Browsing by Author "Colpan, C. Ozgur"
Now showing 1 - 12 of 12
- Results Per Page
- Sort Options
Conference Object Citation Count: 31Development of a one-dimensional and semi-empirical model for a high temperature proton exchange membrane fuel cell(Pergamon-elsevier Science Ltd, 2018) Devrim, Yılser; Colpan, C. Ozgur; Devrim, Yilser; Energy Systems EngineeringHigh temperature proton exchange membrane fuel cells (HT-PEMFC), which operate between 160 degrees C and 200 degrees C, can be generally used in portable and stationary power generation applications. In this study, a one-dimensional, semi-empirical, and steady-state model of a HT-PEMFC fed with a gas mixture consisting of hydrogen and carbon monoxide is developed. Some modeling parameters are adjusted using empirical data, which are obtained conducting experiments on a HT-PEMFC for different values of Pt loading and cell temperature. For adjusting these parameters, the total summation of the square of the difference between the cell voltages found using the experimental and theoretical methods is minimized using genetic algorithm. After finding the values of the adjusted parameters, the effects of different cell temperature, Pt loading, phosphoric acid (PA) percentage, and different binders (PBI and PVDF) on the performance of the fuel cell are examined. It was found that, the performance of the fuel cell using PVDF binder exhibited better performance as compared to that using PBI binder. (c) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Conference Object Citation Count: 47Energy and exergy performance assessments of a high temperature-proton exchange membrane fuel cell based integrated cogeneration system(Pergamon-elsevier Science Ltd, 2020) Devrim, Yılser; Colpan, C. Ozgur; Devrim, Yilser; Energy Systems EngineeringHigh-temperature proton exchange membrane fuel cell (HT-PEMFC), which operates between 160 degrees C and 200 degrees C, is considered to be a promising technology, especially for cogeneration applications. In this study, a mathematical model of a natural gas fed integrated energy system based on HT-PEMFC is first developed using the principles of electrochemistry and thermodynamics (including energy and exergy analyses). The effects of some key operating parameters (e.g., steam-to-carbon ratio, HT-PEMFC operating temperature, and anode stoichiometric ratio) on the system performance (electrical, cogeneration, and exergetic efficiencies) are examined. The exergy destruction rates of each component in the integrated system are found for different values of these parameters. The results show that the most influential parameter which affects the performance of the integrated system is the anode stoichiometric ratio. For the baseline conditions, when the anode stoichiometric ratio increases from 1.2 to 2, the electrical, cogeneration, and exergetic efficiencies decrease by 42.04%, 33.15%, and 37.39%, respectively. The highest electrical power output of the system is obtained when the SCR, operating temperature, and anode stoichiometric ratio are taken as 2, 160 degrees C, and 1.2, respectively. For this case, the electrical, cogeneration, and exergetic efficiencies are found as 26.20%, 70.34%, and 26.74%, respectively. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Conference Object Citation Count: 25Enhancement of direct methanol fuel cell performance through the inclusion of zirconium phosphate(Pergamon-elsevier Science Ltd, 2017) Devrim, Yılser; Ercelik, Mustafa; Ozdemir, Yagmur; Devrim, Yilser; Colpan, C. Ozgur; Energy Systems EngineeringNafion/zirconium hydrogen phosphate (ZrP) composite membranes containing 2.5 wt.% ZrP (NZ-2.5) or 5 wt.% ZrP (NZ-5) were prepared to improve the performance of a direct methanol fuel cell (DMFC). The influence of ZrP content on the Nafion matrix is assessed through characterization techniques, such as Thermogravimetric Analysis (TGA), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Electrochemical Impedance Spectroscopy (EIS), and water uptake measurement. Performance testings of the DMFCs based on these composite membranes as well as commercial Nafion (R) 115 membrane were performed using a computer aided fuel cell test station for different values of cell temperature (40 degrees C, 60 degrees C, 80 degrees C, and 100 degrees C) and methanol concentration (0.75 M, 1.00 M, and 1.50 M). Characterization studies indicated that incorporation of ZrP into polymer matrix enhanced the water uptake and proton conductivity values of Nafion membrane. The results of the performance tests showed that the Membrane Electrode Assembly (MEA) having NZ-2.5 provided the highest performance with the peak power density of 551.52 W/m(2) at 100 degrees C and 1.00 M. Then, the performances of the MEAs having the same NZ-2.5 membrane but different cathode catalysts were investigated by fabricating two different MEAs using cathode catalysts made of Pt/C-ZrP and Pt/C (HiSPEC (R) 9100). According to the results of these experiments, the MEA having NZ-2.5 membrane and Pt/C (HiSPEC (R) 9100) cathode catalyst containing 10 wt.