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Article Citation - WoS: 3Citation - Scopus: 4Experimental Evaluation of Surveillance Capsule Assemblies for Life Assessment of Chasnupp Unit-1 Reactor Pressure Vessel(Pergamon-elsevier Science Ltd, 2016) Sahin, Sumer; Saeed, AsimNeutron flux and energy spectrum were determined at the surface of three in-vessel Surveillance Capsule Assemblies (SCAs) removed from CHASNUPP Unit-1 after 2nd, 4th, and 9th fuel cycles for the life assessment of reactor pressure vessel belt line region. Dosimetry data were measured from radiometric sensors irradiated in base material section of SCAs. Fast neutron flux (E > 1.0 MeV) was best estimated at the surface of three SCAs corresponding to the center of C-1 core using the least square method by employing LSL-M2 package. These results were compared with fast neutron flux calculated using DOT3.5 code and both results are within good agreement of +/- 20% acceptance criteria as described in Regulatory Guide 1.190. Therefore, calculational model was validated by dosimetry evaluation and these results can be used in the life assessment of CHASNUPP Unit-1 pressure vessel belt line region. (C) 2015 Elsevier Ltd. All rights reserved.Article Citation - WoS: 5Citation - Scopus: 52-D Digital Filter Realization Without Overflow Oscillations(Pergamon-elsevier Science Ltd, 2013) Singh, VimalA novel criterion for the elimination of overflow oscillations in 2-D state-space digital filters described by the Roesser model employing two's complement overflow arithmetic is presented. The criterion takes the form of linear matrix inequality (LMI) and, hence, is computationally tractable. The criterion is a generalization and improvement over an earlier criterion. An example shows the effectiveness of the new criterion. (C) 2012 Elsevier Ltd. All rights reserved.Article Citation - WoS: 52Citation - Scopus: 60Comparative Study of Pv/Pem Fuel Cell Hybrid Energy System Based on Methanol and Water Electrolysis(Pergamon-elsevier Science Ltd, 2019) Budak, Yagmur; Devrim, YilserIn this study, we investigated the comparative analysis of a solar-fuel cell hybrid system based on water and methanol electrolysis. The proposed system comprises PV, electrolyzer and proton exchange membrane fuel cell (PEMFC). The hybrid system is designed to supply the hydrogen (H-2) needed of the PEMFC system and also to fulfill the H-2 requirement of other applications. The actual data of solar irradiation of Izmir, Turkey are used in the simulation. The methanol and water electrolyzers were designed for 1.2 kW PEMFC H-2 demand which were met a house-hold energy requirement. Analyzes show that the use of the methanol electrolyzer can produce 27% more H-2 than the water electrolyzer. According to the study, it was determined that the methanol-based hybrid system offered a viable option for self-sustaining in household application.Article Citation - WoS: 21Citation - Scopus: 27LIFE hybrid reactor as reactor grade plutonium burner(Pergamon-elsevier Science Ltd, 2012) Sahin, Sumer; Sahin, Haci Mehmet; Acir, AdemThe early version of the conceptual modified design of the Laser Inertial Confinement Fusion Fission Energy (LIFE) engine consists of a spherical fusion chamber of 5 m diameter, surrounded by a multi-layered blanket. The first wall is made of 2 cm thick ODS and followed by a Li17Pb83 zone (2 cm), acting as neutron multiplier, tritium breeding and front coolant zone. It is separated by an ODS layer (2 cm) from the FLIBE molten salt zone (50 cm), containing fissionable fuel. A 3rd ODS layer (2 cm) separates the molten salt zone on the right side from the graphite reflector (30 cm). Calculations have been conducted for a constant fusion driver power of 500 MWth, in S-8-P-3 approximation using 238-neutron groups. Reactor grade (RG) plutonium carbide fuel in form of TRISO particles with volume fractions of 2%, 3%, 4%, 5% and 6% have been dispersed homogenously in the FLIBE coolant. Tritium breeding ratio (TBR) values per incident fusion neutron for the above cited cases start with TBR = 1.35, 1.52, 1.73, 2.02 and 2.47, respectively. With the depletion of fissionable RG-Pu isotopes, TBR decreases gradually. At startup, higher fissionable fuel content in the molten salt leads to higher blanket energy multiplication, namely M-0 = 3.8, 5.5, 7.7, 10.8 and 15.4 with 2%, 3%, 4%, 5% and 6% TRISO volume fraction, respectively. Calculations have led to very high burn up values (>400,000 MD.D/MT). TRISO particles can withstand such high burn ups. Such high burn ups would lead to drastic reduction of final nuclear waste per unit energy production. (C) 2012 Elsevier Ltd. All rights reserved.Article Citation - WoS: 11Citation - Scopus: 13Characterization and Fuel Cell Performance of Divinylbenzene Crosslinked Phosphoric Acid Doped Membranes Based on 4-Vinylpyridine Grafting Onto Poly(ethylene-Co Films(Pergamon-elsevier Science Ltd, 2018) Guler, Enver; Sadeghi, Sahl; Gursel, Selmiye AlkanThe effect of divinylbenzene (DVB) as crosslinker on the graft polymerization of 4-vinylpyridine (4VP) from poly(ethylene-co-tetrafluoroethylene) (ETFE) films was studied. The resulted films were doped with phosphoric acid (PA) and characterized for mechanical, surface, thermal properties, and fuel cell performance. The crosslinked membrane obtained from grafting a mixture of 4VP with 1% DVB improved the polymerization kinetics and resulted in about 50% graft level depending on graft conditions. The crosslinked membranes were also found to have better mechanical properties compared to its non-crosslinked counterpart. The resulted membrane exhibited proton conductivity as high as 75 mS/cm under 50% relative humidity (RH) at 120 degrees C, besides almost doubling the power output of fuel cell compared to a non-crosslinked membrane. To the best of our knowledge, DVB crosslinked 4VP based ETFE membranes were, for the first time, tested in practical fuel cell test station correlating their performance to operating temperature. Furthermore, surface properties of produced membranes were additionally correlated to the degree of crosslinking. Humidity dependence is less pronounced in the produced membranes resulting in strong potential for testing at intermediate temperature (80-120 degrees C) polymer electrolyte membrane fuel cells. