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Book Part Fuel Cell Energy Conversion(Elsevier, 2025) Ercelik, M.; Nalbant, Y.; Çolpan, C.; Ismail, M.S.Fuel cells are electrochemical devices that convert the chemical energy of the fuel into electrical energy directly. There are different types of fuel cells, which can be categorized according to their electrolyte type and fuel used. The performance of these fuel cells mainly depends on the materials of their components and the manufacturing method. In this chapter, an introduction to different fuel cell types, the materials and manufacturing methods that can be used for fuel cells, and characterization techniques are first presented. Then, the basic concepts and equations for the thermodynamics and electrochemistry of fuel cells are given. The principles of fuel cell stack design including the calculations of pressure drop within a flow field are discussed. Energy and exergy analyses of integrated fuel cells systems are also presented. This chapter also covers several illustrative examples and a case study on the mathematical modeling of fuel cells. © 2025 Elsevier Inc. All rights are reserved, including those for text and data mining, AI training, and similar technologies.Article Citation - WoS: 11Citation - Scopus: 10Modeling of Claim Exceedances Over Random Thresholds for Related Insurance Portfolios(Elsevier, 2011) Eryilmaz, Serkan; Gebizlioglu, Omer L.; Tank, FatihLarge claims in an actuarial risk process are of special importance for the actuarial decision making about several issues like pricing of risks, determination of retention treaties and capital requirements for solvency. This paper presents a model about claim occurrences in an insurance portfolio that exceed the largest claim of another portfolio providing the same sort of insurance coverages. Two cases are taken into consideration: independent and identically distributed claims and exchangeable dependent claims in each of the portfolios. Copulas are used to model the dependence situations. Several theorems and examples are presented for the distributional properties and expected values of the critical quantities under concern. (C) 2011 Elsevier B.V. All rights reserved.Article Citation - WoS: 63Citation - Scopus: 80Hybrid Microgrid for Microfinance Institutions in Rural Areas - a Field Demonstration in West Africa(Elsevier, 2019) Ayodele, Esan; Misra, Sanjay; Damasevicius, Robertas; Maskeliunas, RytisWe present a hybrid energy microgrid optimization model for a microbank in a remote rural residential area. The model is based on the use of renewable (wind turbines & solar photovoltaic (PV)) and conventional (gasoline generators) energy sources and battery storage systems. We conducted a detailed assessment of a typical microbank's load, residential loads and energy resources in a village called Ajasse-Ipo in Kwara State, Nigeria. We performed the modeling of a hybrid microgrid system, followed by an economic analysis and sensitivity analysis to optimize the hybrid system design. We performed simulations based on the energy resources available (solar PV, wind, gasoline generator & battery energy storage system) to satisfy the energy demands of the microbank, while the excess energy was supplied to meet the demand of the community loads, i.e. water pumping machine and rural home lighting. The results obtained showed that the hybrid system comprising the solar PV/battery/diesel was most techno-economically viable with a Net Present Cost (NPC) and Cost of Energy (COE) of $468,914 and 0.667$/kWh, respectively. Comparing these results with those obtained using analytical methods, the solar PV, battery and converter sizes obtained were slightly higher than the optimal system configurations as produced by HOMER. The proposed hybrid energy system also allowed to achieve almost 50% reductions in CO2, CO, unburned hydrocarbons, particulate matter, SO2 & NO2. The system can be applicable for other rural regions in the developing countries with similar environmental conditions.Article Citation - WoS: 2Citation - Scopus: 2Investigations of Ph-Dependent Dynamic Properties of Ompg-16sl, an Outer Membrane Protein G Mutant by Atr-Ftir Spectroscopy(Elsevier, 2022) Yilmaz, Irem; Korkmaz, FilizIn this paper, the dynamic properties of outer membrane protein G mutant (OmpG-16SL) are investigated with ATR-FTIR spectroscopy. While OmpG-WT has 14 beta-strands in its structure, the mutant is designed to have 16 beta-strands with the intention of creating an enlarged pore. Loop L6 is elongated by introducing six residues, two of which are negatively charged. The solvent accessibility of the OmpG-16SL mutant is compared with WT and a previously reported mutant OmpG-16S by tracking the H-1/H-2 exchange kinetics in acidic and neutral buffer conditions. The exchange kinetics and dynamics in the fast and slow exchange phases are separately investigated using the 2DCOS technique, which enables the tracking of the structural changes at each phase of the exchange process. The results suggest that the mutant OmpG-16SL is equally exposed to buffer in both acidic and neutral pH conditions. Additionally, the time range in the fast phase is very short - one-tenth of that for WT - and most of the exchange is completed in this phase. This fast exchange within minutes is also indicative of the presence of highly flexible and/or unstructured regions. In all, the fast exchange rates independent of the buffer pH justify the assumption that there is an altered interaction among the charged residues, which leads to a steadily-open pore. The role of the side-chain interactions within the pore and between the loops involving the loop L6 is also discussed.Article Citation - WoS: 14Citation - Scopus: 18Traps distribution in sol-gel synthesized ZnO nanoparticles(Elsevier, 2019) Delice, S.; Isik, M.; Gasanly, N. M.The distribution of shallow traps within the sol-gel synthesized ZnO nanoparticles was investigated using thermoluminescence (TL) experiments in the 10-300 K temperature range. TL measurements presented two overlapped peaks around 110 and 155 K. The experimental technique based on radiating the nanoparticles at different temperatures (T-exc.) between 60 and 125 K was carried out to understand the trap distribution characteristics of peaks. It was observed that peak maximum temperature shifted to higher values and activation energy (E-t) increased as irradiating temperature was increased. The E-t vs. T-exc. presented that ZnO nanoparticles have quasi-continuously distributed traps possessing activation energies increasing from 80 to 171 meV. (C) 2019 Elsevier B.V. All rights reserved.Article Citation - WoS: 16Citation - Scopus: 26An Intelligent Fuzzy Object-Oriented Database Framework for Video Database Applications(Elsevier, 2009) Ozgur, Nezihe Burcu; Koyuncu, Murat; Yazici, AdnanVideo database applications call for flexible and powerful modeling and querying facilities, which require an integration or interaction between database and knowledge-based technologies. It is also necessary for many real life video database applications to incorporate uncertainty, which naturally occurs due to the complex and subjective semantic content of video data. In this study, firstly, we introduce a fuzzy conceptual data model to represent the semantic content of video data. For that purpose, UML (unified modeling language) is utilized and extended to represent uncertain information along with video specific properties. Secondly, we present an intelligent fuzzy object-oriented database framework for video database applications. The introduced fuzzy conceptual model is used in this framework, which provides modeling of complex and rich semantic content and knowledge of video data including uncertainty. Moreover, it supports various flexible queries including (fuzzy) semantic, temporal and (fuzzy) spatial queries, based on the video data model. We think that the presented conceptual data model and the framework can be used for any video database application. (C) 2009 Elsevier B.V. All rights reserved.Article Citation - WoS: 8Citation - Scopus: 8Defect Characterization in Bi12geo20< Single Crystals by Thermoluminescence(Elsevier, 2021) Delice, S.; Isik, M.; Sarigul, N.; Gasanly, N. M.Bi12GeO20 single crystal grown by Czochralski method was investigated in terms of thermoluminescence (TL) properties. TL experiments were performed for various heating rates between 1 and 6 K/s in the temperature region of 300-675 K. One TL peak with peak maximum temperature of 557 K was observed in the TL spectrum as constant heating rate of 1 K/s was employed. Curve fitting, initial rise and variable heating rate methods were applied to calculate the activation energy of trap level corresponding to this TL peak. Analyses resulted in a presence of one trap center having mean activation energy of 0.78 eV. Heating rate characteristics of revealed trap center was also explored and theoretically well-known behavior that TL intensity decreases and peak maximum temperature increases with heating rates was observed for the trap level. Distribution of trapping levels was studied by thermally cleaning process for different T-stop between 425 and 525 K. Quasi-continuously distributed trapping levels were revealed with mean activation energies ranging from 0.78 to 1.26 eV. Moreover, absorption analysis revealed an optical transition taking place between a defect level and conduction band with an energy difference of 2.51 eV. These results are in good agreement for the presence of intrinsic defects above valence band in Bi12GeO20 crystals.Article Citation - WoS: 4Citation - Scopus: 5Thermoluminescence characteristics of GaSe and Ga2Se3 single crystals(Elsevier, 2022) Isik, M.; Sarigul, N.; Gasanly, N. M.GaSe and Ga2Se3 are semiconducting compounds formed from same constituent elements. These compounds have been attractive due to their optoelectronic and photovoltaic applications. Defects take remarkable attention since they affect quality of semiconductor devices. In the present paper, deep defect centers in GaSe and Ga2Se3 single crystals grown by Bridgman method were reported from the analyses of thermoluminescence measurements performed in the 350-675 K range. Experimental TL curves of GaSe and Ga2Se3 single crystals presented one and two overlapped peaks, respectively. The applied curve fitting and initial rise techniques were in good agreement about trap activation energies of 0.83 eV for GaSe, 0.96 and 1.24 eV for Ga2Se3 crystals. Crystalline structural properties of the grown single crystals were also investigated by x-ray diffraction measurements. The peaks observed in XRD patterns of the GaSe and Ga2Se3 crystals were well-consistent with hexagonal and zinc blende structures, respectively.Article Citation - WoS: 17Citation - Scopus: 18Investigation of Band Gap Energy Versus Temperature for Sns 2 Thin Films Grown by Rf-Magnetron Sputtering(Elsevier, 2020) Isik, M.; Gullu, H. H.; Terlemezoglu, M.; Surucu, O. Bayrakli; Parlak, M.; Gasanly, N. M.[No Abstract Available]Article Citation - WoS: 11Citation - Scopus: 12Structural and Temperature-Tuned Optical Characteristics of Bi12geo20< Sillenite Crystals(Elsevier, 2020) Delice, S.; Isik, M.; Gasanly, N. M.; Darvishov, N. H.; Bagiev, V. E.Sillenite compounds exhibit unique photorefractive and electro-optic characteristics providing attractiveness to these materials in various optoelectronic applications. The present paper aims at investigating one of the members of this family. Structural and optical characteristics of Bi12GeO20 (BGO) were studied by means of x-ray diffraction, Raman spectroscopy and temperature-dependent transmittance measurements. Obtained transmission curves in the wavelength range of 350-1100 nm and at different applied temperatures between 10 and 300 K were employed to find out the absorption coefficient dependence on the photon energy. Tauc relation revealed the presence of an energy gap of 2.49 eV at room temperature. Extension of energy gap up to 2.57 eV due to decreased temperature down to 10 K was deduced by the analysis. In order to have reliable results, the energy gap value was corroborated by utilizing derivative spectral method and well consistency between both methods was indicated. Energy gap change with temperature was also discussed in the study using an empirical formula developed by Varshni. Energy gap at absolute zero and rate of band gap alteration with temperature were determined as 2.57 eV and -2.4 x 10(-4) eV K (- 1), respectively. Taking into account the previously reported studies on investigation of band gap characteristics of BGO, intrinsic Bi-Ge(3+) + V-O(+) defect could be responsible for the revealed energy value of 2.49 eV which is much lower than reported band gap energy of similar to 3.2 eV.