% of ZrP exhibited the highest performance with the peak power density of 620.88 W/m(2) at 100 degrees C and 1.00 M. In addition, short-term stability tests were conducted for all the MEAs. The results of the stability tests revealed that introduction of ZrP to commercial (HiSPEC (R) 9100) cathode catalyst improves its stability characteristics. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Article Citation Count: 56Evaluation of sulfonated polysulfone/zirconium hydrogen phosphate composite membranes for direct methanol fuel cells(Pergamon-elsevier Science Ltd, 2017) Devrim, Yılser; Ercelik, Mustafa; Devrim, Yilser; Colpan, C. Ozgur; Hamdullahpur, Feridun; Energy Systems EngineeringDirect methanol fuel cell (DMFC) technology has advanced perceivably, but technical challenges remain that must be overcome for further performance improvements. Thus, in this study, sulfonated polysulfone/zirconium hydrogen phosphate (SPSf/ZrP) composite membranes with various sulfonation degrees (20%, 35%, and 42%) and a constant concentration of ZrP (2.5%) were prepared to mitigate the technical challenges associated with the use of conventional Nafion (R) membranes in DMFCs. The composite membranes were investigated through Scanning Electron Microscopy (SEM), Electrochemical Impedance Spectroscopy (EIS), Thermogravimetric Analysis (TGA), oxidative stability and water uptake measurements, and single cell testing. Comparison was also made with Nafion (R) 115. Single cell tests were performed under various methanol concentrations and cell temperatures. Stability characteristics of the DMFCs under charging and discharging conditions were investigated via 1200 min short-term stability tests. The response characteristics of the DMFCs under dynamic conditions were determined at the start-up and shut-down stages. Composite membranes with sulfonation degrees of 35% and 42% were found to be highly promising due to their advanced characteristics with respect to proton conductivity, water uptake, thermal resistance, oxidative stability, and methanol suppression. For the whole range of parameters studied, the maximum power density obtained for SPSf/ZrP-42 (119 mW cm (2)) was found to be 13% higher than that obtained for Nafion (R) 115 (105 mW cm (2)). (C) 2017 Elsevier Ltd. All rights reserved.Article Citation Count: 2Experimental and modeling studies of a high-temperature electrochemical hydrogen compressor(Pergamon-elsevier Science Ltd, 2024) Durmuş, Gizem Nur Bulanık; Kuzu, Cemil; Devrim, Yılser; Colpan, C. Ozgur; Mechanical Engineering; Energy Systems EngineeringSome non-technical factors such as economics and logistics prevent hydrogen (H2) tech-nologies from becoming more widespread in daily life. Today, the prevalence of H2 tech-nologies requires new technological developments. Electrochemical hydrogen compressors (ECHC) are of great interest due to their ability to pressurize and purify in one step. In this study, the electrochemical H2 compression performance of high phosphoric acid (PA) doped poly 2,2-m-phenylene-5,5-benzimidazole (PBI) membrane-based HT-ECHC under high temperature and non-humid conditions was investigated through both an experimental and a numerical approach. The H2 compression capacity of HT-ECHC at different operating voltages was examined by performance tests at 160 degrees C, and it was determined that the electrochemical compression performance increased with increasing operating voltage. It was observed that the current density values also increased with increasing voltage, and it was determined that a current density of 61.2 A was obtained at 1 V. As a result of the tests, H2 was successfully compressed from atmospheric pressure to 60 bar by HT-ECHC without any gas leakage. The results of the developed model were compared with the experimental performance test data, and the variation of molar flow, cell voltage, and cell efficiency over time was examined. It has been determined that the back diffusion from the cathode to the anode in the cell increases with the increasing operating voltage of HT-ECHC and therefore the cell efficiency decreases. It has been evaluated that the developed model and experimental results are in good agreement. (c) 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Article Citation Count: 3High-temperature electrochemical hydrogen separation from reformate gases using PBI/MOF composite membrane(Pergamon-elsevier Science Ltd, 2023) Durmuş, Gizem Nur Bulanık; Eren, Enis Oguzhan; Devrim, Yılser; Colpan, C. Ozgur; Ozkan, Necati; Mechanical Engineering; Energy Systems