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Article Citation - WoS: 45Citation - Scopus: 46Novel Hybrid Scaffolds for the Cultivation of Osteoblast Cells(Elsevier, 2011) Sasmazel, Hilal TurkogluIn this study, natural biodegradable polysaccharide, chitosan, and synthetic biodegradable polymer, poly(epsilon-caprolactone) (PCL) were used to prepare 3D, hybrid polymeric tissue scaffolds (PCL/chitosan blend and PCL/chitosan/PCL layer by layer scaffolds) by using the electrospinning technique. The hybrid scaffolds were developed through HA addition to accelerate osteoblast cell growth. Characteristic examinations of the scaffolds were performed by micrometer, SEM, contact angle measurement system, ATR-FTIR, tensile machine and swelling experiments. The thickness of all electrospun scaffolds was determined in the range of 0.010 +/- 0.001-0.012 +/- 0.002 mm. In order to optimize electrospinning processes, suitable bead-free and uniform scaffolds were selected by using SEM images. Blending of PCL with chitosan resulted in better hydrophilicity for the PCL/chitosan scaffolds. The characteristic peaks of PCL and chitosan in the blend and layer by layer nanofibers were observed. The PCL/chitosan/PCL layer by layer structure had higher elastic modulus and tensile strength values than both individual PCL and chitosan structures. The layer by layer scaffolds exhibited the PBS absorption values of 184.2; 197.2% which were higher than those of PCL scaffolds but lower than those of PCL/chitosan blend scaffolds. SaOs-2 osteosarcoma cell culture studies showed that the highest ALP activities belonged to novel PCL/chitosan/PCL layer by layer scaffolds meaning better cell differentiation on the surfaces. (C) 2011 Elsevier B.V. All rights reserved.Article Citation - WoS: 12Citation - Scopus: 13Optical and Structural Characteristics of Electrodeposited Cd1-xznx< Nanostructured Thin Films(Elsevier, 2021) Erturk, K.; Isik, M.; Terlemezoglu, M.; Gasanly, N. M.The structural and optical characteristics of Cd1-xZnxS (CdZnS) thin films grown by the electrodeposition method were investigated in the present paper. The crystalline structure of the grown CdZnS thin film was determined as cubic wurtzite due to observed diffraction peaks associated with (111) and (220) planes. Atomic compositional ratios of the constituent elements were obtained using energy dispersive spectroscopy and doping concentration of the Zn was found as 5% (x similar to 0.05). Scanning electron microscopy image of the studied thin film indicated that grown film is nanostructured. Raman spectra of CdS and CdZnS thin films were measured and it was seen that observed longitudinal optical modes for CdZnS present a blue-shift. Temperature-dependent band gap energy characteristics of the thin films were studied performing transmission experiments in the 10-300 K temperature range. The analyses of the recorded transmittance spectra showed that direct band gap energy of the films decreases from 2.56 eV (10 K) to 2.51 eV (300 K) with the increase of temperature. The band gap energy vs. temperature dependency was studied applying well-known Varshni optical model and various optical parameters of the films were reported according to the results of the applied model.Article Citation - WoS: 6Citation - Scopus: 6Linear and Nonlinear Optical Characteristics of Bi12sio20 Single Crystals(Elsevier, 2022) Isik, M.; Gasanly, N. M.Bi12SiO20 single crystals grown by Czochralski method were optically investigated in detail in the present paper. Transmission and reflection measurements were performed at room temperature in the 400-800 nm spectral range on the (111) plane. Linear and nonlinear optical characteristics of the Bi12SiO20 crystal were determined analyzing the transmission and reflection spectra. The spectral dependencies of absorption coefficient, skin depth, refractive index, optical and electrical conductivities, real and imaginary parts of dielectric function were plotted. Analyses of optical parameters presented the direct band gap and Urbach energies as 2.55 and 0.33 eV, respectively. Static refractive index and dielectric constant, oscillator strength, dispersion and single oscillator energies, nonlinear refractive index, first- and third-order nonlinear susceptibilities were revealed. Structural properties of the Bi12SiO20 crystal were investigated by x-ray diffraction and scanning electron microscopy measurements.Article Citation - WoS: 9Citation - Scopus: 10Space Efficiency in Timber Office