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Article Citation - WoS: 30Citation - Scopus: 32Effect of Fluorine Substituted Benzothiadiazole on Electro-Optical Properties of Donor-Acceptor Type Monomers and Their Polymers(Elsevier Sci Ltd, 2020) Cakal, Deniz; Ercan, Yunus Emre; Onal, Ahmet M.; Cihaner, AtillaA series of trimeric monomers bearing thiophene donor units and fluorinated analogues of benzothiadiazole acceptor units was synthesized via donor-acceptor-donor approach and polymerized electrochemically in order to investigate the effect of fluorine atom on electro-optical properties of both monomers and their corresponding polymers. All monomers exhibited solvatochromic and fluorescent properties. The introduction of fluorine atom into the conjugated backbone increased the oxidation potentials. Upon moving from nonfluorinated to fully fluorinated analogues, the oxidation potential shifts anodically from 1.30 V to 1.7 V. As in the case of monomers, the fluorine atom substitution also resulted in a decrease in the HOMO energy level of the corresponding polymers, leading to an increase in the electrochemical band gap energy (1.71-1.97 eV). This result can be attributed to deviations from planarity and also to decrease in the effective conjugation length. The polymeric film also exhibited electrochromic properties under various external potentials. Switching time and coloration efficiency values decreased with increasing number of fluorine atom substitution.Article Citation - WoS: 13Citation - Scopus: 13Effect of the Donor Units on the Properties of Fluorinated Acceptor Based Systems(Elsevier Sci Ltd, 2021) Cakal, Deniz; Akdag, Akin; Cihaner, Atilla; Onal, Ahmet M.A new series of monomers in the donor-acceptor-donor array, namely 5-fluoro-4,7-di(furan-2-yl)benzo[c][1,2,5] thiadiazole (F2BT-F), and 5-fluoro-4,7-di(selenophen-2-yl)benzo[c][1,2,5] thiadiazole (S2BT-F), bearing 5-fluorobenzo[c][1,2,5]-thiadiazole as the acceptor moiety and furan and selenophene as the electron donating groups was synthesized and polymerized electrochemically. To compare heteroatom effect, thiophene analogue of newly synthesized (FBT)-B-2-F and S2BT-F namely, (5-fluoro-4,7-di(thiophen-2-yl)benzo[c][1,2,5] thiadiazole (T2BT-F)) and its corresponding polymer were also synthesized. Effect of donor units on the electrochemical and optical properties of fluorinated acceptor based systems was investigated in terms of the effect of different sized heteroatoms in five-membered rings on the dihedral angle and planarity. Theoretical calculations also suggested a deviation from planarity upon fluorination. Moreover, electrochemically obtained polymers possess low bandgap values (1.62 eV-1.68 eV for PF2BT-F and PS2BT-F, respectively) and exhibited electrochromic properties with relatively low switching times.Article Citation - WoS: 27Citation - Scopus: 31Donor-acceptor polymer electrochromes with cyan color: Effect of alkyl chain length on doping processes(Elsevier, 2012) Celikbilek, Ozden; Icli-Ozkut, Merve; Algi, Fatih; Onal, Ahmet M.; Cihaner, AtillaA new series of donor-acceptor-donor (D-A-D) type compounds consisting of dialkyl substituted 3,4-propylenedioxythiophene and benzothiadiazole units were synthesized and polymerized chemically and electrochemically to investigate the effect of alkyl chain length on the doping process of the conjugated polymers. It was found that the alkyl chain length plays a key role on both doping processes and the solubility of the polymer. It is also noteworthy that this new series of D-A-D electrochromes transmits or reflects the cyan color of the Cyan-Magenta-Yellow (CMY) color space in the neutral state which can be switched to transmissive grey when oxidized. (C) 2011 Elsevier B.V. All rights reserved.