EngineeringIn this paper, the high-temperature electrochemical Hydrogen (H2) purification perfor-mance of a polybenzimidazole/UIO-66 metal-organic framework (PBI/UIO-66) membrane is investigated and analyzed at different values of current, temperature, and reformate feed composition. Purification measurements show that a significant reduction in gas impu-rities can be obtained. In the performance tests, three different ratios of reformate gas (RG) (H2:carbon dioxide (CO2):carbon monoxide (CO)) as RG-1= (75:25:0), RG-2= (75:22:3), and RG-3= (95:0:5) were used. The highest purification values were observed at 160 & DEG;C as 99.999%, 99.931%, and 99.708% for RG-1, RG-2, and RG-3, respectively. The obtained results show that an electrochemical H2 purification (ECHP) based on PBI/UIO-66 composite membrane is promising for H2 purification.& COPY; 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Article Citation Count: 65Investigation of Nafion based composite membranes on the performance of DMFCs(Pergamon-elsevier Science Ltd, 2017) Devrim, Yılser; Ozden, Adnan; Devrim, Yilser; Colpan, C. Ozgur; Energy Systems EngineeringIn this study, Direct Methanol Fuel Cells (DMFCs) based on composite membranes (Nafion/ SiO2 and Nafion/TiO2) were manufactured; and their performances were compared with that of the DMFC based on Nafion (R) 115 membrane. For this purpose, composite membranes were synthesized applying the recasting method with the inorganic particle loading of 2.5 wt%. The structures of these composite membranes were investigated by Scanning Electron Microscopy (SEM), proton conductivity measurement and water uptake measurement. Ultrasonic coating technique was used in the manufacturing of the Membrane Electrode Assemblies (MEAs). The performance tests of the composite membranes were conducted using in-house experiments. In these tests, the effect of methanol concentration (0.75, 1, and 1.5 M) on the performance of the MEA having Nafion 115 was investigated at 80 degrees C to find the value of the methanol concentration that yields the highest power density. This study showed that the MEA operating at 1 M gives the highest performance. Then, the performance of this MEA was compared with that of the MEAs having Nafion/ SiO2 and Nafion/TiO2 composite membranes in single cell DMFC setup at 60 degrees C, 80 degrees C, and 95 degrees C. The results of these experiments demonstrated that the MEA having Nafion/TiO2 composite membrane provides much better performance with the maximum power density values of 422.04 W/m(2), 641.16 W/m(2), and 710.88 W/m(2) at 60 degrees C, 80 degrees C, and 95 degrees C, respectively. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Article Citation Count: 5Investigation of the performance of high-temperature electrochemical hydrogen purification from reformate gases(Wiley, 2022) Durmuş, Gizem Nur Bulanık; Colpan, C. Ozgur; Devrim, Yılser; Mechanical Engineering; Energy Systems EngineeringIn the present work, the purification of hydrogen from a hydrogen/carbon dioxide/carbon monoxide (H-2:CO2:CO) mixture by a high-temperature electrochemical purification (HT-ECHP) system is examined. Electrochemical H-2 purification experiments were carried out in the temperature range of 140-180 degrees C. The effects of the molar ratio of the gases in the mixture (H-2:CO2:CO-75:25:0, H-2:CO2:CO-72:26:2,0 H-2:CO2:CO-75:22:3, H-2:CO2:CO-75:20:5, H-2:CO2:CO-97:0:3, H-2:CO2:CO-95:0:5) and the operating temperature on the electrochemical H-2 separation were investigated. As a result of the electrochemical H-2 purification experiments, it was determined that the operating temperature is the most important parameter affecting the performance. According to the results obtained, H-2 purity of 99.999% was achieved at 160 degrees C with the reformate gas mixture containing 72% H-2, 26% CO2, and 2% CO by volume. According to the polarization curves of the gas mixtures containing CO, high current densities at low voltage were reached at 180 degrees C, and it was observed that the performance increased as the temperature increased, whereas the gas mixture without CO gave the best performance at 160 degrees C.Article Citation Count: 0Mathematical modeling of a direct dimethyl ether fuel cell(Wiley-hindawi, 2022) Durmuş, Gizem Nur Bulanık; Durmus, Gizem Nur Bulanik; Devrim, Yılser; Devrim, Yilser; Mechanical Engineering; Energy Systems EngineeringIn this study, a mathematical model of a direct dimethyl ether fuel cell (DDMEFC) is developed to examine the effect of operating conditions on voltage losses and cell performance. In modeling, the electrochemical relations and mass balances are used to find the cell voltage for the given conditions. The values of some modeling parameters are determined using experimental data through curve fitting. For validation