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Article Citation - WoS: 8Citation - Scopus: 9Reliability-Based Evaluation of Hybrid Wind-Solar Energy System(Sage Publications Ltd, 2021) Devrim, Yilser; Eryilmaz, SerkanIn this article, a hybrid system that consists of a specified number of wind turbines and solar modules is considered. In particular, the system is modeled using weightedk-out-of-nsystem which is also known as a threshold system in reliability literature. The system under concern consists ofn1identical wind turbines andn2identical solar modules, and each turbine and module can be in one of two states as working or failed. The probability that the entire hybrid system withn=n1+n2components produces power at minimum levelkis computed and evaluated. The importance of single-wind turbine and solar module is also calculated to measure which renewable energy component is more critical and important. Extensive numerical results that are based on real data set are presented to illustrate the model.Article Citation - WoS: 31Citation - Scopus: 35Preparation and Testing of Nafion/Titanium Dioxide Nanocomposite Membrane Electrode Assembly by Ultrasonic Coating Technique(Wiley-blackwell, 2014) Devrim, Yilser; Alemdaroğlu Temel, Mine; Alemdaroğlu Temel, MineMembrane electrode assemblies with Nafion/nanosize titanium dioxide (TiO2) composite membranes were manufactured with a novel ultrasonic-spray technique (UST) and tested in proton exchange membrane fuel cell (PEMFC). The structures of the membranes were investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), and thermogravimetric analysis. The composite membranes gained good thermal resistance with insertion of TiO2. The SEM and XRD techniques have proved the uniform and homogeneous distribution of TiO2 and the consequent enhancement of crystalline character of these membranes. The existence of nanometer size TiO2 has improved the thermal resistance, water uptake, and proton conductivity of composite membranes. Gas diffusion electrodes were fabricated by UST. Catalyst loading was 0.4 (mg Pt) cm(-2) for both anode and cathode sides. The membranes were tested in a single cell with a 5 cm(2) active area operating at the temperature range of 70 degrees C to 110 degrees C and in humidified under 50% relative humidity (RH) conditions. Single PEMFC tests performed at different operating temperatures indicated that Nafion/TiO2 composite membrane is more stable and also performed better than Nafion membranes. The results show that Nafion/TiO2 is a promising membrane material for possible use in PEMFC at higher temperature. (c) 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40541.Article Citation - WoS: 2Citation - Scopus: 2Performance Assessment of Anion Exchange Electrolyzer With PBI-BASED Membrane Through 0-D Modeling(Elsevier Ltd, 2025) Celebi, Ceren; Colpan, C. Ozgur; Devrim, YilserAnion exchange membrane (AEM) water electrolysis is emerging as a promising method for the sustainable production of hydrogen. A key advantage lies in the potential for cost-effective hydrogen production by substituting expensive noble metal electrocatalysts with affordable transition metals. This work presents a 0-D mathematical model for evaluating the performance of AEMWEs, with a particular focus on polybenzimidazole (PBI)-based membranes, which are renowned for their high thermal stability, chemical resistance and excellent conductivity in alkaline media. The objective of the model is to predict the behavior of membranes in AEMWE systems, and it has been employed to evaluate the performance of a range of PBI membranes. To ensure precision, the values were meticulously selected from the literature, in accordance with the experimental conditions. Furthermore, IR-corrected validation was incorporated to isolate the impact of membrane conductivity on performance, thereby facilitating a dependable assessment of PBI membranes under diverse conditions. The model considers the effects of electrolyte resistance and bubble formation on cell voltage behavior. The efficiency was evaluated on the basis of the higher heating value (HHV). The findings demonstrate that one membrane exhibits consistent efficiency across a broad temperature range (40-90 degrees C), whereas the other displays notable variability under diverse conditions. In particular, the efficiency of the electrolyzer is significantly enhanced by the use of thinner membranes and higher temperatures. The highest efficiencies obtained were 83.9% and 79.8% for 25 mu m and 50 mu m PBI/Polystyrene membrane under the operating conditions of 1 M KOH solution at 80 degrees C and current density of 2 A/cm2. This study aims to provide valuable information on the performance of PBI membranes through a zero-dimensional model validated by experimental data.Article Citation - WoS: 83Citation - Scopus: 92Investigation of Micro-Combined Heat and Power Application of Pem Fuel Cell Systems(Pergamon-elsevier Science Ltd, 2018) Budak, Yagmur; Devrim, YilserThis study focuses on the investigating different working temperature effect on Proton Exchange Membrane Fuel Cell (PEMFC) stack performance, micro-combined heat and power (mu CHP) application and their simple payback time. LT-PEMFC and HT-PEMFC short stacks were designed and analyzed for 480 W net power output. Liquid cooling method was choosing for the cooling the PEMFC stacks due for efficient mu CHP applications. The experimental studies were carried out by using 13 cells HT-PEMFC and 6 cells LT-PEMFC short stacks and design parameters were determined. 