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  • Conference Object
    Citation - WoS: 4
    Citation - Scopus: 3
    Temperature-dependent material characterization of CuZnSe2 thin films
    (Elsevier Science Sa, 2020) Gullu, H. H.; Surucu, O.; Terlemezoglu, M.; Isik, M.; Ercelebi, C.; Gasanly, N. M.; Parlak, M.
    In the present work, CuZnSe2 (CZSe) thin films were co-deposited by magnetron sputtering of ZnSe and Cu targets. The structural analyses resulted in the stoichiometric elemental composition and polycrystalline nature without secondary phase contribution in the film structure. Optical and electrical properties of CZSe thin films were investigated using temperature-dependent optical transmission and electrical conductivity measurements. The band gap energy values were obtained using transmittance spectra under the light of expression relating absorption coefficient to incident photon energy. Band gap energy values were found in decreasing behavior from 2.31 to 2.27 eV with increase in temperature from 10 to 300 K. Temperature-band gap dependency was evaluated by Varshni and O'Donnell models to detail the optical parameters of the thin films. The experimental dark and photoconductivity values were investigated by thermionic emission model over the grain boundary potential. Room temperature conductivity values were obtained in between 0.91 and 4.65 ( x 10(-4) Omega(-1)cm(-1)) under various illumination intensities. Three different linear conductivity regions were observed in the temperature dependent profile. These linear regions were analyzed to extract the activation energy values.
  • Article
    Citation - WoS: 8
    Citation - Scopus: 9
    Investigation of Electrical Properties of In/Znin2< Diode
    (indian Acad Sciences, 2019) Gullu, H. H.
    In/ZnIn2Te4/n-Si/Ag diode structure was fabricated by the thermal deposition of a ZnIn2Te4 thin film on n-Si wafer substrate with Ag metal back contact. The structural characteristics of the film were investigated in terms of composition, X-ray diffraction and topographic measurements. The diode structure was completed by evaporating In metal on the film surface as a top contact. The diode parameters as saturation current, barrier height, ideality factor and series resistance values were determined from the semi-logarithmic forward bias current-voltage characteristics of the diode. According to the assumption of the thermionic emission model, the ideality factor was found higher than unity and it was also observed that the barrier height and ideality factor showed a temperature-dependent profile resulting from the non-ideality in the current-voltage behaviour of the diode. As a result, the model was modified by considering inhomogeneous barrier formation and Gaussian distribution was expected to be dominant on 1.37 eV mean barrier height with a deviation of 0.18. In addition, the voltage dependence of these Gaussian diode parameters was investigated. The forward and reverse bias capacitance and conductance measurements showed that there was a slight change in capacitance values with frequency whereas the conductance values decreased with increase in frequency. In addition to the current-voltage analysis, the distribution of density of interface states and the values of series resistance were evaluated as a function of bias voltage and frequency.
  • Article
    Citation - Scopus: 11
    Cd-Doping Effects on the Properties of Polycrystalline Α-In2se3 Thin Films
    (2002) Qasrawi,A.F.
    The X-ray diffraction has revealed that the polycrystalline hexagonal structured α-In2Se3 thin films grown at substrate temperature of 200°C with the unit cell parameters a=4.03°A and c=19.23°A becomes polycrystalline hexagonal structured InSe with a unit cell parameters of a=4.00°A and c=16.63°A by Cd-doping. The analysis of the conductivity temperature dependence in the range 300-40 K revealed that the thermionic emission of charged carriers and the variable range hopping are the predominant conduction mechanism above and below 100 K, respectively. Hall measurements revealed that the mobility is limited by the scattering of charged carriers through the grain boundaries above 200 K and 120 K for the undoped and Cd-doped samples, respectively. The photocurrent (Iph) increases with increasing illumination intensity (F) and decreasing temperature up to a maximum temperature of ∼100 K, below which Iph is temperature invariant. It is found to have the monomolecular and bimolecular recombination characters at low and high illumination intensities, respectively. The Cd-doping increases the density of trapping states that changes the position of the dark Fermi level leading to the deviation from linearity in the dependence of Iph on F at low illumination intensities.