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Article Citation - WoS: 5Citation - Scopus: 5Structural and Optical Properties of Thermally Evaporated (gase)0.75-(gas)0.25 Thin Films(Elsevier Gmbh, 2021) Isik, M.; Işık, Mehmet; Emir, C.; Gasanly, N. M.; Işık, Mehmet; Department of Electrical & Electronics Engineering; Department of Electrical & Electronics EngineeringGaSe and GaS binary semiconducting compounds are layered structured and have been an attractive research interest in two-dimensional material research area. The present paper aims at growing (GaSe)0.75 - (GaS)0.25 (or simply GaSe0.75S0.25) thin film and investigating its structural and optical properties. Thin films were prepared by thermal evaporation technique using evaporation source of its single crystal grown by Bridgman method. The structural properties were revealed using x-ray diffraction (XRD), energy dispersive spectroscopy (EDS), scanning electron microscopy (SEM) and atomic force microscopy (AFM) techniques. XRD pattern and EDS analyses indicated that thin films annealed at 300 ?C were successfully deposited and its structural characteristics are well-consistent with its single crystal form. Surface morphology was studied by means of SEM and AFM measurements. Optical properties were investigated by transmission and Raman spectroscopy techniques. Raman spectrum exhibited three peaks around 172, 242 and 342 cm-1. Analyses of transmission spectrum revealed the direct band gap energy as 2.34 eV. The mixed compounds of GaSe0.75S0.25 were prepared for the first time in a thin film form and the results of the present paper would provide valuable information to research area in which layered compounds have been studied in detail.Article Citation - WoS: 1Citation - Scopus: 1Material Characterization of Thermally Evaporated Znsn2te4< Thin Films(Elsevier Gmbh, Urban & Fischer verlag, 2019) Gullu, H. H.Polycrystalline and stoichiometric ZnSn2Te4 (ZST) thin films were deposited on glass substrates by sequential evaporation of elemental powder sources. The deposited films were annealed in nitrogen atmosphere at annealing temperature ranging 100-300 degrees C. Under post-annealing treatments, the composition, structural, surface morphological, optical and electrical characteristics of the films were investigated. Annealing treatments lead to maintain the structural characteristics with the possible change in atomic concentration of the constituent elements in limit of detection and crystallinity of the films increased with increasing annealing temperature. Grainy surface morphology was observed in as-grown and annealed films and densely packed appearance of the surface of the samples indicates uniform deposition of the film over the entire substrate surface. Under the aim of visible light harvesting in the applications of thin film photovoltaics, normal-incidence transmittance measurements were performed and the direct band gap values were found in the range of 1.8-2.1 eV. Temperature dependent conductivity characteristics of the films were investigated under dark condition and the observed conductivity profiles were found in Arrhenius behavior with temperature dominated by the thermionic emission model.Article Citation - WoS: 22Citation - Scopus: 24Synthesis and Temperature-Tuned Band Gap Characteristics of Magnetron Sputtered Znte Thin Films(Elsevier, 2020) Isik, M.; Gullu, H. H.; Parlak, M.; Gasanly, N. M.Zinc telluride (ZnTe) is one of the attractive semiconducting compounds used in various optoelectronic devices. The usage of ZnTe in optoelectronic applications directs researchers to search its optical characteristics in great detail. For this purpose, structural and optical properties of magnetron sputtered ZnTe thin films were studied by means of x-ray diffraction and transmission spectroscopy measurements. Structural analyses indicated that ZnTe thin films having cubic crystalline structure were successfully grown on soda-lime glass substrates. Transmittance spectra in the 400-1000 nm were recorded in between 10 and 300 K temperature region. The analyses of absorption coefficient spectra resulted in band gap energies decreasing from around 2.31 (10 K) to 2.26 eV (300 K). Temperature dependency of gap energy was studied by Varshni and O'Donnell-Chen relations to determine various optical parameters like absolute zero temperature band gap energy, change of gap energy with temperature, phonon energy.Article Citation - WoS: 3Citation - Scopus: 3Fabrication of Cdsexte1-X Thin Films by Sequential Growth Using Double Sources(Elsevier, 