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  • Article
    Citation - WoS: 55
    Citation - Scopus: 61
    Encoding the Future: Successful Processing of Intentions Engages Predictive Brain Networks
    (Academic Press inc Elsevier Science, 2010) Poppenk, J.; Moscovitch, M.; McIntosh, A. R.; Ozcelik, E.; Craik, F. I. M.
    Evidence from cognitive, patient and neuroimaging research indicates that "remembering to remember" intentions, i.e., prospective memory (PM) retrieval, requires both general memory systems involving the medial temporal lobes and an executive system involving rostral PFC (BA 10). However, it is not known how prospective memories are initially formed. Using fMRI, we investigated whether brain activity during encoding Of future intentions and present actions differentially predicted later memory for those same intentions (PM) and actions (retrospective memory). We identified two significant patterns of neural activity: a network linked to overall memory and another linked specifically to PM. While overall memory success was predicted by temporal lobe activations that included the hippocampus, PM success was also uniquely predicted by activations in additional regions, including left rostrolateral PFC and the right parahippocampal gyrus. This finding extends the role of these structures to the formation of individual intentions. It also provides the first evidence that PM encoding, like PM retrieval, is supported by both a common episodic memory network and an executive network specifically recruited by future-oriented processing. (C) 2009 Elsevier Inc. All rights reserved.
  • Article
    Citation - WoS: 8
    Citation - Scopus: 9
    A New Approach To the Existence and Uniqueness of Solutions for A Class of Nonlinear Q-Fractional Boundary Value Problems
    (Institute of Applied Mathematics of Baku State University, 2025) Karapinar, E.; Sevinik-Adiguzel, R.; Aksoy, U.; Erhan, I. M.
    The object of this study is a boundary value problem associated with a q-difference equation of fractional order. The existence and uniqueness of a solution in the case of multi-point boundary conditions is studied from the viewpoint of fixed point theory. An integral equation equivalent to the boundary value problem is derived and the fixed points of the related integral operator are investigated by using a contractive condition involving a comparison function. The Ulam-Hyers stability of the problem is also discussed. Theoretical results are followed by a particular example.
  • Article
    Citation - WoS: 49
    Citation - Scopus: 55
    Synthesis of Α-fe2o3< Heterogeneous Composites by the Sol-Gel Process and Their Photocatalytic Activity
    (Elsevier Science Sa, 2020) Bouziani, Asmae; Park, Jongee; Ozturk, Abdullah
    alpha-Fe2O3/TiO2 heterogeneous composites were synthesized by the sol-gel process to increase the photocatalytic activity of TiO2. The structural, morphological, and optical characteristics of the composites were determined by X-ray diffraction, scanning electron microscope, and UV-vis diffuse reflectance spectroscopy. Results revealed that the incorporation of alpha-Fe2O3 to TiO2 widened the visible light absorption ability of TiO2. It was realized that the calcination temperature plays a crucial role in morphology development hence photocatalytic activity of the alpha-Fe2O3/TiO2 heterogeneous composites. The photocatalytic activity of the composites calcined at various temperatures was evaluated for the degradation of Methylene Blue (MB) and Phenol (Ph) in aqueous medium under UV and sun-like illuminations. The alpha-Fe2O3-TiO2 composites exhibits superior photocatalytic efficiency to degrade both MB and Ph as compared to both pristine TiO2 and pristine alpha-Fe2O3 under sun-like illumination. The alpha-Fe2O3/TiO2 composite degraded approximately 90 % of MB and 50 % of Ph in 180 min sun-like illumination. Improvement in photocatalytic activity is attributed to the separation of photogenerated electron/hole pairs through the interaction of alpha-Fe(2)O(3 )and TiO2.
  • Article
    Citation - WoS: 19
    Citation - Scopus: 21
    Mean Instantaneous Performance of a System With Weighted Components That Have Arbitrarily Distributed Lifetimes
    (Elsevier Sci Ltd, 2013) Eryilmaz, Serkan
    There are various systems consisting of components which may have different contribution to the performance of the system. Such systems can be modeled systems with weighted components. In this paper, we study the mean instantaneous performance of this type of systems after successive component failures. The mean instantaneous performance is a useful characteristic to take preventive action about the system. In particular, we obtain explicit expressions for the mean instantaneous performance of a system with weighted components that have arbitrarily distributed lifetimes. We illustrate the results when the lifetime distribution of components follow proportional hazard model. Some further results are also presented for the components having exponential lifetime distribution. (C) 2013 Elsevier Ltd. All rights reserved.
