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Article Citation - WoS: 12Citation - Scopus: 14Numerical Modeling of Visco-Elasto Hygro-Thermal Stresses and the Effects of Operating Conditions on the Mechanical Degradation of Pefc Membranes(Elsevier, 2018) Mehrtash, Mehdi; Tari, Ilker; Yesilyurt, SerhatDurability of membranes is one of the concerns for widespread commercialization of polymer electrolyte fuel cells. Effects of membrane swelling on the durability pose important challenges for the fabrication of the catalyst-coated membrane. This study provides insight into vulnerable locations of the membrane under hygrothermal loading, mechanical loading due to clamping and realistic conditions where a combination of both of these loadings are imposed. With a half rib-channel model, we simulate a polymer electrolyte fuel cell that operates under varying loads and clamping pressure. Model considers anisotropic diffusion in the gas diffusion layer as well as complex interactions of water transport dynamics between gas diffusion layers and the membrane. Mechanical responses of the membrane subject to conjugate hygro-thermo-mechanical loadings during typical scenarios of fuel cell operation reveal the effects of operating parameters as well as individual contributing factors on the development of local stresses in the membrane.Article Citation - WoS: 22Citation - Scopus: 24Synthesis and Temperature-Tuned Band Gap Characteristics of Magnetron Sputtered Znte Thin Films(Elsevier, 2020) Isik, M.; Gullu, H. H.; Parlak, M.; Gasanly, N. M.Zinc telluride (ZnTe) is one of the attractive semiconducting compounds used in various optoelectronic devices. The usage of ZnTe in optoelectronic applications directs researchers to search its optical characteristics in great detail. For this purpose, structural and optical properties of magnetron sputtered ZnTe thin films were studied by means of x-ray diffraction and transmission spectroscopy measurements. Structural analyses indicated that ZnTe thin films having cubic crystalline structure were successfully grown on soda-lime glass substrates. Transmittance spectra in the 400-1000 nm were recorded in between 10 and 300 K temperature region. The analyses of absorption coefficient spectra resulted in band gap energies decreasing from around 2.31 (10 K) to 2.26 eV (300 K). Temperature dependency of gap energy was studied by Varshni and O'Donnell-Chen relations to determine various optical parameters like absolute zero temperature band gap energy, change of gap energy with temperature, phonon energy.Article Citation - WoS: 4Citation - Scopus: 5Forecasting Turkish Local Elections(Elsevier, 2012) Toros, EmreThe literature on political forecasting is large, although the main focus of this literature is limited to a number of countries. Nevertheless, and despite the major differences between political systems, scientific forecasting work has proved to be broadly possible, with noteworthy extensions to new countries. This article extends the literature further by developing a new forecasting model for local elections in Turkey. The basic motivation of this article is to test the usefulness of political forecasting in the contexts of alternative democratic settings. Turkey, in that sense, seems to be an interesting case for a number of reasons. First, the Turkish Republic has been a multi-party democracy since the mid-1940s. Although it has been interrupted by three military coups, the party and election system in Turkey has brought real alternations in the government starting from very early years of the multi-party system. So, it is plausible to argue that Turkish voters have the tradition of evaluating the performances of political parties, as in any other Western-type democracy. That is to say, the dynamics of evaluations of political parties in Turkey follow a similar pattern to other contemporary democracies, being driven by economic and political forces. The main contribution of this analysis is the introduction of an explicit model, which can forecast the impact of economic and political variables across local elections in Turkey by using reliable, public, and macro-level data. In particular, this study offers a new forecasting model which tries to forecast the Justice and Development Party's (Adalet ve Kalkinma Partisi, AKP) vote share in 81 cities. (C) 2012 International Institute of Forecasters. Published by Elsevier B.V. All rights reserved.Article Citation - WoS: 113Citation - Scopus: 147Experiments and Finite Element Simulations on Micro-Milling of Ti-6al Alloy With Uncoated and Cbn Coated Micro-Tools(Elsevier, 2011) Oezel, T.; Thepsonthi, T.; Ulutan, D.; Kaftanoglu, B.This paper presents experimental investigations and finite element simulations on micro-milling of Ti-6Al-4V alloy with fine grain uncoated and cBN coated micro-end mills. Micro-milling of Ti-6Al-4V using uncoated and cBN coated tungsten carbide micro-end mills are conducted; surface roughness, burr formation and tool wear are measured. Effects of machining parameters on surface roughness, burr formation, and tool wear for uncoated and cBN coated micro-tools are investigated. Finite element