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Conference Object Citation - WoS: 58Citation - Scopus: 62Energy and Exergy Performance Assessments of a High Temperature-Proton Exchange Membrane Fuel Cell Based Integrated Cogeneration System(Pergamon-elsevier Science Ltd, 2020) Nalbant, Yagmur; Colpan, C. Ozgur; Devrim, YilserHigh-temperature proton exchange membrane fuel cell (HT-PEMFC), which operates between 160 degrees C and 200 degrees C, is considered to be a promising technology, especially for cogeneration applications. In this study, a mathematical model of a natural gas fed integrated energy system based on HT-PEMFC is first developed using the principles of electrochemistry and thermodynamics (including energy and exergy analyses). The effects of some key operating parameters (e.g., steam-to-carbon ratio, HT-PEMFC operating temperature, and anode stoichiometric ratio) on the system performance (electrical, cogeneration, and exergetic efficiencies) are examined. The exergy destruction rates of each component in the integrated system are found for different values of these parameters. The results show that the most influential parameter which affects the performance of the integrated system is the anode stoichiometric ratio. For the baseline conditions, when the anode stoichiometric ratio increases from 1.2 to 2, the electrical, cogeneration, and exergetic efficiencies decrease by 42.04%, 33.15%, and 37.39%, respectively. The highest electrical power output of the system is obtained when the SCR, operating temperature, and anode stoichiometric ratio are taken as 2, 160 degrees C, and 1.2, respectively. For this case, the electrical, cogeneration, and exergetic efficiencies are found as 26.20%, 70.34%, and 26.74%, respectively. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Conference Object Citation - WoS: 34Citation - Scopus: 39Development of a One-Dimensional and Semi-Empirical Model for a High Temperature Proton Exchange Membrane Fuel Cell(Pergamon-elsevier Science Ltd, 2018) Nalbant, Yagmur; Colpan, C. Ozgur; Devrim, YilserHigh temperature proton exchange membrane fuel cells (HT-PEMFC), which operate between 160 degrees C and 200 degrees C, can be generally used in portable and stationary power generation applications. In this study, a one-dimensional, semi-empirical, and steady-state model of a HT-PEMFC fed with a gas mixture consisting of hydrogen and carbon monoxide is developed. Some modeling parameters are adjusted using empirical data, which are obtained conducting experiments on a HT-PEMFC for different values of Pt loading and cell temperature. For adjusting these parameters, the total summation of the square of the difference between the cell voltages found using the experimental and theoretical methods is minimized using genetic algorithm. After finding the values of the adjusted parameters, the effects of different cell temperature, Pt loading, phosphoric acid (PA) percentage, and different binders (PBI and PVDF) on the performance of the fuel cell are examined. It was found that, the performance of the fuel cell using PVDF binder exhibited better performance as compared to that using PBI binder. (c) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