Buildings(Elsevier, 2024) Aslantamer, Ozlem Nur; Ilgin, Huseyin EmreTimber offices indicate a growing field, principally thanks to their potential to offer noteworthy ecological and financial gains over their entire life. Like many other building types, space efficiency is a crucial design parameter in timber structures to ensure a project's feasibility. This factor is especially significant in office buildings, where maximizing rental income reflects effective planning. Currently, there is a lack of exhaustive inquiry providing a thorough insight of space efficiency in modern timber office buildings. This study fills this gap in the literature by collecting data from 33 buildings through literature reviews and case study method to investigate space efficiency with the key architectural and structural factors that influence it. The results showed that: (i) central cores stood out as the prevailing core layouts, while peripheral arrangements were noted as alternative preferences. Prismatic shapes emerged as the most favored options; (ii) timber was extensively used as a primary building material, closely followed by combinations of timber and concrete. Load-bearing systems mainly relied on shear walled frames and configurations; (iii) average space utilization across examined cases was 88 %, with variances ranging from 75 % to 95 % among different instances; (iv) average ratio of core area to GFA was 10 %, showing variations between 4 % and 19 % across various scenarios; and (v) there were no substantial variances noted in the effect of different core planning strategies on spatial efficiency. Similar conclusions were drawn regarding building forms and structural materials. Our paper will assist in crafting design principles customized for diverse stakeholders, including architectural designers of timber offices.Article Citation - WoS: 3Citation - Scopus: 3Fabrication of Cdsexte1-X Thin Films by Sequential Growth Using Double Sources(Elsevier, 2021) Demir, M.; Gullu, H. H.; Terlemezoglu, M.; Parlak, M.CdSexTe(1-x) (CST) ternary thin films were fabricated by stacking thermally evaporated CdSe and electron beam evaporated CdTe layers. The final structure was achieved in a stoichiometric form of approximately Cd:Se:Te = 50:25:25. The post-annealing processes at 300, 400, and 450 degrees C were applied to trigger the compound formation of CST thin films. The X-ray diffraction (XRD) profiles revealed that CdTe and CdSe have major peaks at 23.9 degrees and 25.5 degrees corresponds to (111) direction in cubic zinc-blend structure. Raman modes of CdTe were observed at 140 and 168 cm(-1), while Raman modes of CdSe films were detected at 208 and 417 cm(-1). The post-annealing process was found to be an effective method in order to combine both diffraction peaks and the vibrational modes of CdTe and CdSe, consequently to form CST ternary alloy. Transmission spectroscopy analysis revealed that CST films have direct band gap value of 1.6 eV.Article Citation - WoS: 66Citation - Scopus: 76Multivariate Copula Based Dynamic Reliability Modeling With Application To Weighted-k-out-of-n< Systems of Dependent Components(Elsevier, 2014) Eryilmaz, SerkanIn this paper, a multivariate copula based modeling methodology for dynamic reliability modeling of weighted-k-out-of-n systems is applied. The system under consideration is assumed to have n dependent components each having its own weight. It has a performance level of at least k when the total weight of operating components is k or above. Copula based expressions for the survival function and mean time to failure of such a system are obtained. Extensive numerical results are presented for Clayton and Gumbel type copulas. The behavior of survival function and mean time to failure are investigated with respect to the value of Kendall's correlation coefficient. (C) 2014 Elsevier Ltd. All rights reserved.Article Citation - WoS: 142Citation - Scopus: 148Carbon Dispersed Copper-Cobalt Alloy Nanoparticles: a Cost-Effective Heterogeneous Catalyst With Exceptional Performance in the Hydrolytic Dehydrogenation of Ammonia-Borane(Elsevier, 2016) Bulut, Ahmet; Yurderi, Mehmet; Ertas, Ilknur Efecan; Celebi, Metin; Kaya, Murat; Zahmakiran, MehmetHerein, we report the development of a new and cost-effective nanocatalyst for the hydrolytic dehydrogenation of ammonia-borane (NH3BH3), which is considered to be one of the most promising solid hydrogen carriers due to its high gravimetric hydrogen storage capacity (19.6 wt%) and low