modelling is utilized to predict forces, temperatures, and wear rate for uncoated and cBN coated micro-tools. Predicted temperature and tool wear contours for uncoated and cBN coated micro-tool edges reveal advantages of cBN coatings. Optimization studies on the experimental results are also conducted to identify the optimum process parameters which minimize both surface roughness and burr formation concurrently. (C) 2011 CIRP.Article Citation - WoS: 20Citation - Scopus: 23A Novel Comfort Temperature Determination Model Based on Psychology of the Participants for Educational Buildings in a Temperate Climate Zone(Elsevier, 2023) Ozbey, Mehmet Furkan; Turhan, CihanMaintaining thermal comfort in the educational buildings is vital due to the impacts on learning effectiveness of students. Therefore, development of a proper comfort temperature in educational buildings is a must. In naturally ventilated and mixed-mode buildings, the adaptive thermal comfort model, which considers additively psychological, and behavioural factors to the Fanger's PMV/PPD model, is commonly applied based on regression analyses. However, the psychological adjustments based on current mood state are very limited in these adaptive thermal comfort models. Therefore, this study focuses on the psychological adjustments in terms of Profile of Mood States in order to predict comfort temperature of students in a case building. The experiments are conducted in a university on a temperate climate zone for a long period-data including both heating and cooling seasons. In this study, the comfort temperatures for each student are determined via Griffith method for the case building. Moreover, the current mood states of students are assessed utilizing the Profile of Mood States survey, which are collected via a developed mobile application. As a conclusion, the relation between the current mood state of the students and comfort temperature are statistically investigated. The results show that a Griffith constant are found as 0.332/K and mean annual comfort temperature is found as 21.32 degrees C in the case building. Additionally, a significant difference is found in the comfort temperatures among the students who have more, or fewer concerns than typically reported. The novelty of the study is to present a comfort temperature determination model which considers human psychology as a starter study in the literature.Article Citation - WoS: 30Citation - Scopus: 30New approach to stability of 2-D discrete systems with state saturation(Elsevier, 2012) Singh, VimalA new criterion for the global asymptotic stability of 2-D discrete systems described by the Roesser model using saturation arithmetic is presented. The criterion is a generalization over an earlier criterion due to Liu and Michel. The generalized criterion has the feature that Lyapunov matrix P is not restricted to be symmetric, i.e., P can be even unsymmetric. A modified form of the criterion is also presented. Two examples showing the effectiveness of the generalized approach to yield new 2-D stability results are provided. To the best of author's knowledge, the use of unsymmetric P to obtain new 2-D stability conditions (i.e., conditions which are outside the scope of symmetric P) is demonstrated, for first time, in this paper. (C) 2011 Elsevier B.V. All rights reserved.Article Citation - WoS: 23Citation - Scopus: 22Wavelength Dependence of the Nonlinear Absorption Performance and Optical Limiting in Bi12tio20 Single Crystal(Elsevier, 2023) Pepe, Yasemin; Isik, Mehmet; Karatay, Ahmet; Gasanly, Nizami; Elmali, AyhanIn this study, the influence of excitation wavelength and input intensity on the nonlinear absorption (NA) mechanism and optical limiting behavior of the Bi12TiO20 (BTO) single crystal were reported. The energy band gap of the BTO single crystal was obtained to be 2.38 eV. Urbach energy revealed that the single crystal has a highly defective structure. Open aperture (OA) Z-scan experiments were conducted at 532 and 1064 nm exci-tation wavelengths at various input intensities. Obtained experimental data were analyzed with a theoretical model considering one photon, two-photon and free carrier absorption contributions to NA. The obtained results revealed that the BTO single crystal possesses NA. The NA coefficient increased with increasing input intensity at 532 nm excitation wavelength, while it decreased with increasing input intensity at 1064 nm excitation wave-length. Due to the intense localized defect states distribution at the energy of 532 nm excitation wavelength within the band gap, increasing contribution to NA came from one photon absorption (OPA), sequential two -photon absorption (TPA) and free carrier absorption (FCA) with increasing input intensity. The filling of the defect states at 1064 excitation wavelength caused a reduction in NA due to increasing saturable absorption with increasing input intensity. TPA coefficients were also found from the fitting ignoring the defect states. As ex-pected, the values of the nonlinear absorption coefficient beta eff are higher than that of the TPA coefficients for both excitation wavelengths. The optical limiting threshold