purposes, in-house experimental studies are conducted. For this purpose, Pt50Ru25Pd25/C, Pt40Ru40Pd20/C, and Pt50Pd50/C anode catalysts are synthesized by the microwave method. The effects of these synthesized catalysts and the operating conditions (cell temperature, the molar ratio of dimethyl ether, and water) on the DDMEFC performance are discussed by comparing the activation and ohmic polarization as well as the polarization curves using the model developed. This cell-level modeling approach could be considered as a preliminary step in the design process of a DDMEFC stack.Conference Object Citation Count: 0Optimization of modeling parameters of of a direct dimethyl ether fuel cell (DDMEFC)(Ieee, 2019) Devrim, Yılser; Colpan, C. Ozgur; Devrim, Yilser; Energy Systems EngineeringDirect alcohol fuel cells are one of the suitable candidates for sustainable power generation in portable applications. Among the different alcohol types that can be used in these fuel cells, DME, which is almost non-toxic at room temperature and easy to liquefy, and has a molecular structure similar to methanol, is one of the suitable options. For this reason, many studies have been carried out to develop direct dimethyl ether fuel cell (DDMEFC). Mathematical modeling studies also play an important role in the development of DDMEFC since they enable the understanding of the performance of the fuel cells more thoroughly. In this study, a model has been developed by using the principles of conservation chemical species and electrochemistry. A modeling study was performed using MATLAB. The values of some modeling parameters were estimated using the genetic algorithm optimization technique.Article Citation Count: 23Performance of an HT-PEMFC having a catalyst with graphene and multiwalled carbon nanotube support(Wiley, 2019) Devrim, Yılser; Devrim, Yilser; Colpan, C. Ozgur; Energy Systems EngineeringIn this study, the effect of multiwalled carbon nanotube and graphene nanoplatelet-based catalyst supports on the performance of reformate gas-fed polybenzimidazole (PBI)-based high-temperature proton exchange membrane fuel cell (HT-PEMFC) was investigated. In addition, the effect of several microwave conditions on the performance of the Pt-Ru/multiwalled carbon nanotube (MWCNT)-graphene nanoplatelet (GNP) catalyst was assessed. Through X-ray diffraction, thermal gravimetric analysis, transmission electron microscopy, scanning electron microscopy, and energy dispersive spectroscopy, the catalysts' chemical structure and morphology were characterized. Cyclic voltammetry analysis was used for the electrochemical characterization of catalysts through an electrochemical cell with three electrodes connected to a potentiostat. The results showed that the best performing catalyst is the catalyst produced using 800-W power for 40 seconds. The electrochemically active surface area values of this catalyst ranged from 54 to 45 m(2)/g. Single-cell performance tests of the HT-PEMFC were then carried out. In these tests, reformate gas mixture, consisting of H-2, CO2, and CO, was fed to the anode side at 160 degrees C without humidification. These tests for the best performing catalyst yielded peak power density of 0.280 W/cm(2) and current density (at 0.6 V) of 0.180 A/cm(2) in the H-2/air environment and peak power density of 0.266 W/cm(2) and current density (at 0.6 V) of 0.171 A/cm(2) in the reformate gas/air environment. As a result of the experiments, it was found that Pt-Ru/MWCNT-GNP hybrid material is a suitable catalyst for HT-PEMFC.Review Citation Count: 42A review on the development of the electrochemical hydrogen compressors(Elsevier, 2021) Durmuş, Gizem Nur Bulanık; Colpan, C. Ozgur; Devrim, Yılser; Mechanical Engineering; Energy Systems EngineeringHydrogen should be stored at high pressure and high purity, especially when utilized in fuel cells. Conventionally, mechanical compressors are used for pressurization of hydrogen; however, this technology has disadvantages such as noise and vibration during operation due to their moving parts. Electrochemical hydrogen compressors (ECHC) have emerged as an alternative solution, as these devices can purify and compress hydrogen electrochemically in a single device. This review provides a comprehensive overview of key components and management strategies of the ECHC systems. This review will also provide an overview of different hydrogen compression technologies and provides a comprehensive overview of the latest developments and current issues and future of ECHCs. For this purpose, firstly, the advantages and disadvantages of ECHC compared to mechanical compressors are explained. Then, recent studies on hydrogen purification methods are given. The working principle of ECHC, material development studies and mathematical modeling of ECHCs are also discussed.