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Article Citation - WoS: 9Citation - Scopus: 9Experimental and Modeling Studies of a High-Temperature Electrochemical Hydrogen Compressor(Pergamon-elsevier Science Ltd, 2024) Durmus, Gizem Nur Bulanik; Kuzu, Cemil; Devrim, Yilser; Colpan, C. OzgurSome non-technical factors such as economics and logistics prevent hydrogen (H2) tech-nologies from becoming more widespread in daily life. Today, the prevalence of H2 tech-nologies requires new technological developments. Electrochemical hydrogen compressors (ECHC) are of great interest due to their ability to pressurize and purify in one step. In this study, the electrochemical H2 compression performance of high phosphoric acid (PA) doped poly 2,2-m-phenylene-5,5-benzimidazole (PBI) membrane-based HT-ECHC under high temperature and non-humid conditions was investigated through both an experimental and a numerical approach. The H2 compression capacity of HT-ECHC at different operating voltages was examined by performance tests at 160 degrees C, and it was determined that the electrochemical compression performance increased with increasing operating voltage. It was observed that the current density values also increased with increasing voltage, and it was determined that a current density of 61.2 A was obtained at 1 V. As a result of the tests, H2 was successfully compressed from atmospheric pressure to 60 bar by HT-ECHC without any gas leakage. The results of the developed model were compared with the experimental performance test data, and the variation of molar flow, cell voltage, and cell efficiency over time was examined. It has been determined that the back diffusion from the cathode to the anode in the cell increases with the increasing operating voltage of HT-ECHC and therefore the cell efficiency decreases. It has been evaluated that the developed model and experimental results are in good agreement. (c) 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Article Citation - WoS: 13Citation - Scopus: 17Effect of hydrogen on fracture locus of Fe-16Mn-0.6C-2.15Al TWIP steel(Pergamon-elsevier Science Ltd, 2020) Bal, Burak; Cetin, Baris; Bayram, Ferdi Caner; Billur, ErenEffect of hydrogen on the mechanical response and fracture locus of commercial TWIP steel was investigated comprehensively by tensile testing TWIP steel samples at room temperature and quasi-static regime. 5 different sample geometries were utilized to ensure different specific stress states and a digital image correlation (DIC) system was used during tensile tests. Electrochemical charging method was utilized for hydrogen charging and microstructural characterizations were carried out by scanning electron microscope. Stress triaxiality factors were calculated throughout the plastic deformation via finite element analysis (FEA) based simulations and average values were calculated at the most critical node. A specific Python script was developed to determine the equivalent fracture strain. Based on the experimental and numerical results, the relation between the equivalent fracture strain and stress triaxiality was determined and the effect of hydrogen on the corresponding fracture locus was quantified. The deterioration in the mechanical response due to hydrogen was observed regardless of the sample geometry and hydrogen changed the fracture mode from ductile to brittle. Moreover, hydrogen affected the fracture locus of TWIP steel by lowering the equivalent failure strains at given stress triaxiality levels. In this study, a modified Johnson-Cook failure mode was proposed and effect of hydrogen on damage constants were quantified. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Article Citation - WoS: 56Citation - Scopus: 64Development of 500 W Pem Fuel Cell Stack for Portable Power Generators(Pergamon-elsevier Science Ltd, 2015) Devrim, Yilser; Devrim, Huseyin; Eroglu, InciPolymer Electrolyte Membrane Fuel Cell (PEMFC) portable power generators are gaining importance in emergency applications. In this study, an air-cooled PEMFC stack was designed and fabricated for net 500 W power output. Gas Diffusion Electrodes (GDE's) were manufactured by ultrasonic spray coating technique. Stack design was based on electrochemical data obtained at 0.60 V was 0.5 A/cm(2) from performance tests of a single cell having the same membrane electrode assemblies (MEA) that had an active area of 100 cm(2). Graphite bipolar plates were designed and machined by serpentines type flow. The stack comprising of 24 cells was assembled with external fixing plates. The stack temperature was effectively regulated by the cooling fan based on on-off control system. A maximum power of 647 