1.2 kW PEMFCs with mu CHP systems with different working temperature were designed based on electrochemical data obtained from short stack testing. The proposed PEMFC systems can supply electric and hot water. The highest mu CHP system efficiency was calculated with a value of 92% for HT-PEMFC based system. The corresponding electrical and thermal efficiencies are 48% and 44%, respectively. In this study, two important parameters have been analyzing: efficiency and simple payback time. By using mu CHP application, both natural gas and H-2 based PEMFC systems SPT values are reduced.Conference Object Citation - WoS: 98Citation - Scopus: 102Experimental Investigation of Co Tolerance in High Temperature Pem Fuel Cells(Pergamon-elsevier Science Ltd, 2018) Devrim, Yilser; Albostan, Ayhan; Devrim, HuseyinIn the present work, the effect of operating a high temperature proton exchange membrane fuel cell (HT-PEMFC) with different reactant gases has been investigated throughout performance tests. Also, the effects of temperature on the performance of a HT-PEMFC were analyzed at varying temperatures, ranging from 140 degrees C to 200 degrees C. Increasing the operating temperature of the cell increases the performance of the HT-PEMFC. The optimum operating temperature was determined to be 160 degrees C due to the deformations occurring in the cell components at high working temperatures. To investigate the effects of CO on the performance of HT-PEMFC, the CO concentration ranged from 1 to 5 vol %. The current density at 0.6 V decreases from 0.33 A/cm(2) for H-2 to 0.31 A/cm(2) for H-2 containing 1 vol % CO, to 0.29 A/cm(2) for 3 vol % CO, and 0.25 A/cm(2) for 5 vol % CO, respectively. The experimental results show that the presence of 25 vol % CO2 or N-2 has only a dilution effect and therefore, there is a minor impact on the HT-PEMFC performance. However, the addition of CO to H-2/N-2 or H-2/CO2 mixtures increased the performance loss. After longterm performance test for 500 h, the observed voltage drop at constant current density was obtained as similar to 14.8% for H-2/CO2/CO (75/22/3) mixture. The overall results suggest that the anode side gas mixture with up to 5 vol % CO can be supplied to the HT-PEMFC stack directly from the reformer. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Article Citation - WoS: 5Citation - Scopus: 5The Design and Techno-Economic Evaluation of Wind Energy Integrated On-Site Hydrogen Fueling Stations for Different Electrolyzer Technologies(Pergamon-Elsevier Science Ltd, 2025) Devrim, Yilser; Ozturk, Reyhan AtabayHydrogen refueling stations (HRS) integrated with renewable energy sources present a pivotal solution for achieving sustainable transportation systems. This study focuses on the design and techno-economic analysis of a grid-connected, on-site hydrogen production HRS powered by wind energy, incorporating various electrolyzer technologies. The selected location for the HRS installation is & Ccedil;anakkale, Turkey, where daily wind speed data has been utilized for performance calculations. The proposed HRS system integrates a wind turbine (WT) with three different electrolyzer technologies: alkaline electrolyzer (AEL), proton exchange membrane electrolyzer (PEMEL), and anion exchange membrane electrolyzer (AEMEL). A comprehensive techno-economic analysis was conducted to evaluate the system's performance, considering factors such as initial capital investment, installation, operation, and replacement costs. The results of the analysis reveal that the levelized cost of hydrogen (LCOH) varies between 9.0 and 18.7 /kg H2, depending on the type of electrolyzer technology used and the daily hydrogen refueling capacity. Notably, increasing the hydrogen refueling capacity significantly reduces production costs. The minimum LCOH of 9.0 /kg H2, achieved under a 20-year investment scenario, corresponds to a refueling capacity of 250 kg H2/day when utilizing the AEL-integrated HRS system. The findings underscore the economic feasibility of on-site hydrogen refueling stations powered by wind energy and utilizing AEL, AEMEL, and PEMEL systems. Among the systems analyzed, the AEL-based HRS system demonstrated the highest return on investment (ROI) of 13.02 % and the shortest payback period (PBP) of 7.7 years, highlighting its economic performance. This study provides valuable insights into the integration of renewable energy with hydrogen production infrastructure, emphasizing the potential of wind-powered HRS systems to advance the sustainability and economic viability of hydrogen-based transportation solutions.Conference Object Citation - WoS: 76Citation - Scopus: 92Modeling and Simulation of a Hybrid Photovoltaic (pv) Module-Electrolyzer Fuel Cell System for Micro-Cogeneration Applications(Pergamon-elsevier Science Ltd, 2015) Ozgirgin, Ekin; Devrim, Yilser; Albostan, AyhanThe rising cost of energy and power, depreciation of natural resources like fossil fuels and the global warming issues have all led the need for developing advanced clean energy systems. Hydrogen, which is clean energy carrier, can be produced by using solar electric energy from photovoltaic (PV) modules for the water electrolysis without emitting carbon dioxide. Modeling of PV