molecular weight. The new catalyst system consisting of bimetallic copper-cobalt alloy nanoparticles supported on activated carbon was simply and reproducibly prepared by surfactant-free deposition-reduction technique at room temperature. The characterization of this new catalytic material was done by the combination of multi-pronged techniques including ICP-MS, XRD, XPS, BFTEM, HR-TEM, STEM and HAADF-STEM-line analysis. The sum of their results revealed that the formation of copper-cobalt alloy nanoparticles (d(mean) =1.8 nm) on the surface of activated carbon (CuCo/C). These new carbon supported copper-cobalt alloy nanoparticles act as highly active catalyst in the hydrolytic dehydrogenation of ammonia-borane, providing an initial turnover frequency of TOF = 2700 h(-1) at 298 K, which is not only higher than all the non-noble metal catalysts but also higher than the majority of the noble metal based homogeneous and heterogeneous catalysts employed in the same reaction. More importantly, easy recovery and high durability of these supported CuCo nanoparticles make CuCo/C recyclable heterogeneous catalyst for the hydrolytic dehydrogenation of ammonia-borane. They retain almost their inherent activity even at 10th catalytic reuse in the hydrolytic dehydrogenation of ammonia-borane at 298K. (C) 2015 Elsevier B.V. All rights reserved.Article Citation - WoS: 1Citation - Scopus: 2On Bivariate Compound Sums(Elsevier, 2020) Tank, Fatih; Eryilmaz, SerkanThe study of compound sums have always been very popular in the literature. Many models in insurance and engineering have been represented and solved by compound sums. In this paper, two different bivariate compound sums are proposed and studied. The phase-type distribution is applied to obtain the probability generating function of the bivariate sum. (C) 2019 Elsevier B.V. All rights reserved.Article Citation - WoS: 14Citation - Scopus: 14Low Temperature Thermoluminescence Behaviour of Y2o3< Nanoparticles(Elsevier, 2019) Delice, S.; Isik, M.; Gasanly, N. M.Y2O3 nanoparticles were investigated using low temperature thermoluminescence (TL) experiments. TL glow curve recorded at constant heating rate of 0.4 K/s exhibits seven peaks around 19, 62, 91, 115, 162, 196 and 215 K. Activation energies and characteristics of traps responsible for observed curves were revealed under the light of results of initial rise analyses and T-max-T-stop experimental methods. Analyses of TL curves obtained at different stopping temperatures resulted in presence of one quasi-continuously distributed trap with activation energies increasing from 18 to 24 meV and six single trapping centers at 49, 117, 315, 409, 651 and 740 meV. Activation energies of all revealed centers were reported in the present paper. Structural characterization of Y2O3 nanoparticles was accomplished using X-ray diffraction and scanning electron microscopy measurements. (C) 2019 Chinese Society of Rare Earths. Published by Elsevier B.V. All rights reserved.Book Part Citation - Scopus: 3Ion Exchange Membranes in Electrodialysis Process for Wastewater Treatment(Elsevier, 2023) Altıok,E.; Cihanoğlu,A.; Güler,E.; Kabay,N.Water is the most important natural resource on earth. Survival without water is impossible and industries cannot operate without water as well. Availability of safe and reliable source of water is therefore essential. Different practical solutions are needed for sustainable preservation of water resources as freshwater resources are limited in terms of technical and economical aspects. Membrane technologies can be applied to water and wastewater treatment for removal of various unwanted substances from water. Recently, the utilization of membrane technologies in the water purification sector has grown exponentially. Compared to conventional reclamation methods, membrane technologies are much more efficient for removal of various contaminants and they are able to overcome more stringent water regulations. Membrane separation processes employed for water treatment include reverse osmosis, nanofiltration, ultrafiltration, microfiltration, and electrodialysis (ED). In this chapter, we reviewed the basic principles of electromembrane processes, such as ED, electrodeionization, electrodialysis reversal, and bipolar membrane ED based on ion exchange membranes (IEMs) along with few examples of the use of these processes in water and wastewater treatment. In addition, fouling of IEMs is also discussed. © 2024 Elsevier Inc. All rights reserved.