W was obtained from the stack. The PEMFC stack was stable during start-up and shutdown cycling testing for 7 days at 65 degrees C in H-2/air at a constant cell voltage. Copyright (c) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.Article Citation - WoS: 1Citation - Scopus: 1Novel Frequency-Domain Criterion for Elimination of Limit Cycles in a Class of Digital Filters With Single Saturation Nonlinearity(Pergamon-elsevier Science Ltd, 2008) Singh, VimalA frequency-domain criterion for the elimination of limit cycles in a class of digital filters utilizing single saturation nonlinearity is presented. The criterion is derived by exploiting the structural properties of the system under consideration in a greater detail. A novel feature of the criterion is that it takes the form of a matrix inequality, despite the fact that there is single nonlinearity in the system. An example showing the effectiveness of the criterion is given. (c) 2006 Elsevier Ltd. All rights reserved.Conference Object Citation - WoS: 86Citation - Scopus: 95Enhancement of Pem Fuel Cell Performance at Higher Temperatures and Lower Humidities by High Performance Membrane Electrode Assembly Based on Nafion/Zeolite Membrane(Pergamon-elsevier Science Ltd, 2015) Devrim, Yilser; Albostan, AyhanThis work reports the preparation of Nafion/zeolite composite membranes with different zeolite loading. The structure of the Nafion/zeolite composite membranes are investigated by Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD) and by thermogravimetric analysis (TGA). The introduction of zeolite particles into the Nafion matrix helps to improve the water uptake, proton conductivity and thermal stability of the nanocomposite membranes compared to the virgin Nafion membrane. The SEM analyses have proved the uniform and homogeneous distribution of zeolite in composite membranes. The composite membranes are tested in a single PEMFC with a 5 cm(2) active area operating at the temperature range of 75-120 degrees C and in humidified under 50% relative humidity (RH) and fully humidified conditions. Single PEMFC tests show that Nafion/zeolite composite membrane is more stable and also performed better than virgin Nafion membrane at low humidity condition. The results indicate the Nafion/zeolite composite membranes could be utilized as the proton exchange membranes for PEMFC. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.Article Citation - WoS: 76Citation - Scopus: 76Composite Membrane by Incorporating Sulfonated Graphene Oxide in Polybenzimidazole for High Temperature Proton Exchange Membrane Fuel Cells(Pergamon-elsevier Science Ltd, 2022) Devrim, Yilser; Durmus, Gizem Nur BulanikThe objective of this work is to examine the polybenzimidazole (PBI)/sulfonated graphene oxide (sGO) membranes as alternative materials for high-temperature proton exchange membrane fuel cell (HT-PEMFC). PBI/sGO composite membranes were characterized by TGA, FTIR, SEM analysis, acid doping&acid leaching tests, mechanical analysis, and proton conductivity measurements. The proton conductivity of composite membranes was considerably enhanced by the existence of sGO filler. The enhancement of these properties is related to the increased content of -SO3H groups in the PBI/sGO composite membrane, increasing the channel availability required for the proton transport. The PBI/sGO membranes were tested in a single HT-PEMFC to evaluate high-temperature fuel cell performance. Amongst the PBI/sGO composite membranes, the membrane containing 5 wt. % GO (PBI/sGO-2) showed the highest HT-PEMFC performance. The maximum power density of 364 mW/cm(2) was yielded by PBI/sGO-2 membrane when operating the cell at 160 degrees C under non humidified conditions. In comparison, a maximum power density of 235 mW/cm(2) was determined by the PBI membrane under the same operating conditions. To investigate the HT-PEMFC stability, long-term stability tests were performed in comparison with the PBI membrane. After a long-term performance test for 200 h, the HT-PEMFC performance loss was obtained as 9% and 13% for PBI/sGO-2 and PBI membranes, respectively. The improved HT-PEMFC performance of PBI/sGO composite membranes suggests that PBI/sGO composites are feasible candidates for HT-PEMFC applications. (C) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Article Citation - WoS: 79Citation - Scopus: 82A Generalized Contraction Principle With Control Functions on Partial Metric Spaces(Pergamon-elsevier Science Ltd, 2012) Abdeljawad, Thabet; Karapinar, Erdal; Tas, KenanPartial metric spaces were introduced by Matthews in 1994 as a part of the study of denotational semantics of data flow networks. In this article, we prove