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Article Citation - WoS: 7Citation - Scopus: 7Trapping Centers and Their Distribution in Tl2ga2< Layered Single Crystals(Pergamon-elsevier Science Ltd, 2009) Isik, M.; Gasanly, N. M.Thermally stimulated current (TSC) measurements with current flowing perpendicular to the layers were carried out on Tl2Ga2Se3S layered single crystals in the temperature range of 10-260K. The experimental data were analyzed by using different methods, such as curve fitting, initial rise and isothermal decay methods. The analysis revealed that there were three trapping centers with activation energies of 12, 76 and 177 meV. It was concluded that retrapping in these centers was negligible, which was confirmed by the good agreement between the experimental results and the theoretical predictions of the model that assumes slow retrapping. The capture cross section and the concentration of the traps have been also determined. An exponential distribution of electron traps was revealed from the analysis of the TSC data obtained at different light illumination temperatures. This experimental technique provided values of 10 and 88 meV/decade for the traps distribution related to two different trapping centers. (C) 2009 Elsevier Ltd. All rights reserved.Article Citation - WoS: 25Citation - Scopus: 26Identifying the Potentials for Charge Transport Layers Free N-P Homojunction-Based Perovskite Solar Cells(Pergamon-elsevier Science Ltd, 2022) Khan, Danish; Sajid, Sajid; Khan, Suliman; Park, Jongee; Ullah, IhsanPerovskite solar cells (PSCs) with no charge transport layers (CTLs) could be one of the major device architectures for the production of simple and low-cost devices. However, CTLs-free PSCs based on n-p homojunction have yet to show high power conversion efficiency (PCE), which is most likely due to inadequate light-and charge-management in the p-type perovskite. The device operation is examined using Solar Cell Capacitance Simulator (SCAPS)-software, and a novel n-p homojunction design is proposed to attempt efficient CTLs-free PSCs. Several aspects of p-type layer that can affect device performance, such as acceptor density, photon harvesting capability, defects density, and resistances to the transport of charge-carriers are scrutinized and adjusted. Furthermore, the effects of different work-functions of metal electrodes are examined. A suitable acceptor concentration is required for oriented charge transport. It is determined that a p-type perovskite with a thickness of 0.3 mu m is advantageous for high performance. A metal electrode with a high work-function is essential for efficient device. Consequently, a PCE of 15.60% is obtained with an optimal defect density of E15 cm(-3), indicating that n-p homojunction-based CTLs-free PSCs are promising since they simplify the device design and fabrication process while retaining an acceptable PCE.Review Citation - WoS: 120Citation - Scopus: 142Dynamic Thermal and Hygrometric Simulation of Historical Buildings: Critical Factors and Possible Solutions(Pergamon-elsevier Science Ltd, 2020) Akkurt, G. G.; Aste, N.; Borderon, J.; Buda, A.; Calzolari, M.; Chung, D.; Turhan, C.Building dynamic simulation tools, traditionally used to study the hygrothermal performance of new buildings during the preliminary design steps, have been recently adopted also in historical buildings, as a tool to investigate possible strategies for their conservation and the suitability of energy retrofit scenarios, according to the boundary conditions. However, designers often face with the lack of reliable thermophysical input data for various envelope components as well as with some intrinsic limitations in the simulation models, especially to describe the geometric features and peculiarities of the heritage buildings. This paper attempts to bridge this knowledge gap, providing critical factors and possible solutions to support hygrothermal simulations of historical buildings. The information collected in the present work could be used by researchers, specialists and policy-makers involved in the conservation of building's heritage, who need to address a detailed study of the hygrothermal performance of historical buildings thorugh dynamic simulation tools.Article Citation - WoS: 17Citation - Scopus: 18Optimal Design and Technoeconomic Analysis of On-Site Hydrogen Refueling Station Powered by Wind and Solar Photovoltaic Hybrid Energy Systems(Pergamon-elsevier Science Ltd, 2025) Ozturk, Reyhan Atabay; Devrim, YilserIn this study, a grid-connected on-site hydrogen filling station (HRS) integrated with renewable energy systems is designed and examined for different daily hydrogen refueling capacities. The installation location of the HRS is selected in Izmir (Turkey) and daily solar radiation and wind speed data are used in the calculations. The HRS station was integrated with a hybrid energy system using photovoltaic panels (PV), wind turbine (WT) and PV/ WT and five different daily refueling scenarios were investigated. A techno-economic analysis is conducted for the designed HRS system, considering the initial investment