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Article Citation - WoS: 3Citation - Scopus: 4Structural, Optical and Electrical Properties of Bi1.5zn0.92< Pyrochlore Ceramics(Univ Fed Sao Carlos, dept Engenharia Materials, 2021) Qasrawi, A. F.; Abdalghafour, Mays A.; Mergen, A.Herein, the structural, morphological, compositional, optical, electrical and dielectric properties of Bi1.5Zn0.92Nb1.5-6x/5WxO6.92 (BZN) solid solutions are reported. Tungsten substituted BZN ceramics which are fabricated by the solid state reaction technique exhibited solubility limits at substitution level below x=0.18. Remarkable engineering in the structural, optical, electrical and dielectric properties of the pyrochlore ceramics is achieved via W substitution. Namely, shrinkage in both of the lattice parameters and in the energy band gap accompanied with decrease in the microstrain, in the dielectric constant and in the electrical resistivity is observed upon increasing the W content below the solubility limit. The increase in the W content in the BZN ceramics enhances the densification of the pyrochlore and leads to higher light absorbability and larger crystallites growth. The temperature dependent electrical resistivity measurements has also shown that the pyrochlore exhibit thermal stability below 380 K.Article Citation - WoS: 1Citation - Scopus: 1Growth and Optical Properties of (na0.5bi0.5< (x=0.25) Single Crystal: a Potential Candidate for Optoelectronic Devices(Springer, 2024) Guler, I.; Isik, M.; Gasanly, N.Double tungstates (DT) and double molybdates (DM) have significant importance because of their optoelectronic applications. Regarding the importance of DT and DM, we investigated experimentally structural and optical properties of (Na0.5Bi0.5)(Mo1-xWx)O-4 (x = 0.25) crystal that belongs to the NaBi-DT and DM crystals group. Czochralski method was used to grow the single crystals. The structure of the crystal was identified using X-ray diffraction (XRD) measurements. Two sharp peaks associated with tetragonal crystal structure appeared in the pattern. Vibrational modes of the studied crystal were obtained from the Raman experiments. By the help of the Fourier transform infrared spectrophotometer (FTIR) measurements, infrared transmittance spectrum of the studied compound was recorded. Band gap energy wase found around 3.04 eV using two methods, Tauc and derivative analysis, based on transmission spectrum. Based on the analysis of absorption coefficient, Urbach energy was obtained as 0.22 eV. The revealed structural and optical properties of the crystal indicated that the material may be a candidate for optoelectronic devices in which NaBi(MoO4)(2) and NaBi(WO4)(2) materials are utilized.Article Citation - WoS: 1Citation - Scopus: 1Tungsten Doped Bi1.5zn0.92< Ceramics Designed as Radio/Microwave Band Pass/Reject Filters(Wiley, 2021) Qasrawi, Atef F.; Abdalghafour, Mays A.; Mergen, A.Herein, radiowave/microwave bandpass/reject filters are fabricated from the tungsten doped Bi1.5Zn0.92Nb1.5-6x/5WxO6.92 (W-BZN) pyrochlore ceramics. The W-BZN band filters are prepared by the solid state reaction technique and subjected to X-ray diffraction (XRD) and impedance spectroscopy analyses. It was shown that the W-BZN filters can display negative capacitance effects accompanied with resonance-antiresonance oscillations. The calculations of the reflection coefficient parameter (S-11), the return loss (L-r) and the voltage standing wave ratios (VSWR) in the frequency domain of 0.01 to 1.80 GHz, has shown that the W-BZN device can perform as microwave cavities at two notch frequency values of 0.44 and 1.53 GHz. W-BZN devices can also be nominated as noise reducers and radiowave/microwave signal receivers suitable for telecommunication technology.Article Citation - Scopus: 11Cd-Doping Effects on the Properties of Polycrystalline Α-In2se3 Thin Films(2002) Qasrawi,A.F.The X-ray diffraction has revealed that the polycrystalline hexagonal structured α-In2Se3 thin films grown at substrate temperature of 200°C with the unit cell parameters a=4.03°A and c=19.23°A becomes polycrystalline hexagonal structured InSe with a unit cell parameters of a=4.00°A and c=16.63°A by Cd-doping. The analysis of the conductivity temperature dependence in the range 300-40 K revealed that the thermionic emission of charged carriers and the variable range hopping are the predominant conduction mechanism above and below 100 K, respectively. Hall measurements revealed that the mobility is limited by the scattering of charged carriers through the grain boundaries above 200 K and 120 K for the undoped and Cd-doped samples, respectively. The photocurrent (Iph) increases with increasing illumination intensity (F) and decreasing temperature up to a maximum temperature of ∼100 K, below which Iph is temperature invariant. It is found to have the monomolecular and bimolecular recombination characters at low and high illumination intensities, respectively. The Cd-doping increases the density of trapping states that changes the position of the dark Fermi level leading to the deviation from linearity in the dependence of Iph on F at low illumination intensities.Article Citation - WoS: 11Cd-Doping Effects on the Properties of Polycrystalline Α-in2se3< Thin Films(Wiley-v C H verlag Gmbh, 2002) Qasrawi, AFThe X-ray diffraction has revealed that the polycrystalline hexagonal structured alpha-In2Se3 thin films grown at substrate temperature of 200degreesC with the unit cell parameters a=4.03degreesA and c=19.23degreesA becomes polycrystalline hexagonal structured InSe with a unit cell parameters of a=4.00degreesA and c=16.63degreesA by Cd-doping. The analysis of the conductivity temperature dependence in the range 300-40 K revealed that the thermionic emission of charged carriers and the variable range hopping are the predominant conduction mechanism above and below 100 K, respectively. Hall measurements revealed that the mobility is limited by the scattering of charged carriers through the grain boundaries above 200 K and 120 K for the undoped and Cd-doped samples, respectively. The photocurrent (I-ph) increases with increasing illumination intensity (T) and decreasing temperature up to a maximum temperature of similar to100 K, below which I-ph is temperature invariant. It is found to have the monomolecular and bimolccular recombination characters at low and high illumination intensities, respectively. The Cd-doping increases the density of trapping states that changes the position of the dark Fermi level leading to the deviation from linearity in the dependence of I-ph on F at low illumination intensities.