of the BTO single crystal was obtained to be 6.62 mJ/cm2. The results of the present works indicated that BTO single crystal can be used as a potential optical limiter.Article Citation - WoS: 136Citation - Scopus: 148Palladium(0) Nanoparticles Supported on Silica-Coated Cobalt Ferrite: a Highly Active, Magnetically Isolable and Reusable Catalyst for Hydrolytic Dehydrogenation of Ammonia Borane(Elsevier, 2014) Akbayrak, Serdar; Kaya, Murat; Volkan, Murvet; Ozkar, SaimPalladium(0) nanoparticles supported on silica-coated cobalt ferrite (Pd(0)/SiO2-CoFe2O4) were in situ generated during the hydrolysis of ammonia borane, isolated from the reaction solution by using a permanent magnet and characterized by ICP-OES, XRD, TEM, TEM-EDX, XPS and the N-2 adsorption-desorption techniques. All the results reveal that well dispersed palladium(0) nanoparticles were successfully supported on silica coated cobalt ferrite and the resulting Pd(0)/SiO2-CoFe2O4 are highly active, magnetically isolable, and recyclable catalysts in hydrogen generation from the hydrolysis of ammonia borane with an unprecedented turnover frequency (TOF, calculated on the basis of the total amount of Pd) of 254 mol H-2 (mol Pd min)(-1) at 25 +/- 0.1 degrees C. The reusability tests reveal that Pd(0)/SiO2-CoFe2O4 are still active in the subsequent runs of hydrolysis of ammonia borane providing 100% conversion. Pd(0)/SiO2-CoFe2O4 provide the highest catalytic activity with a TOF value of 198 mol H-2 (mol Pd min)(-1) in the 10th use in hydrogen generation from the hydrolysis of ammonia borane as compared to the other palladium catalysts. The work reported here also includes the kinetic studies depending on the temperature to determine the activation energy of the reaction (E-a = 52 +/- 2 kJ/mol) and the effect of catalyst concentration on the rate of hydrolytic dehydrogenation of ammonia borane, respectively. (C) 2013 Elsevier B.V. All rights reserved.Article Citation - WoS: 27Citation - Scopus: 30Effects of Au Nanoslabs on the Performance of Cdo Thin Films Designed for Optoelectronic Applications(Elsevier, 2021) Alharbi, Seham Reef; Qasrawi, A. F.In this work, the effect of 50 nm thick gold nanosheets on the structural, morphological, optical and electrical properties of stacked layers of CdO are investigated. The insertion of Au nanoslabs decreased the lattice parameters of the cubic unit cells of CdO. It also decreased the microstrain, the defect density, the stacking fault percentage and increased the crystallite and grain sizes. Optically, the light absorbability is enhanced, the energy band gap is shrunk and the optical conductivity is increased. The optical conductivity parameters presented by scattering time, plasmon frequency, drift mobility and free carrier density are all engineered via participation of Au nanosheets. On the other hand, electrical measurements in the frequency domain of 0.01-1.80 GHz indicated that the Au nanosheets forced the capacitance spectra to exhibit negative values and increased the electrical conductivity in the studied frequency domain. The terahertz cutoff frequency is tuned in the range of 5.0-22.0 THz indicating the applicability of the CdO/Au/CdO (CAC) films as terahertz filters. The direct current electrical conductivity measurements have shown that while the CC samples exhibit nondegenerate extrinsic nature of conduction, the CAC samples displayed degenerate/nondegenerate transitions at 400 K. With the feature of negative capacitance that can be used for noise reduction and parasitic capacitance cancellation, the CAC films can be regarded as promising structure for multifunctional device applications.Book Part Citation - Scopus: 3Ion Exchange Membranes in Electrodialysis Process for Wastewater Treatment(Elsevier, 2023) Altıok,E.; Cihanoğlu,A.; Güler,E.; Kabay,N.Water is the most important natural resource on earth. Survival without water is impossible and industries cannot operate without water as well. Availability of safe and reliable source of water is therefore essential. Different practical solutions are needed for sustainable preservation of water resources as freshwater resources are limited in terms of technical and economical aspects. Membrane technologies can be applied to water and wastewater treatment for removal of various unwanted substances from water. Recently, the utilization of membrane technologies in the water purification sector has grown exponentially. Compared to conventional reclamation methods, membrane technologies are much more efficient for removal of various contaminants and they are able to overcome more stringent water regulations. Membrane separation processes employed for water treatment include reverse osmosis, nanofiltration, ultrafiltration, microfiltration, and electrodialysis (ED). In this chapter, we reviewed the basic principles of electromembrane processes, such as ED, electrodeionization, electrodialysis reversal, and bipolar membrane ED based on ion exchange membranes (IEMs) along with few examples of the use of these processes in water and wastewater treatment. In addition, fouling of IEMs is also discussed. © 2024 Elsevier Inc. All rights reserved.