capital, installation and operating costs. The levelized cost of hydrogen (LCOH) is evaluated according to different refueling capacity scenarios, periods of operation and renewable energy installation capacities. The lowest LCOH is obtained as 4.5 /kg H2 in the PVintegrated HRS system for a 20-year investment scenario. The results prove the suitability of the HRS system for integrating renewable energy in the identified region. It is recommended to integrate analytical models for the system components to increase the reliability of the design and optimization process in future planned studies.Article Citation - WoS: 137Citation - Scopus: 173Re-Usage of Waste Foundry Sand in High-Strength Concrete(Pergamon-elsevier Science Ltd, 2010) Guney, Yucel; Sari, Yasin Dursun; Yalcin, Muhsin; Tuncan, Ahmet; Donmez, SenayiIn this study, the potential re-use of waste foundry sand in high-strength concrete production was investigated. The natural fine sand is replaced with waste foundry sand (0%, 5%, 10%, and 15%). The findings from a series of test program has shown reduction in compressive and tensile strengths, and the elasticity modulus which is directly related to waste foundry inclusion in concrete. Nevertheless the concrete with 10% waste foundry sand exhibits almost similar results to that of the control one. The slump and the workability of the fresh concrete decreases with the increase of the waste foundry sand ratio. Although the freezing and thawing significantly reduces the mechanical and physical properties of the concrete. The obtained results satisfies the acceptable limits set by the American Concrete Institute (Ad). (C) 2010 Elsevier Ltd. All rights reserved.Article Citation - WoS: 45Citation - Scopus: 46Carbon Nanotube-Graphene Supported Bimetallic Electrocatalyst for Direct Borohydride Hydrogen Peroxide Fuel Cells(Pergamon-elsevier Science Ltd, 2021) Uzundurukan, Arife; Akca, Elif Seda; Budak, Yagmur; Devrim, YilserAt present study, carbon nanotube-graphene (CNT-G) supported PtAu, Au and Pt catalysts were prepared by microwave-assisted synthesis method to investigate the direct liquid-fed sodium borohydride/hydrogen peroxide (NaBH4/H2O2) fuel cell performance. Prepared catalysts were characterized by TGA, XRD, TEM, ICP-OES, cyclic voltammetry and rotating disc electrode (RDE) voltammetry. The catalysts were tested in a single NaBH4/H2O2 fuel cell with 25 cm(2) active area to evaluate fuel cell performance. The effects of temperature and fuel concentration on fuel cell performance were examined to observed best operating conditions. As a result of direct NaBH4/H2O2 fuel cell experiments, maximum power densities of 139 mW/cm(2), 125 mW/cm(2) and 113 mW/cm(2) were obtained for PtAu/CNT-G, Au/CNT-G and Pt/CNT-G catalysts, respectively. PtAu/CNT-G catalyst showed the enhanced NaBH4/H2O2 fuel cell performance, which was higher than the Pt/CNT-G catalyst and Au/CNT-G catalyst at 50 degrees C. The enhanced NaBH4/H2O2 performance can be attributed to synergistic effects between Pt and Au particles on CNT-G support providing a better catalyst utilization and interaction. These results suggest that the prepared PtAu/CNT-G catalyst is a promising anode catalyst for NaBH4/H2O2 fuel cell application. (c) 2020 Elsevier Ltd. All rights reserved.Article Citation - WoS: 36Citation - Scopus: 42Development of a Personalized Thermal Comfort Driven Controller for Hvac Systems(Pergamon-elsevier Science Ltd, 2021) Turhan, Cihan; Simani, Silvio; Akkurt, Gulden GokcenIncreasing thermal comfort and reducing energy consumption are two main objectives of advanced HVAC control systems. In this study, a thermal comfort driven control (PTC-DC) algorithm was developed to improve HVAC control systems with no need of retrofitting HVAC system components. A case building located in Izmir Institute of Technology Campus-Izmir-Turkey was selected to test the developed system. First, wireless sensors were installed to the building and a mobile application was developed to monitor/ collect temperature, relative humidity and thermal comfort data of an occupant. Then, the PTC-DC algorithm was developed to meet the highest occupant thermal comfort as well as saving energy. The prototypes of the controller were tested on the case building from July 3rd, 2017 to November 1st, 2018 and compared with a conventional PID controller. The results showed that the developed control algorithm and conventional controller satisfy neutral thermal comfort for 92 % and 6 % of total measurement days, respectively. From energy consumption point of view, the PTC-DC decreased energy consumption by 13.2 % compared to the conventional controller. Consequently, the PTC-DC differs from other works in the literature that the prototype of PTC-DC can be easily deployed in real environments. Moreover, the PTC-DC is low-cost and user-friendly. (c) 2021 Elsevier Ltd. All rights reserved.Review Citation - WoS: 39Citation - Scopus: 43Hydropower in Turkey: Analysis in the View of Vision 2023(Pergamon-elsevier Science Ltd, 2013) Melikoglu, MehmetTurkey is a recently developed country, a regional power in the Middle East and an economic powerhouse of the