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Article Citation - WoS: 5Citation - Scopus: 6A new frequency-domain criterion for elimination of limit cycles in fixed-point state-space digital filters using saturation arithmetic(Pergamon-elsevier Science Ltd, 2007) Singh, VimalIn [Singh V. Elimination of overflow oscillations in fixed-point state-space digital filters using saturation arithmetic. IEEE Trans Circ Syst 1990;37(6):814-8], a frequency-domain criterion for the suppression of limit cycles in fixed-point state-space digital filters using saturation overflow arithmetic was presented. The passivity property owing to the presence of multiple saturation nonlinearities was exploited therein. In the present paper, a new notion of passivity, namely, that involving the state variables is considered, thereby arriving at an entirely new frequency-domain criterion for the suppression of limit cycles in such filters. (C) 2006 Elsevier Ltd. All rights reserved.Article Citation - WoS: 137Citation - Scopus: 173Re-Usage of Waste Foundry Sand in High-Strength Concrete(Pergamon-elsevier Science Ltd, 2010) Guney, Yucel; Sari, Yasin Dursun; Yalcin, Muhsin; Tuncan, Ahmet; Donmez, SenayiIn this study, the potential re-use of waste foundry sand in high-strength concrete production was investigated. The natural fine sand is replaced with waste foundry sand (0%, 5%, 10%, and 15%). The findings from a series of test program has shown reduction in compressive and tensile strengths, and the elasticity modulus which is directly related to waste foundry inclusion in concrete. Nevertheless the concrete with 10% waste foundry sand exhibits almost similar results to that of the control one. The slump and the workability of the fresh concrete decreases with the increase of the waste foundry sand ratio. Although the freezing and thawing significantly reduces the mechanical and physical properties of the concrete. The obtained results satisfies the acceptable limits set by the American Concrete Institute (Ad). (C) 2010 Elsevier Ltd. All rights reserved.Article Citation - WoS: 14Citation - Scopus: 14The Number of Failed Components in Series-Parallel System and Its Application To Optimal Design(Pergamon-elsevier Science Ltd, 2020) Eryilmaz, Serkan; Ozkurt, Fatma Yerlikaya; Erkan, T. ErmanThe number of components that are failed at the time of system failure is a useful quantity since it gives an idea of how many spares should be available to replace all failed components upon the system failure. In this paper, the number of failed components is considered at subsystem and system levels for the series-parallel system that consists of K subsystems. In particular, the joint behavior of the number of failed components in each subsystem is studied when each subsystem has identical components and different subsystems have different types of components. The results are then used to find the optimal number of components in each subsystem by minimizing an expected cost per unit of time upon the system failure.Article Citation - WoS: 12Citation - Scopus: 16The Laplace Transform on Isolated Time Scales(Pergamon-elsevier Science Ltd, 2010) Bohner, Martin; Guseinov, Gusein Sh.Starting with a general definition of the Laplace transform on arbitrary time scales, we specify the Laplace transform on isolated time scales, prove several properties of the Laplace transform in this case, and establish a formula for the inverse Laplace transform. The concept of convolution is considered in more detail by proving the convolution theorem and a discrete analogue of the classical theorem of Titchmarsh for the usual continuous convolution. (C) 2010 Elsevier Ltd. All rights reserved.Article Citation - WoS: 14Citation - Scopus: 19Electrochemistry of nickel(II) complexes with N,N'-bis(3,5-di-tert-butylsalicylidene)polymethylenediamines(Pergamon-elsevier Science Ltd, 2005) Özalp-Yaman, S; Kasumov, VT; Önal, AMThe electrochemical oxidation of several N,N'-polymethylenebis(3,5-di-tert- butylsalicylaldiminato)nickel(II) complexes, Ni(L-x), has been studied by cyclic voltammetry and in situ UV-Vis spectroscopy in DMF Cyclic voltammograms of Ni(L-x) (x = 1-4) complexes displayed two-step oxidation processes under nitrogen gas atmosphere. The first oxidation peak potentials of all the Ni(II) complexes corresponds to the reversible one-electron oxidation process of the metal center, yielding Ni(III) species. EPR spectrum of the electrolysis solution was recorded after one electron transfer at liquid nitrogen temperature also confirms the formation of [Ni-III (L-3)](+) species (g(x) > g(y) > g(z)) with a (2)A(1)(d(z)(2))(1) ground state. Upon addition of pyridine to one electron oxidised solutions a new penta coordinated species, [Ni-III(L-3)Py](+) (g(perpendicular to) > g(parallel to), a(parallel to)(N-14) = 8 G), was produced. The second oxidation peak of the complexes was assigned as the ligand based oxidation, generating a coordinated phenoxy radical species. (c) 2005 Elsevier Ltd. All rights reserved.