a generalized contraction principle with control functions phi and psi on partial metric spaces. The theorems we prove generalize many previously obtained results. We also give some examples showing that our theorems are indeed proper extensions. (C) 2011 Elsevier Ltd. All rights reserved.Review Citation - WoS: 120Citation - Scopus: 142Dynamic Thermal and Hygrometric Simulation of Historical Buildings: Critical Factors and Possible Solutions(Pergamon-elsevier Science Ltd, 2020) Akkurt, G. G.; Aste, N.; Borderon, J.; Buda, A.; Calzolari, M.; Chung, D.; Turhan, C.Building dynamic simulation tools, traditionally used to study the hygrothermal performance of new buildings during the preliminary design steps, have been recently adopted also in historical buildings, as a tool to investigate possible strategies for their conservation and the suitability of energy retrofit scenarios, according to the boundary conditions. However, designers often face with the lack of reliable thermophysical input data for various envelope components as well as with some intrinsic limitations in the simulation models, especially to describe the geometric features and peculiarities of the heritage buildings. This paper attempts to bridge this knowledge gap, providing critical factors and possible solutions to support hygrothermal simulations of historical buildings. The information collected in the present work could be used by researchers, specialists and policy-makers involved in the conservation of building's heritage, who need to address a detailed study of the hygrothermal performance of historical buildings thorugh dynamic simulation tools.Article Citation - WoS: 20Citation - Scopus: 26Increasing Accuracy of Two-Class Pattern Recognition With Enhanced Fuzzy Functions(Pergamon-elsevier Science Ltd, 2009) Celikyilmaz, Asli; Tuerksen, I. Burhan; Aktas, Ramazan; Doganay, M. Mete; Ceylan, N. BasakIn building an approximate fuzzy classifier system, significant effort is laid oil estimation and fine tuning of fuzzy sets. However, in such systems little thought is given to the way in which membership functions are combined within fuzzy rules. In this paper, a robust method, improved fuzzy classifier functions (IFCF) design is proposed for two-class pattern recognition problems. A supervised hybrid improved fuzzy Clustering for classification (IFC-C) algorithm is implemented for structure identification. IFC-C algorithm is based oil it dual optimization method, which yields simultaneous estimates of the parameters of (c-classification functions together with fuzzy c partitioning of dataset based oil a distance measure. The merit of novel IFCF is that the information oil natural grouping of data samples i.e., the membership values, are utilized as additional predictors of each fuzzy classifier function to improve accuracy of system model. Improved fuzzy classifier functions are approximated using statistical and soft computing approaches. A new semi-non-parametric inference mechanism is implemented for reasoning. The experimental results Of the new modeling approach indicate that the new IFCF is it promising method for two-class pattern recognition problems. (c) 2007 Elsevier Ltd. All rights reserved.Article Citation - WoS: 17Citation - Scopus: 18Optimal Design and Technoeconomic Analysis of On-Site Hydrogen Refueling Station Powered by Wind and Solar Photovoltaic Hybrid Energy Systems(Pergamon-elsevier Science Ltd, 2025) Ozturk, Reyhan Atabay; Devrim, YilserIn this study, a grid-connected on-site hydrogen filling station (HRS) integrated with renewable energy systems is designed and examined for different daily hydrogen refueling capacities. The installation location of the HRS is selected in Izmir (Turkey) and daily solar radiation and wind speed data are used in the calculations. The HRS station was integrated with a hybrid energy system using photovoltaic panels (PV), wind turbine (WT) and PV/ WT and five different daily refueling scenarios were investigated. A techno-economic analysis is conducted for the designed HRS system, considering the initial investment capital, installation and operating costs. The levelized cost of hydrogen (LCOH) is evaluated according to different refueling capacity scenarios, periods of operation and renewable energy installation capacities. The lowest LCOH is obtained as 4.5 /kg H2 in the PVintegrated HRS system for a 20-year investment scenario. The results prove the suitability of the HRS system for integrating renewable energy in the identified region. It is recommended to integrate analytical models for the system components to increase the reliability of the design and optimization process in future planned studies.
