Mathematical modeling of a direct dimethyl ether fuel cell

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Date

2022

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Wiley-hindawi

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Organizational Unit
Mechanical Engineering
(2009)
The Atılım University Department of Mechanical Engineering started education in 2009, and offers graduate and doctorate degree programs, in addition to its undergraduate program. Our main goal is to graduate Mechanical Engineers who have the skills to design, analyze and synthesize; who are able to convert advanced technology and innovations into products; and who have the culture of research and cooperation. While our graduates reach this goal, they adopt the principle of life-long learning, and develop a sense of entrepreneurship, paying importance to professional ethics. With a curriculum prepared in line with the criteria of MÜDEK, we help our students develop themselves professionally, and socially. Graduates of mechanical engineering may be employed in many sectors and in a wide array of positions. Able to work under any field that involves production and energy conversion, graduates of the department may also gain expertise in fields such as aviation, automotive, or material engineering.
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Energy Systems Engineering
(2009)
The Department of Energy Systems Engineering admitted its first students and started education in the academic year of 2009-2010 under Atılım University School of Engineering. In this Department, all kinds of energy are presented in modules (conventional energy, renewable energy, hydrogen energy, bio-energy, nuclear energy, energy planning and management) from their detection, production and procession; to their transfer and distribution. A need is to arise for a surge of energy systems engineers to ensure energy supply security and solve environmental issues as the most important problems of the fifty years to come. In addition, Energy Systems Engineering is becoming among the most important professions required in our country and worldwide, especially within the framework of the European Union harmonization process, and within the free market economy.

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Abstract

In this study, a mathematical model of a direct dimethyl ether fuel cell (DDMEFC) is developed to examine the effect of operating conditions on voltage losses and cell performance. In modeling, the electrochemical relations and mass balances are used to find the cell voltage for the given conditions. The values of some modeling parameters are determined using experimental data through curve fitting. For validation purposes, in-house experimental studies are conducted. For this purpose, Pt50Ru25Pd25/C, Pt40Ru40Pd20/C, and Pt50Pd50/C anode catalysts are synthesized by the microwave method. The effects of these synthesized catalysts and the operating conditions (cell temperature, the molar ratio of dimethyl ether, and water) on the DDMEFC performance are discussed by comparing the activation and ohmic polarization as well as the polarization curves using the model developed. This cell-level modeling approach could be considered as a preliminary step in the design process of a DDMEFC stack.

Description

Colpan, Can Ozgur/0000-0003-0855-3147; DEVRIM, YILSER/0000-0001-8430-0702

Keywords

bimetallic catalyst, catalyst, direct dimethyl ether fuel cell, mathematical modeling

Turkish CoHE Thesis Center URL

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0

WoS Q

Q1

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Q1

Source

Volume

46

Issue

9

Start Page

11989

End Page

12002

URI

https://doi.org/10.1002/er.7966
 https://hdl.handle.net/20.500.14411/1772

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