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Article İKİ KATMANLI DOLU BİR SİLİNDİRİN ELASTİK DAVRANIŞININ FARKLI UÇ VE SINIR KOŞULLARI İÇİN ANALİTİK OLARAK İNCELENMESİ(Turkish Soc thermal Sciences Technology, 2020) Akış, Tolga; Eraslan, Ahmet N.İki katmanlı dolu silindirlerin zamana bağlı termoelastik davranışlarının farklı uç ve sınır koşulları için belirlenmesi amacıyla analitik modeller geliştirilmiştir. Söz konusu silindirler, aralarında mükemmel temas olan ikikatmandan oluşmaktadır. Başlangıçta sıcak olan silindir, yüzeyinden konveksiyon yolu ile sıfır derecelik çevreselsıcaklığa veya önceden daha düşük olarak belirlenen yüzey sıcaklığına ulaşana kadar enerji kaybetmektedir. Tümdurumlarda soğuma yavaş bir biçimde gerçekleştiğinden problemde kuplajsız elastisite teorisinin kullanılması mümkünolmuştur. Genelleştirilmiş düzlemsel şekil değiştirme çözümü elde edilmiş ve bu çözüm, eksenel yöndeki birim şekildeğiştirmeyi sıfıra eşitleyerek düzlemsel şekil değiştirme durumuna ait çözüme indirgenmiştir. Bu çözümlere aitsonuçlar, sınır koşullarının serbest olduğu durumlarda radyal ve teğetsel yöndeki gerilmelerin uç koşullarına göredeğişmediğini göstermiştir. Ancak düzlemsel şekil değiştirme durumunda, eksenel gerilme baskın gerilme olmakta veuçların serbest olduğu duruma göre oldukça yüksek değerlere ulaşmaktadır. Kompozit silindirin eksenel ve radyalyönde yer değiştirmesinin kısıtlanması büyük gerilmelere yol açmasına rağmen ilgili gerilme durumu silindirde akmayayol açmamaktadır.Article Deposition and Characterization of Znsnse2 Thin-Films Deposited by Using Sintered Stoichiometric Powder(2019) Sürücü, Özge Bayraklı; Güllü, Hasan HüseyinIn this work, ZnSnSe2 (ZTSe) thin films were deposited using crystalline powder grown by vertical Bridgman-Stockbarger technique. The deposition process was carried out by means of e-beam evaporation on the well-cleaned soda lime glass substrates and keeping them at the substrate temperature of 200°C. The structural, optical and electrical properties of ternary ZTSe thin films were investigated depending on the annealing temperature at 250 and 300°C. X-ray diffraction analysis showed that as-grown films were in amorphous structure, however annealing at 250°C triggered the crystallization on the preferred ternary structure and annealing at 300°C resulted in the changes from amorphous to the polycrystalline structure. Using the compositional analysis, the detail information about the stoichiometry and the segregation mechanisms of the constituent elements in the structure were determined for both as-grown and annealed samples. In addition, they were morphologically characterized using scanning electron microscopy technique. The electrical properties were analyzed using temperature dependent dark- and photo-conductivity measurements. From the variation of electrical conductivity as a function of the ambient temperature, the current transport mechanisms and corresponding activation energies at specific temperature intervals for each sample were determined. The optical properties for the ZTSe thin films were studied depending on the structural changes with annealing.Article Boric Acid Versus Boron Trioxide as Catalysts for Green Energy Source H2 Production From Sodium Borohydride Methanolysis(2021) Demirci, Sahin; Ari, Betul; Sengel, Sultan B.; Inger, Erk; Sahiner, NurettinHere, boric acid (H3BO3) and its dewatered form, boron trioxide (B2O3) were tested as catalysts for hydrogen (H2) evolution in the methanolysis of sodium borohydride (NaBH4) in methanol. Parameters such as catalyst types and their amounts, NaBH4 concentration, and the reaction temperature affecting the hydrogen generation rate (HGR) were studied. It has been found that H3BO3 and B2O3 catalyzed methanolysis reaction of NaBH4 follow up first-order kinetics relative to the concentration of NaBH4. Furthermore, the conversion and activity of these catalysts were examined to determine their performance in ten consecutive use. Interestingly, H3BO3 and B2O3 have demonstrated superior catalytic performances in methanolysis of NaBH4 comparing to the studies published in literature with the activation energy of respectively 22.08 kJ.mol-1, and 23.30 kJ.mol-1 in H2 production. The HGR was calculated as 6481 mL.min-1.g-1 and 5163 mL.min-1.g-1 for H3BO3 and B2O3 catalyst, respectively for 50 mg catalyst at 298 K. These results are comparably better than most metal nanoparticle catalysts used for H2 production in addition to the naturally occurring boron-based environmentally friendliness of these materials.Article