2021) Demir, M.; Gullu, H. H.; Terlemezoglu, M.; Parlak, M.CdSexTe(1-x) (CST) ternary thin films were fabricated by stacking thermally evaporated CdSe and electron beam evaporated CdTe layers. The final structure was achieved in a stoichiometric form of approximately Cd:Se:Te = 50:25:25. The post-annealing processes at 300, 400, and 450 degrees C were applied to trigger the compound formation of CST thin films. The X-ray diffraction (XRD) profiles revealed that CdTe and CdSe have major peaks at 23.9 degrees and 25.5 degrees corresponds to (111) direction in cubic zinc-blend structure. Raman modes of CdTe were observed at 140 and 168 cm(-1), while Raman modes of CdSe films were detected at 208 and 417 cm(-1). The post-annealing process was found to be an effective method in order to combine both diffraction peaks and the vibrational modes of CdTe and CdSe, consequently to form CST ternary alloy. Transmission spectroscopy analysis revealed that CST films have direct band gap value of 1.6 eV.Article Citation - WoS: 4Citation - Scopus: 4Physical Characterization of Thermally Evaporated Sn-Sb Thin Films for Solar Cell Applications(Springer Heidelberg, 2023) Bektas, Tunc; Surucu, Ozge; Terlemezoglu, Makbule; Parlak, MehmetThe substitution of Sb in binary SnSe structure may lead to tailoring the physical properties of both SnSe and SbSe, promising absorber layers for thin film solar cells. The resulting Sn-Sb-Se structure could be an outstanding material for photovoltaic applications. In this study, Sn-Sb-Se thin films were deposited by thermal evaporation, and the effect of annealing on the films' structural, optical, and electrical properties were reported. XRD measurement shows that annealing at 300 degrees C yields the best crystalline quality, and structural parameters were calculated using XRD data. SEM and AFM measurements indicate deformation in the film surface after annealing at 400 degrees C. UV-Vis spectroscopy measurement provides a high absorption coefficient which indicates a direct band gap. The band gap and activation energies of the as-grown sample were found as 1.59 eV and 106.1 meV, respectively. The results of SEM, AFM, XRD, Raman, UV-Vis spectroscopy and temperature-dependent photoconductivity measurements were discussed throughout the paper.Article Citation - WoS: 2Citation - Scopus: 3Electrical Characterization of Zninse2 Thin-Film Heterojunction(Springer, 2019) Gullu, H. H.; Parlak, M.ZnInSe2/Cu0.5Ag0.5InSe2 diode structures have been fabricated by thermal evaporation of stacked layers on indium tin oxide-coated glass substrates. Temperature-dependent dark current-voltage measurements were carried out to extract the diode parameters and to determine the dominant conduction mechanisms in the forward- and reverse-bias regions. The heterostructure showed three order of magnitude rectifying behavior with a barrier height of 0.72 eV and ideality factor of 2.16 at room temperature. In the high forward-bias region, the series and shunt resistances were calculated with the help of parasitic resistance relations, yielding room-temperature values of 9.54 x 10(2) Omega cm(2) and 1.23 x 10(3) Omega cm(2), respectively. According to the analysis of the current flow in the forward-bias region, abnormal thermionic emission due to the variation of the ideality factor with temperature and space-charge-limited current processes were determined to be the dominant conduction mechanisms in this heterostructure. In the reverse-bias region, the tunneling mechanism was found to be effective in the leakage current flow with trap density of 10(6) cm(-3). Spectral photocurrent measurements were carried out to investigate the spectral working range of the device structure. The main photocurrent peaks observed in the spectrum corresponded to the band-edge values of the active thin-film layers.Article Citation - WoS: 20Citation - Scopus: 24Temperature Dependence of Band Gaps in Sputtered Snse Thin Films(Pergamon-elsevier Science Ltd, 2019) Delice, S.; Isik, M.; Gullu, H. H.; Terlemezoglu, M.; Surucu, O. Bayrakli; Parlak, M.; Gasanly, N. M.Temperature-dependent transmission experiments were performed for tin selenide (SnSe) thin films deposited by rf magnetron sputtering method in between 10 and 300 K and in the wavelength region of 400-1000 nm. Transmission spectra exhibited sharp decrease near the absorption edge around 900 nm. The transmittance spectra were analyzed using Tauc relation and first derivative spectroscopy techniques to get band gap energy of the SnSe thin films. Both of the applied methods resulted in existence