  • Article
    Citation - WoS: 5
    Citation - Scopus: 6
    Parallel and Consecutive-k-out-of-n< Systems Under Stochastic Deterioration
    (Elsevier Science inc, 2014) Eryilmaz, Serkan
    In this paper, we study parallel and consecutive-k-out-of-n:F systems consisting of components which are subject to random deterioration with time. The random deterioration in resistance of a component is defined through a stochastic process. We obtain lifetime distribution of a parallel system via classical probabilistic techniques. The lifetime distribution of a consecutive-k-out-of-n:F system is derived using the lifetime distribution of parallel systems and the concept of maximal signature. We also study the optimal replacement time for a parallel system. We present illustrative computational results using MATHCAD. (C) 2013 Elsevier Inc. All rights reserved.
  • Article
    Citation - WoS: 4
    Citation - Scopus: 6
    A Conceptual Design of Smart Management System for Flooding Disaster
    (Mdpi, 2021) Ibrahim, Thaer; Mishra, Alok
    Disasters pose a real threat to the lives and property of citizens; therefore, it is necessary to reduce their impact to the minimum possible. In order to achieve this goal, a framework for enhancing the current disaster management system was proposed, called the smart disaster management system. The smart aspect of this system is due to the application of the principles of information and communication technology, especially the Internet of Things. All participants and activities of the proposed system were clarified by preparing a conceptual design by using The Unified Modeling Language diagrams. This effort was made to overcome the lack of citizens' readiness towards the use of information and communication technology as well as increase their readiness towards disasters. This study aims to develop conceptual design that can facilitate in development of smart management system for flooding disaster. This will assist in the design process of the Internet of Things systems in this regard.
  • Article
    Citation - WoS: 20
    Citation - Scopus: 21
    Electrochemical Behaviour and Electrochemical Polymerization of Fluoro-Substituted Anilines
    (Wiley, 2002) Cihaner, A; Önal, AM
    The electrochemical behaviour of three fluoro-substituted aniline monomers, 2-fluoroaniline (2FAN), 3-fluoroaniline (3FAN) and 4-fluoroaniline (4FAN), was investigated in aqueous acidic and organic media by means of cyclic voltammetry (CV) studies. Constant potential electrolysis (CPE) of the monomers in acetonitrile-water mixture (1: 1 by volume) using NaClO4 as supporting electrolyte yielded soluble polymers. The mechanism of electrochemical polymerization was investigated using in situ electron spin resonance (ESR) and in situ UV-VIS spectroscopic techniques for one of the monomers (4FAN). Both CV and in situ LTV-VIS measurements indicated that the polymers obtained are in the emeraldine base form. In situ ESR studies indicated that electrochemical polymerization involves a radical-cation as an intermediate. Characterization of polymer products have been carried out using FTIR and NMR spectroscopic techniques, and thermal behaviour was studied using differential scanning calorimetry (DSC). It was found that conductivity can be imparted to assynthesized polyfluoroanilines via iodine doping. (C) 2002 Society of Chemical Industry.
  • Article
    Citation - WoS: 9
    Citation - Scopus: 9
    Urinalysis of Individuals With Renal Hyperfiltration Using Atr-Ftir Spectroscopy
    (Nature Portfolio, 2022) Kurultak, Ilhan; Sarigul, Neslihan; Kodal, Nil Su; Korkmaz, Filiz
    Abnormal increased glomerular filtration rate (GFR), otherwise known as renal hyperfiltration (RHf), is associated with an increased risk of chronic kidney disease and cardiovascular mortality. Although it is not considered as a disease alone in medicine today, early detection of RHf is essential to reducing risk in a timely manner. However, detecting RHf is a challenge since it does not have a practical biochemical marker that can be followed or quantified. In this study, we tested the ability of ATR-FTIR spectroscopy to distinguish 17 individuals with RHf (hyperfiltraters; RHf (+)), from 20 who have normal GFR (normofiltraters; RHf(-)), using urine samples. Spectra collected from hyperfiltraters were significantly different from the control group at positions 1621, 1390, 1346, 933 and 783/cm. Intensity changes at these positions could be followed directly from the absorbance spectra without the need for pre-processing. They were tentatively attributed to urea, citrate, creatinine, phosphate groups, and uric acid, respectively. Using principal component analysis (PCA), major peaks of the second derivative forms for the classification of two groups were determined. Peaks at 1540, 1492, 1390, 1200, 1000 and 840/cm were significantly different between the two groups. Statistical analysis showed that the spectra of normofiltraters are similar; however, those of hyperfiltraters show diversity at multiple positions that can be observed both from the absorbance spectra and the second derivative profiles. This observation implies that RHf can simultaneously affect the excretion of many substances, and that a spectroscopic analysis of urine can be used as a rapid and non-invasive pre-screening tool.