Experimental and Theoretical Investigation of the Reaction Between Co2andcarbon Dioxide Binding Organic Liquids(2016) Tankal, Hilal; Orhan, Özge Yüksel; Alper, Erdoğan; Özdoğan, Telhat; Kayı, HakanThe reaction kinetics of CO2absorption into new carbon dioxide binding organic liquids (CO2BOLs) was com-prehensively studied to evaluate their potential for CO2removal. A stopped- ow apparatus with conductivity detectionwas used to determine the CO2absorption kinetics of novel CO2BOLs composed of DBN (1,5-diazabicyclo[4.3.0]non-5-ene)/1-propanol and TBD (1,5,7-triazabicyclo[4.4.0]dec-5-ene)/1-butanol. A modi ed termolecular reaction mechanismfor the reaction of CO2with CO2BOLs was used to calculate the observed pseudo- rst{order rate constant k0(s1)and second-order reaction rate constant k2(m3/kmol.s). Experiments were performed by varying organic base (DBN orTBD) weight percentage in alcohol medium for a temperature range of 288{308 K. It was found that k0increased withincreasing amine concentration and temperature. By comparing using two different CO2BOL systems, it was observedthat the TBD/1-butanol system has faster reaction kinetics than the DBN/1-propanol system. Finally, experimentaland theoretical activation energies of these CO2BOL systems were obtained and compared. Quantum chemical calcula-tions using spin restricted B3LYP and MP2 methods were utilized to reveal the structural and energetic details of thesingle-step termolecular reaction mechanism.Research Project Nadir Toprak Elementi Katkılı Zno Nanokritallerinin Sentezlenmesi ve Düşük Sıcaklık Termolüminesans Özelliklerinin İncelenmesi(2019) Işık, MehmetKatkısız ve Gd, Yb ve Er katkılı ZnO nanokristaller sol-jel yöntemi ile sentezlendi. Sentezlenen nanoparçacıkların yapısal ve termolüminesans (TL) özellikleri bu çalışmada incelendi. Yapısal özelliklerinin incelenmesi x-ışını kırınımı ve tarayıcı elektron mikroskobu (SEM) ölçüm teknikleri ile gerçekleştirildi. X-ışını kırınımı sonucunda sentezlenen nanoparçacıkların kristal yapıları hakkında bilgi edinilirken, SEM görüntüleri sayesinde de nanoparçacıkların boyutları hakkında bilgi sahibi olundu. Nanoparçacıkların TL eğrileri 10- 300 K sıcaklık aralığında sabit bir ısıtma hızı (0.2 K/s) kullanılarak yapılan ölçümler ile elde edildi. Ölçümler sonucunda gözlemlenen TL eğrileri eğri fit ve ilk yükselme yöntemleri kullanılarak analiz edildi. Analizler sonucunda TL eğrilerinin oluşmasına sebep olan tuzak merkezlerinin aktivasyon enerjileri belirlendi. Farklı oranlarda sentezleme yapılan katkılamalar sonucunda herbir katkılama oranında gözlemlenen TL eğrileri katkısız ZnO nanoparçacıklara ait TL eğrileri ile kıyaslanarak katkılamanın ZnO malzemesine etkisi incelendi. Tuzak dağılımlarının karakteristikleri ile ilgili bilgi edinebilmek amacı ile katkısız ZnO nanoparçacıklar ışıklandırma sıcaklığı değiştirerek uygulanan deneysel bir yönteme tabi tutuldu. Farklı sıcaklıklarda yapılan ışıklandırma sonucunda gözlemlenen TL eğrilerinin özellikleri incelenerek tuzak merkezlerinin yasaklı bant boşluğu içerisindeki dağılımı hakkında detaylı bir bilgiye sahip olundu.Article Synthesis and Investigation of Structural-Mechanical Properties of C-Bn Based Bn Thin Films(2017) Efeoğlu, İhsan; Totik, Yaşar; Keleş, Ayşenur; Ersoy, Kıvılcım; Durkaya, Göksel; Dayauç, Ayşenur KeleşC-BN films are candidate material to diamond due to their promising properties. Although some properties of c-BN films are better than diamond, adhesion properties between the substrate and the film are very poor. In this study, c-BN films were deposited by closed-field unbalanced magnetron sputtering system onto 4140 steels in Ar/N2 atmosphere. The c-BN films coated in three different N2flow rates. The coated specimens were characterized by SEM and X-ray diffraction techniques. The bonding state of B, N and C elements were obtained using XPS. The mechanical properties of the c-BN films were tested by micro-indentation. The adhesion properties between substrate and the film were investigated by using scratch test. The tribological properties were carried out using pin-on-disc in atmospheric conditions. Our results showed that the c-BN films exhibited very dense and columnar microstructure. The maximum critical load was read 23 N in the softest c-BN film. The maximum and minimum hardness were measured 69 GPa and 33 GPa, respectively. When the hardness was increased the friction coefficient was decreased. The lowest friction coefficient (0.15) was obtained from the hardest film and the highest friction coefficient (0.65) was obtained from the lowest hardness
