasmon frequency (1.53 GHz) of the InSe films. On the other hand, upon annealing, a metal induced crystallization process is observed for the InSe/Au (100 nm)/InSe sandwiches. Particularly, while the samples sandwiched with a layer of 20 nm thickness hardly revealed hexagonal gamma -In2Se3 when annealed at 300 degrees C, those sandwiched with 100 nm Au slab, displayed well crystalline phase of hexagonal gamma -In2Se3 at annealing temperature of 200 degrees C. The further annealing at 300 degrees C, forced the appearing of the orthorhombic In4Se3 phase. Optically, the annealing of the InSe/Au(100 nm)/InSe at 200 degrees C improved the absorption ratio by similar to 9 times and decreased the energy band gap. The nanosandwiching technique of InSe seems to be promising for the engineering of the optical properties of the InSe photovoltaic material.
  • Article
    Citation - WoS: 6
    Citation - Scopus: 6
    Design and characterization of (Al, C)/p-Ge/p-BN/C isotype resonant electronic devices
    (Wiley-v C H verlag Gmbh, 2015) Al Garni, S. E.; Qasrawi, A. F.
    In this work, a Ge/BN isotype electronic device that works as a selective microwave bandstop filter is designed and characterized. The interface is designed using a 50-m thick p-type BN on a 0.2-m thick p-type germanium thin film. The modeling of current-voltage characteristics of the Al/Ge/BN/C channel of the device revealed that the current is dominated by thermionic emission and by the tunneling of charged particles through energy barriers. The evaluation of the conduction parameters reflected a resonant circuit with a peak-to-valley current ratio of (PVCR) of 63 at a peak (V-p) and valley (V-v) voltages of 1.84 and 2.30V, respectively. The ac signal analysis of the Al/Ge/BN/C channel that was carried out in the frequency range of 1.0-3.0GHz displayed a bandstop filter properties with notch frequency (f(n)) of 2.04GHz and quality factor (Q) of 102. The replacement of the Al electrode by C through the C/Ge/BN/C channel caused the disappearance of the PVCR and shifted f(n) and Q to 2.70GHz and 100, respectively. The features of the Ge/BN device are promising as they indicate the applicability of these sensors in communication technology.
  • Article
    Citation - WoS: 4
    Citation - Scopus: 4
    Characterization of Bi2o3< Heterojunctions Designed for Visible Light Communications
    (Iop Publishing Ltd, 2019) Al Garni, S. E.; Qasrawi, A. F.
    In the current work, the structural, morphological and optical properties of the Bi2O3/ZnS heterojunctions as visible light communication (VLC) technology element are explored. Bismuth oxide layers of thicknesses of 200 nm are used as substrate to evaporate ZnS films of thicknesses of 500 nm by the thermal evaporation technique under vacuum pressure of 10(-5) mbar. The heterojunction devices are studied by the x-ray diffraction, scanning electron microscopy, optical spectrophotometry and microwave spectroscopy techniques. The Bi2O3/ZnS heterojunctions are found to form a highly strained structure with extremely large lattice mismatches. By the strained structure and with the valence and conduction band offsets that exhibit values of 1.04 and 0.41 eV, respectively, it was possible to enhance the light absorbability of ZnS by 459 times at 3.10 eV. In addition, the dielectric constant spectra of the device display a linear and nonlinear optical properties below and above 1.94 eV, respectively. Moreover, the optical conductivity parameters including the drift mobility and plasmon frequency and the cutoff frequency spectra of an area of 0.50 cm(2) of Bi2O3/ZnS interfaces have shown the ability of using these heterojunction devices as light signal receivers that attenuate signals at terahertz frequencies in the range of 0.27-1.00 THz. As an additional demonstration, the Bi2O3/ZnS heterojunction devices were subjected to a microwave signal propagation in the frequency domain of 0.01-2.90 GHz. The device performed as band filters at gigahertz frequencies.