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Article Citation - WoS: 2Citation - Scopus: 2Post Annealing Effects on the Structural and Optical Properties of Moo3 Sandwiched With Indium Slabs(Iop Publishing Ltd, 2019) Qasrawi, A. F.; Qasrawı, Atef Fayez Hasan; Kmail, Haifaa K.; AbuSaa, M.; Khanfar, Hazem K.; Qasrawı, Atef Fayez Hasan; Department of Electrical & Electronics Engineering; Department of Electrical & Electronics EngineeringMolybdenum trioxide thin films are prepared by the thermal evaporation technique under vacuum pressure of 10(-5) mbar through insertion of indium slabs of thickness of 200 nm between layers of MoO3 and annealing the produced films in the air atmosphere at 250 degrees C for one hour. The films are studied by means of x-ray diffraction, scanning electron microscopy, energy dispersive x-ray spectroscopy, and optical spectrophotometry techniques. The structure of the films is found to be composed monoclinic MoO3, tetragonal indium and cubic In2O3. The phase percentage of In2O3 in the films increased to 26.3% upon annealing at 250 degrees C. The annealing process increased the microstrain, the defect density, the oxygen atomic content and lowered the crystallites and grains sizes in the films. Optically, two energy band gaps of values of 3.20 and 1.70 eV were detected for the MoO3/In/MoO3 system. In addition, nonlinear dielectric response associated with wide range of tunability in the dielectric constant value, in the optical conductivity and in the terahertz cutoff frequency was observed in the near IR spectral range. The annealing of the samples improved the nonlinearity in these parameters and make MoO3/In/MoO3 system more appropriates for optoelectronic technology applications as terahertz cavities and frequency convertors.Article Citation - WoS: 4Citation - Scopus: 4Characterization of Bi2o3< Heterojunctions Designed for Visible Light Communications(Iop Publishing Ltd, 2019) Al Garni, S. E.; Qasrawi, A. F.In the current work, the structural, morphological and optical properties of the Bi2O3/ZnS heterojunctions as visible light communication (VLC) technology element are explored. Bismuth oxide layers of thicknesses of 200 nm are used as substrate to evaporate ZnS films of thicknesses of 500 nm by the thermal evaporation technique under vacuum pressure of 10(-5) mbar. The heterojunction devices are studied by the x-ray diffraction, scanning electron microscopy, optical spectrophotometry and microwave spectroscopy techniques. The Bi2O3/ZnS heterojunctions are found to form a highly strained structure with extremely large lattice mismatches. By the strained structure and with the valence and conduction band offsets that exhibit values of 1.04 and 0.41 eV, respectively, it was possible to enhance the light absorbability of ZnS by 459 times at 3.10 eV. In addition, the dielectric constant spectra of the device display a linear and nonlinear optical properties below and above 1.94 eV, respectively. Moreover, the optical conductivity parameters including the drift mobility and plasmon frequency and the cutoff frequency spectra of an area of 0.50 cm(2) of Bi2O3/ZnS interfaces have shown the ability of using these heterojunction devices as light signal receivers that attenuate signals at terahertz frequencies in the range of 0.27-1.00 THz. As an additional demonstration, the Bi2O3/ZnS heterojunction devices were subjected to a microwave signal propagation in the frequency domain of 0.01-2.90 GHz. The device performed as band filters at gigahertz frequencies.
