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Article Citation - WoS: 45Citation - Scopus: 47An Electroactive Polymeric Material and Its Voltammetric Response Towards Alkali Metal Cations in Neat Water(Pergamon-elsevier Science Ltd, 2008) Algi, Fatih; Cihaner, AtillaThe syntheses and characterization of a unique system based on thiophene, pyrrole and benzo-15-crown-5 (SNS-Crown) and its corresponding polymer (PSNS-Crown) are reported. Furthermore, selective, clear and reversible voltammetric responses of the conjugated polymer (PSNS-Crown) film towards the alkali series Li+, Na+ and K+ in both neat water and organic media (ethanol) are described. (c) 2008 Elsevier Ltd. All rights reserved.Article Citation - WoS: 96Citation - Scopus: 99A Processable Rainbow Mimic Fluorescent Polymer and Its Unprecedented Coloration Efficiency in Electrochromic Device(Pergamon-elsevier Science Ltd, 2008) Cihaner, Atilla; Algi, FatihA processable rainbow mimic fluorescent polymer (PSNSF) based on 1-(9H-fluoren-2-yl)-2,5-di(thiophen-2-yl)-1H-pyrrole (SNSF) was synthesized via electrochemical polymerization in a mixture of ethanol and CH2Cl2 solution containing 0.1 M LiClO4. Characterization was carried out using cyclic voltammetry, UV-vis and F-FAR spectroscopic techniques. Also, an electrochromic device based on PSNSF was studied, which exhibits high coloration efficiency (CE), high redox stability (retaining 98.6% of its optical activity after 4000th switch) and very low response time (less than 0.5 s). (c) 2007 Elsevier Ltd. All rights reserved.