of two band gaps with energies around 1.34 and 1.56 eV. The origin of these band gaps was investigated and it was assigned to the splitting of valence band into two bands due to spin-orbit interaction. Alteration of these band gap values due to varying sample temperature of the thin films were also explored in the study. It was seen that the gap energy values increased almost linearly with decreasing temperature as expected according to theoretical knowledge.Article Citation - WoS: 11Citation - Scopus: 10Optical Conduction in Amorphous Gase Thin Films(Elsevier Gmbh, 2016) Qasrawi, A. F.; Khanfar, Hazem. K.; Kmail, Renal R. N.In this work, the optical conduction mechanism in GaSe thin films was explored by means of dielectric spectral analysis in the 270-1000 THz range of frequency. The GaSe films which are found to be amorphous in nature are observed to follow the Lorentz approach for optical conduction. The modeling of the optical conductivity which takes into account the damped electronic motion resulting from the collision of photogenerated carriers with impurities, phonons and other damping sources allowed determining the optical conduction parameters. Particularly, an average carrier scattering time, a free carrier density, a reduced resonant frequency, a field effect mobility and an electron bounded plasma frequency of 0.142 (fs), 1.7 x 10(19) (cm(-3)), 875.8 (THz), 1.25 (cm(2)/Vs) and 82.8 (THz), respectively, were determined. These parameters are promising as they indicate the applicability of GaSe in the technology of mid-infrared plasmonic nanoantennas. In addition, the dielectric optical signal which displayed a resonance peak at 500 THz seems to be attractive for use in passive modes operating optoelectronic devices like field effect transistors as they exhibit an increasing signal quality factor with decreasing incident light frequency (C) 2016 Elsevier GmbH. All rights reserved.Article Citation - WoS: 9Citation - Scopus: 10Investigation of Structural and Optical Characteristics of Thermally Evaporated Ga2se3< Thin Films(Pergamon-elsevier Science Ltd, 2020) Isik, M.; Gasanly, N. M.Ga2Se3 thin films were prepared by thermal evaporation technique and structural, optical characteristics of the deposited thin films were investigated in the present study. X-ray diffraction pattern of the thin film exhibited one intensive and sharp peak associated with (111) plane of cubic crystalline structure of the compound. Energy dispersive spectroscopic analyses pointed out the atomic compositional ratio of the constituent elements as consistent with chemical formula of Ga2Se3. The optical characteristics of thin film were studied by means of temperature-dependent transmission experiments carried out in between 10 and 300 K. The analyses to get band gap energies at applied temperatures were accomplished using absorption coefficient according to Tauc relation and derivative transmittance spectra. Absorption coefficient analyses end up with band gap energies increasing from 2.60 eV (room temperature) to 2.67 eV (10 K). The derivatives of transmittance spectra were also utilized for purpose and band gap energies were found very closer (max. +/- 0.02 eV deviation) to those of absorption coefficient analyses. Varshni and Fan models were applied to band gap energy vs. temperature plot and various optical parameters of Ga2Se3 thin film were determined.Article Citation - WoS: 5Citation - Scopus: 5Improvement of Electrical Characteristics of Snse/Si Heterostructure by Integration of Si Nanowires(Elsevier, 2021) Coskun, E.; Gullu, H. H.; Emir, C.; Parlak, M.In this study, the effects of the nanowire geometry on Si wafer substrate were investigated for the SnSe/Si-nanowire heterojunction device and the obtained results were compared with the one fabricated on planar Si surface. Nanowires on Si surface were produced by metal-assisted etching method and the SnSe film layer was deposited by thermal evaporation technique. On both Si and glass surfaces, deposited film shows polycrystalline and single SnSe phase. From optical transmission measurements, optical band gap of this film was determined as 1.36 eV in a good agreement with the literature. All SnSe/Si heterostructures were found in a p-n diode behavior and the ideality factor and series resistance values were calculated as 2.40, 547 Omega, and 3.71, 1.57 x 10(3) Omega, for SnSe/Si-nanowire and SnSe/Si heterojunctions, respectively. As a result, an improvement in device characteristics concerning the planar Si structure was found by utilizing Si nanowire structure.