module-electrolyzer hydrogen system is important for their planning and control strategies in many applications. In this respect, high-efficiency cogeneration systems for producing both heat and electricity coupled with clean energy sources such as PVs and fuel cells are gaining more attention, due to their advantages in terms of increasing efficiency and power quality, reducing harmful emissions and flexibility of operation. This study describes the analysis of the PV module-fuel cell hybrid system for house-hold micro co-generation applications. The system consists of PV modules, batteries, proton exchange membrane type water electrolyzer and proton exchange membrane fuel cell (PEMFC). The excess heat of PEMFC was used to supply hot water and/or heating energy of the house. Electrical energy was stored in the batteries. The analysis of the PV-electrolyzer-PEMFC system can be further used for designing co-generation systems for various application optimizing the PV module, electrolyzer and PEMFC sizes. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.Article Citation - WoS: 147Citation - Scopus: 163Polybenzimidazole Based Nanocomposite Membranes With Enhanced Proton Conductivity for High Temperature Pem Fuel Cells(Pergamon-elsevier Science Ltd, 2017) Ozdemir, Yagmur; Uregen, Nurhan; Devrim, YilserIn this study, phosphoric acid doped PBI nanocomposite membranes were prepared by dispersion of various amounts of inorganic nanoparticles in PBI polymer followed by phosphoric acid (H3PO4) doping for high temperature proton exchange membrane fuel cells (HT-PEMFC). All of the PBI composite membranes were cast from the same FBI polymer with the same molecular weight. Titanium dioxide (TiO2), silicon dioxide (SiO2) and inorganic proton conductor zirconium phosphate (ZrP) were used as inorganic fillers. The PBI based composite membranes were characterized in terms of their acid uptake and acid leaching properties, mechanical properties, chemical stabilities in N-N Dimethylacetamide (DMAc) and impedance analyses. Thermal gravimetric analysis confirmed the improved thermal stability of the PBI composite membranes. The existence of inorganic fillers was improved the acid retention capability. Electrochemical Impedance Spectroscopy (EIS) showed that the introduction of 5 wt. % SiO2 or 5 wt. % ZrP helps to increase proton conductivity. The composite membrane with TiO2 retained low conductivity values than pristine PBI and this is a result of its non-uniform membrane structure. The highest proton conductivity of 0.200 S/cm was obtained for PBI/ZrP composite membrane with the highest value of H3PO4 doping level. Nyquist plots are drawn for all the membranes at different temperatures and the plots showed good fit with Randel's circuit. As a result the experimental results suggested that the PBI based composite membranes may be a promising electrolyte used in HT-PEMFC. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Article Citation - WoS: 93Citation - Scopus: 104Fabrication and Characterization of Cross-Linked Polybenzimidazole Based Membranes for High Temperature Pem Fuel Cells(Pergamon-elsevier Science Ltd, 2017) Ozdemir, Yagmur; Ozkan, Necati; Devrim, YilserIn this study different types of crosslinked polybenzimidazole (PBI) membranes were compared as high temperature proton exchange membrane fuel cells (HT-PEMFC). Cross-linking of PBI was performed with different cross-linkers including bisphenol A diglycidyl ether (BADGE), ethylene glycol diglycidyl ether (EGDE), alpha-alpha'-dibromo-p-xylene (DBpX), and terephthalaldehyde (TPA). The crosslinked membranes have been characterized by thermogravimetric analysis, scanning electron microscopy, acid uptake and impedance analyses. The crosslinking of the PBI polymer matrix helps to improve the acid retention properties. PBI/BADGE presented the highest acid retention properties. Proton conductivities of the membranes were comparable to that of commercial membranes. Conductivity values up to 0.151 S.cm(-1) were obtained at 180 degrees C with PBI/DBpX membranes. Gas diffusion electrodes (GDE) were fabricated by an ultrasonic coating technique with 0.6 mg Pt.cm(-2) catalyst loading for both anode and cathode. The crosslinked membranes were tested in a single HT-PEMFC with a 5 cm(2) active area at 165 degrees C without humidification. PBI/BADGE crosslinked membranes demonstrated stability and high performance on single cell HT-PEMFC tests. The maximum power density for PBI/BADGE was determined as 0.123 W. cm(-2). As a result, the experimental results suggested that the PBI/ BADGE and PBI/DBpX cross-linked membranes are promising electrolyte options for HT-PEMFC. (C) 2017 Elsevier Ltd. All rights reserved.Article Citation - WoS: 65Citation - Scopus: 69Reliability and Optimal Replacement Policy for a k-out-of-n< System Subject To Shocks(Elsevier Sci Ltd, 2019) Eryilmaz, Serkan; Devrim, YilserConsider a k-out-of-n system which is subject to shocks that occur at random times. Each shock causes failure of random number of components, and hence the system's lifetime corresponds to one of the arrival times of shocks. The reliability and mean time to failure of the system are studied when the times between shocks follow a phase type distribution. The optimal replacement time problem which is concerned with the minimization of the total long-run average cost per unit time is also defined and studied.
