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Article Citation - WoS: 9Citation - Scopus: 10Spectroscopic Ellipsometry Investigation of Optical Properties of Β-ga2s3< Single Crystals(Elsevier Science Bv, 2018) Isik, M.; Gasanly, N. M.; Gasanova, L.Ga2S3 single crystals were studied by x-ray diffraction (XRD), energy dispersive spectroscopy and spectroscopic ellipsometry measurements. XRD pattern of the sample is well-matched with reported hexagonal structure of beta-Ga2S3 . The spectra of real and imaginary parts of complex dielectric function (epsilon = epsilon(1) + epsilon(2)) and refractive index (N = n + ik) were plotted in the 1.2-6.2 eV range according to results of ellipsometric data. The e 2 -spectrum and analyses of absorption coefficient pointed out that studied sample has band gap energy of 2.48 eV which is consistent with that of beta-Ga(2)S(3)2. Critical point energies of beta-Ga2S3 were also reported in the present study.Article Citation - WoS: 24Citation - Scopus: 22Spectroscopic Ellipsometry Study of Above-Band Gap Optical Constants of Layered Structured Tlgase2, Tlgas2 and Tlins2 Single Crystals(Elsevier Science Bv, 2012) Isik, M.; Gasanly, N. M.; Turan, R.Spectroscopic ellipsometry measurements on TlGaSe2, TlGaS2 and TlInS2 layered crystals were carried out on the layer-plane (0 0 1) surfaces, which are perpendicular to the optic axis c*, in the 1.2- 6.2 eV spectral range at room temperature. The real and imaginary parts of the pseudodielectric function as well as pseudorefractive index and pseudoextinction coefficient were found as a result of analysis of ellipsometric data. The structures of critical points in the above-band gap energy range have been characterized from the second derivative spectra of the pseudodielectric function. The analysis revealed four, five and three interband transition structures with critical point energies 2.75, 3.13, 3.72 and 4.45 eV (TlGaSe2), 3.03, 3.24, 3.53, 4.20 and 4.83eV (TlGaS2), and 3.50, 3.85 and 4.50 eV (TlInS2). For TlGaSe2 crystals, the determined critical point energies were assigned tentatively to interband transitions using the available electronic energy band structure. (c) 2012 Elsevier B.V. All rights reserved.Article Citation - WoS: 10Citation - Scopus: 10Ellipsometric Study of Optical Properties of Gasxse1-x< Layered Mixed Crystals(Elsevier Science Bv, 2016) Isik, Mehmet; Gasanly, NizamiSpectroscopic ellipsometry measurements were performed on GaSxSe1-x mixed crystals (0 <= x <= 1) in the 1.2-6.2 eV range. Spectral dependence of optical parameters; real and imaginary components of pseudodielectric function, pseudorefractive index and pseudoextinction coefficient were reported in the present work. Critical point (CP) analyses on second-energy derivative spectra of the pseudodielectric function were accomplished to find the interband transition energies. The revealed energy values were associated with each other taking into account the fact that band gap energy of mixed crystals rises with increase in sulfur content. The variation of CP energies with composition (x) was also plotted. Peaks in the spectra of studied optical parameters and CP energy values were observed to be shifted to higher energy values as sulfur concentration is increased in the mixed crystals. (C) 2016 Elsevier B.V. All rights reserved.Article Citation - WoS: 5Citation - Scopus: 5Optical properties of (Ga2Se3)0.75 - (Ga2S3)0.25 single crystals by spectroscopic ellipsometry(Elsevier Science Bv, 2019) Isik, M.; Gasanly, N. M.; Gasanova, L.Structural and optical properties of 75 mol % Ga2Se3 - 25 mol % Ga2S3 system of single crystals were investigated by experimental techniques of x-ray diffraction (XRD), energy dispersive spectroscopy, Raman spectroscopy and ellipsometry. XRD pattern indicated that the studied compound has crystalline nature with cubic structure. Vibrational modes in the crystal were revealed using Raman spectroscopy experiments in the 90-450 cm(-1) frequency range and nine modes were observed in the spectrum. Ellipsometry measurements were utilized in the 1.2-6.2 eV range to get spectral dependencies of optical constants; complex dielectric function, refractive index and extinction coefficient. Under the light of fundamental expressions and models, refractive index and extinction coefficient spectra were analyzed to get various optical parameters of the single crystal.
