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  • Article
    Citation - WoS: 1
    Citation - Scopus: 1
    Characterization of Pbmo0.3w0.7< Crystal: a Potential Material for Photocatalysis and Optoelectronic Applications
    (Wiley-v C H verlag Gmbh, 2024) Isik, Mehmet; Gasanly, Nizami Mamed
    PbMo0.3W0.7O4 semiconductor crystal, which contains the balanced ratios of Mo and W, is grown for the first time by Czochralski method. The structural and optical properties of the crystal are investigated in detail in the present study. Structural analysis shows that crystal has tetragonal structure like PbMoO4 and PbWO4 compounds. The optical characteristics are studied by transmission, Raman, FTIR and photoluminescence methods. The bandgap energy is found to be 3.18 eV, and the positions of the conduction and valence bands are determined. The vibrational characteristics are studied by means of Raman and FTIR spectroscopy techniques. Photoluminescence spectrum presents three peaks around 486, 529, and 544 nm which fall into the green emission spectral range. Taking into account the properties of the compound, it is stated that PbMo0.3W0.7O4 (or Pb(MoO4)(0.3)(WO4)(0.7)) has the potential to be used in water splitting applications and optoelectronic devices that emit green light.
  • Article
    Citation - WoS: 9
    Citation - Scopus: 9
    Determination of optical parameters of Ga0.75In0.25Se layered crystals
    (Wiley-v C H verlag Gmbh, 2012) Isik, M.; Gasanly, N. M.
    The optical properties of the Ga0.75In0.25Se crystals have been investigated by means of transmission and reflection measurements in the wavelength range of 380-1100 nm. The analysis of the results performed at room temperature revealed the presence of optical indirect transtions with band gap energy of 1.89 eV. The variation of the band gap energy as a function of temperature was also studied in the temperature range of 10-300 K. The rate of change of band gap energy (? = 6.2 x 10(4) eV/K) and absolute zero value of the band gap (Egi(0) = 2.01 eV) were reported. The wavelength dependence of the refractive index was analyzed using Wemple and DiDomenico, Sellmeier and Cauchy models to find the oscillator energy, dispersion energy, oscillator strength and zero-frequency refractive index values. (C) 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
  • Article
    Citation - WoS: 3
    Citation - Scopus: 3
    Enhancement of Nonlinear Optical and Dielectric Properties of Cu2o Films Sandwiched With Indium Slabs
    (Wiley-v C H verlag Gmbh, 2020) Omar, Ahmad; Qasrawi, Atef F.
    In this work, the effects of the insertion of indium slabs of thickness 100 nm on the performance of stacked layers of Cu2O are reported. Cu2O/In/Cu2O thin films coated onto ultrasonically cleaned glass substrates are structurally, morphologically, optically, and dielectrically studied. The glassy films of Cu2O display larger, well-ordered grains in an amorphous sea of Cu2O upon insertion of indium slabs between layers of Cu2O. Optically, the indium slabs increase the light absorbability in the IR region by 12.5 times, narrow the energy bandgap, and widen the energy band tails region. They also enhance the nonlinearity in the dielectric response and increase the dielectric constant values by 2.5 times. In addition, the optical conductivity parameters are obtained from the fittings of the dielectric spectra. The analyses reveal an enhancement in the drift mobility, plasmon frequency, and free carrier density via stacking of the indium layer between layers of Cu2O. The drift mobility and plasmon frequency values reach 232.4 cm(2) V-1 s(-1) and 3.95 GHz at a reduced hole-plasmon frequency value of 6.0 x 10(14) Hz (2.48 eV). The values are promising as they indicate the applicability of Cu2O/In/Cu2O interfaces in optoelectronics as thin film transistors and electromagnetic wave cavities.