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Article Citation - WoS: 58Citation - Scopus: 66Experimental Investigation of a Natural Zeolite-Water Adsorption Cooling Unit(Elsevier Sci Ltd, 2011) Solmus, Ismail; Kaftanoglu, Bilgin; Yamali, Cemil; Baker, DerekIn this study, a thermally driven adsorption cooling unit using natural zeolite-water as the adsorbent-refrigerant pair has been built and its performance investigated experimentally at various evaporator temperatures. The primary components of the cooling unit are a shell and tube adsorbent bed, an evaporator, a condenser, heating and cooling baths, measurement instruments and supplementary system components. The adsorbent bed is considered to enhance the bed's heat and mass transfer characteristics; the bed consists of an inner vacuum tube filled with zeolite (zeolite tube) inserted into a larger tubular shell. Under the experimental conditions of 45 degrees C adsorption, 150 degrees C desorption, 30 degrees C condenser and 22.5 degrees C, 15 degrees C and 10 degrees C evaporator temperatures, the COP of the adsorption cooling unit is approximately 0.25 and the maximum average volumetric cooling power density (SCR,) and mass specific cooling power density per kg adsorbent (SCP) of the cooling unit are 5.2 kW/m(3) and 7 W/kg, respectively. (C) 2011 Elsevier Ltd. All rights reserved.Article Citation - WoS: 6Citation - Scopus: 7Polyethyleneimine Functionalized Waste Tissue Paper@waste PET Composite for the Effective Adsorption and Filtration of Organic Dyes From Wastewater(Elsevier B.V., 2025) Radoor, Sabarish; Karayil, Jasila; Devrim, Yilser; Kim, HernThis study explores the potential of repurposing discarded plastic bottles and cellulosic paper waste to develop cost-effective and high-performance composites for dye removal applications. A novel composite, polyethyleneimine (PEI)-functionalized waste tissue integrated into waste polyethylene terephthalate (wPET) (PEIWT/wPET), was designed as an environmentally friendly adsorbent for wastewater treatment. Successful surface functionalization with PEI was confirmed through FTIR, EDX, and XPS analyses. The PEI-modified composite exhibited enhanced mechanical and thermal stability while demonstrating significantly improved dye adsorption/filtration performance. The composite was evaluated for the removal of both cationic (crystal violet, CV) and anionic (orange II, O II) dyes under optimized conditions; (10,000 mg/L and 1666 mg/L) adsorbent dosage, (11 and 1) pH, 10 mg/L initial dye concentration, and (180 min and 120 min) contact time for CV and O II respectively. Experimental results showed that PEIWT/wPET achieved maximum adsorption capacities of 3.94 mg/g for CV and 11.73 mg/g for O II, approximately five times higher than the unmodified composite (0.74 and 2.4 mg/g). Adsorption isotherm and kinetic studies indicated that the data aligned well with the Langmuir as well as Freundlich and pseudo-second order models. The membrane also exhibited filtration capability for both dyes, achieving a filtration efficiency of 78.69 % for anionic and 41.31 % for cationic dye separation. Overall, the PEIWT/wPET composite offers a promising, sustainable, and energy-efficient solution for the removal of organic pollutants.Article Citation - WoS: 43Numerical Investigation of Coupled Heat and Mass Transfer Inside the Adsorbent Bed of an Adsorption Cooling Unit(Elsevier Sci Ltd, 2012) Solmus, Ismail; Rees, D. Andrew S.; Yamali, Cemil; Baker, Derek; Kaftanoglu, BilginIn this study, the influence of several design parameters on the transient distributions of temperature, pressure and amount adsorbed in the radial direction of a cylindrical adsorbent bed of an adsorption cooling unit using silica gel/water have been investigated numerically. For this purpose, a transient one-dimensional local thermal non-equilibrium model that accounts for both internal and external mass transfer resistances has been developed using the local volume averaging method. For the conditions investigated, the validity of the local thermal equilibrium and spatially isobaric bed assumptions have been confirmed. To improve the performance of the bed considered, efforts should be focused on reducing heat transfer resistances and intra-particle (interior) mass transfer resistances but not inter-particle (exterior) mass transfer resistances. (C) 2011 Elsevier Ltd and IIR. All rights reserved.Article Citation - WoS: 77Citation - Scopus: 90Adsorption properties of a natural zeolite-water pair for use in adsorption cooling cycles(Elsevier Sci Ltd, 2010) Solmus, Ismail; Yamali, Cemil; Kaftanoglu, Bilgin; Baker, Derek; Caglar, AhmetThe equilibrium adsorption capacity of water on a natural zeolite has been experimentally determined at different zeolite temperatures and water vapor pressures for use in an adsorption cooling system. The Dubinin-Astakhov adsorption equilibrium model is fitted to experimental data with an acceptable error limit. Separate correlations are obtained for adsorption and desorption processes as well as a single correlation to model both processes. The isosteric heat of adsorption of water on zeolite has been calculated using the Clausius-Clapeyron equation as a function of adsorption capacity. The cyclic adsorption capacity swing for different condenser, evaporator and adsorbent temperatures is compared with that for the following adsorbent-refrigerant pairs: activated carbon-methanol; silica gel-water; and, zeolite 13X-water. Experimental results show that the maximum adsorption capacity of natural zeolite is nearly 0.12 kg(w)/kg(ad) for zeolite temperatures and water vapor pressures in the range 40-150 degrees C and 0.87-738 kPa. (C) 2009 Elsevier Ltd. All rights reserved.