region. Turkey's electricity demand is continuously increasing due to fast economic growth coupled with the country's vibrant young population. It is envisaged that this demand would keep on increasing almost exponentially in the next decade according to the recently avowed Vision 2023 agenda. According to which, the Turkish government ambitiously wants to provide 30.0% of the country's electricity demand from renewable energy sources by 2023. Turkey has vast renewable energy potential including hydro, geothermal, solar and wind. However, historically there is only one playmaker that is hydropower. Thus a detailed review of the current status and future prospects of Turkish hydropower market is urgently needed to generate a roadmap for the Vision 2023 agenda. This paper was intended to provide that vital information. Currently, more than 25.0% or 57.5 TWh of the country's electricity demand is supplied from hydropower. According to official projections this would increase to approximately 116.0 TWh in 2023. In this study, hydropower's supply rate of Turkey's annual electricity demand was assessed based on the official projections and a forecast was generated. Results showed that between 22.0% and 27.0% of Turkey's annual electricity demand should be supplied from hydropower in 2023. Therefore, between 22.5 TWh and 45.0 TWh of electricity should be generated from renewable energy sources other than hydropower to provide a total of 30.0% renewable energy based electricity generation in 2023. (C) 2013 Elsevier Ltd. All rights reserved.Review Citation - WoS: 88Citation - Scopus: 95Vision 2023: Forecasting Turkey's Natural Gas Demand Between 2013 and 2030(Pergamon-elsevier Science Ltd, 2013) Melikoglu, MehmetNatural gas is the primary source for electricity production in Turkey. However, Turkey does not have indigenous resources and imports more than 98.0% of the natural gas it consumes. In 2011, more than 20.0% of Turkey's annual trade deficit was due to imported natural gas, estimated at US$ 20.0 billion. Turkish government has very ambitious targets for the country's energy sector in the next decade according to the Vision 2023 agenda. Previously, we have estimated that Turkey's annual electricity demand would be 530,000 GWh at the year 2023. Considering current energy market dynamics it is almost evident that a substantial amount of this demand would be supplied from natural gas. However, meticulous analysis of the Vision 2023 goals clearly showed that the information about the natural gas sector is scarce. Most importantly there is no demand forecast for natural gas in the Vision 2023 agenda. Therefore, in this study the aim was to generate accurate forecasts for Turkey's natural gas demand between 2013 and 2030. For this purpose, two semi-empirical models based on econometrics, gross domestic product (GDP) at purchasing power parity (PPP) per capita, and demographics, population change, were developed. The logistic equation, which can be used for long term natural gas demand forecasting, and the linear equation, which can be used for medium term demand forecasting, fitted to the timeline series almost seamlessly. In addition, these two models provided reasonable fits according to the mean absolute percentage error, MAPE %, criteria. Turkey's natural gas demand at the year 2030 was calculated as 76.8 billion m(3) using the linear model and 83.8 billion m(3) based on the logistic model. Consequently, found to be in better agreement with the official Turkish petroleum pipeline corporation (BOTAS) forecast, 76.4 billion m(3), than results published in the literature. (C) 2013 Elsevier Ltd. All rights reserved.Article Citation - WoS: 2Citation - Scopus: 2Trap Distribution in Agin5s8< Single Crystals: Thermoluminescence Study(Pergamon-elsevier Science Ltd, 2018) Delice, S.; Işık, Mehmet; Isik, M.; Gasanly, N. M.; Işık, Mehmet; Department of Electrical & Electronics Engineering; Department of Electrical & Electronics EngineeringDistribution of shallow trap levels in AgIn5S8 crystals has been investigated by thermoluminescence (TL) measurements performed below room temperature (10-300 K). One broad TL peak centered at 33 K was observed as constant heating rate of 0.2 K/s was employed for measurement. The peak shape analysis showed that the TL curve could consist of several individual overlapping TL peaks or existence of quasi-continuous distributed traps. Therefore, TL experiments were repeated for different stopping temperatures (T-stop) between 10 and 34 K with constant heating rate of 0.2 K/s to separate the overlapping TL peaks. The E-t vs T-stop indicated that crystal has quasi-continuously distributed traps having activation energies increasing from 13 to 41 meV. Heating rate effect on trapped charge carriers was also investigated by carrying out the TL. experiments with various heating rates between 0.2 and 0.6 K/s for better comprehension of characteristics of existed trap levels. Analyses indicated that the trap levels exhibited the properties of anomalous heating rate behavior which means the TL intensity and area under the TL peak increase with increasing heating rate.