  • Article
    Citation - WoS: 4
    Citation - Scopus: 4
    Growth and Optical Characterization of Sn0.6sb0.4< Layer Single Crystals for Optoelectronic Applications
    (Elsevier Sci Ltd, 2022) Bektas, T.; Terlemezoglu, M.; Surucu, O.; Isik, M.; Parlak, M.
    SnSe compound is an attractive semiconductor material due to its usage in photovoltaic applications. The sub-stitution of Sb in the SnSe compound presents a remarkable advantage especially in point of tuning optical characteristics. The present paper reports the structural and optical properties of Sn1-xSbxSe (x = 0.4) layered single crystals grown by the vertical Bridgman method. To the best of our knowledge, this work is the first investigation of the Sn0.6Sb0.4Se crystal grown with the vertical Bridgman technique. X-ray diffraction (XRD) pattern of the grown crystal indicated the well crystalline structure of the grown crystals. Lattice strain and interplanar spacing of the crystal structure were determined using the XRD pattern. Scanning electron micro-scope images allowed to the observation of the layer crystal structure. The layer crystalline structure shows 2D material properties and provides 2D applications. Optical properties were revealed by carrying out Raman, ellipsometry and transmission measurements. Raman modes, refractive index, extinction coefficient, and dielectric spectra, band gap energy of the crystal were presented throughout the paper. The obtained results indicated that Sn1-xSbxSe (x = 0.4) layer single crystals may be an alternative potential for photovoltaic and optoelectronic applications.
  • Article
    Citation - WoS: 24
    Citation - Scopus: 24
    Complete Dehydrogenation of Hydrazine Borane on Manganese Oxide Nanorod-Supported Ni@ir Core-Shell Nanoparticles
    (Amer Chemical Soc, 2020) Yurderi, Mehmet; Top, Tuba; Bulut, Ahmet; Kanberoglu, Gulsah Saydan; Kaya, Murat; Zahmakiran, Mehmet
    Hydrazine borane (HB; N2H4BH3) has been considered to be one of the most promising solid chemical hydrogen storage materials owing to its high hydrogen capacity and stability under ambient conditions. Despite that, the high purity of hydrogen production from the complete dehydrogenation of HB stands as a major problem that needs to be solved for the convenient use of HB in on-demand hydrogen production systems. In this study, we describe the development of a new catalytic material comprised of bimetallic Ni@Ir core-shell nanoparticles (NPs) supported on OMS-2-type manganese oxide octahedral molecular sieve nanorods (Ni@Ir/OMS-2), which can reproducibly be prepared by following a synthesis protocol including (i) the oleylamine-mediated preparation of colloidal Ni@Ir NPs and (ii) wet impregnation of these ex situ synthesized Ni@Ir NPs onto the OMS-2 surface. The characterization of Ni@Ir/OMS-2 has been done by using various spectroscopic and visualization techniques, and their results have revealed the formation of well-dispersed Ni@Ir core-shell NPs on the surface of OMS-2. The catalytic employment of Ni@Ir/OMS-2 in the dehydrogenation of HB showed that Ni-0.22@Ir-0.78/OMS-2 exhibited high dehydrogenation selectivity (>99%) at complete conversion with a turnover frequency (TOF) value of 2590 h(-1) at 323 K, which is the highest activity value among all reported catalysts for the complete dehydrogenation of HB. Furthermore, the Ni-0.22@Ir-0.78/OMS-2 catalyst enables facile recovery and high stability against agglomeration and leaching, which make it a reusable catalyst in the complete dehydrogenation of HB. The studies reported herein also include the collection of wealthy kinetic data to determine the activation parameters for Ni-0.22@Ir-0.78/OMS-2-catalyzed dehydrogenation of HB.