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Article The Impact of Quaternization Degree in Polyepichlorohydrin-Based Anion Exchange Membranes on Salinity Gradient Energy Generation by Reverse Electrodialysis(Elsevier, 2025) Cihanoglu, Aydin; Guler, Enver; Kabay, NalanAnion exchange membranes with tailored fixed-charge densities can improve monovalent ion selectivity and performance in reverse electrodialysis for salinity gradient power generation. In this study, poly(epichlorohydrin) was blended with polyacrylonitrile and quaternized with 1,4-diazabicyclo[2.2.2]octane at three different molar ratios to produce AEMs with systematically varied quaternization degrees via a one-step amination/ crosslinking procedure. The resulting membranes were characterized for their physicochemical, electrochemical, and RED performance using ATR-FTIR, XPS, SEM, AFM, water uptake, swelling degree, contact angle, surface zeta potential, ion exchange capacity, fixed charge density, and electrical resistance. Higher quaternization increased the IEC, reduced resistance, and shifted surface charge, leading to improved stack power output in model NaCl solutions. In the presence of Na2SO4, power loss was reduced for more highly quaternized membranes, indicating enhanced exclusion of divalent anions (SO42-) and reduced uphill transport. Fouling tests with humic acid/fulvic acid mixtures showed greater stability for quaternized membranes compared to a commercial benchmark. Moreover, stability tests conducted on fouled membranes revealed that the tailor-made membrane exhibits superior durability and lower fouling-induced power loss than commercial Fujifilm Type II AEMs. Overall, these results demonstrate that tuning the degree of quaternization is an effective strategy to balance conductivity and ion selectivity in AEMs for RED applications.Article Citation - WoS: 39Citation - Scopus: 44A Novel Treatment Strategy for Preterm Birth: Intra-Vaginal Progesterone-Loaded Fibrous Patches(Elsevier, 2020) Cam, Muhammet Emin; Hazar-Yavuz, Ayse Nur; Cesur, Sumeyye; Ozkan, Ozan; Alenezi, Hussain; Sasmazel, Hilal Turkoglu; Edirisinghe, MohanProgesterone-loaded poly(lactic) acid fibrous polymeric patches were produced using electrospinning and pressurized gyration for infra-vaginal application to prevent preterm birth. The patches were intravaginally inserted into rats in the final week of their pregnancy, equivalent to the third trimester of human pregnancy. Maintenance tocolysis with progesterone-loaded patches was elucidated by recording the contractile response of uterine smooth muscle to noradrenaline in pregnant rats. Both progesterone-loaded patches indicated similar results from release and thermal studies, however, patches obtained by electrospinning had smaller average diameters and more uniform dispersion compared to pressurized gyration. Patches obtained by pressurized gyration had better results in production yield and tensile strength than electrospinning; thereby pressurized gyration is better suited for scaled-up production. The patches did not affect cell attachment, viability, and proliferation on Vero cells negatively. Consequently, progesterone-loaded patches are a novel and successful treatment strategy for preventing preterm birth.Article Citation - WoS: 50Citation - Scopus: 53Recrystallization and Grain Growth Kinetics of In718 Manufactured by Laser Powder Bed Fusion(Elsevier, 2022) Dogu, Merve Nur; Davut, Kemal; Obeidi, Muhannad Ahmed; Yalcin, Mustafa Alp; Gu, Hengfeng; Low, Thaddeus Song En; Brabazon, DermotThe recrystallization and grain growth behaviour of IN718 alloy additively manufactured by laser powder bed fusion (L-PBF) is presented herein. The effects of three different temperatures (1050, 1150 and 1250 degrees C) and holding times (15, 45 and 90 min) were investigated. The texture evolution of the samples was recorded via electron backscatter diffraction (EBSD). The as-built sample is composed of bowl-shaped melt pools, a chessboard-like grain pattern and has a cube texture {100}<001>. Recrystallized grains were observed in the samples treated at 1150 degrees C for 15 min, as well as the samples treated for longer periods and at higher temperatures. Recrystallization was observed to start from high dislocation density regions, including the overlapping melt pools and the borders of the chessboard-like pattern. The initial cube texture transforms into a first-generation cube-twin texture {122}<212> via a twinning-assisted recrystallization mechanism. Then, those recrystallization nuclei sweep through the high defect density matrix; during which almost no new twins are formed. The samples treated at 1250 degrees C are almost completely recrystallized, which forms a weaker cube texture and a stronger P-orientation {011}<112>. However, the growth of recrystallized grains is very limited due to the presence of non-coherent precipitates. (C) 2022 The Author(s). Published by Elsevier B.V.Article Citation - WoS: 24Citation - Scopus: 27Effect of Solution Heat Treatment on the Microstructure and Crystallographic Texture of In939 Fabricated by Powder Bed Fusion-Laser Beam(Elsevier, 2023) Dogu, Merve Nur; Ozer, Seren; Yalcin, Mustafa Alp; Davut, Kemal; Bilgin, Guney Mert; Obeidi, Muhannad Ahmed; Brabazon, DermotThe effect of various solution heat treatment temperatures (i.e., 1120, 1160, 1200 and 1240 & DEG;C) on the microstructure, grain morphology and crystallographic texture of IN939 fabricated by powder bed fusion-laser beam (PBF-LB) was investigated. Microstructural analyses showed that the high-temperature gradient and rapid solidification of the PBF-LB processing caused different resulting microstructures compared to conventionally pro-duced counterparts. The melt pool morphologies and laser scanning paths were examined in the as-fabricated samples in the XZ-and XY-planes, respectively. After the application of solution heat treatment at 1120 & DEG;C, the as-fabricated PBF-LB initial microstructure was still apparent. For solution heat treatments of 1200 & DEG;C and above, the melt pool and scanning path morphologies disappeared and converted into a mixture of columnar grains in the XZ-plane and equiaxed grains in the XY-plane. On the other hand, large equiaxed grains were observed when the samples were solutionized at 1240 & DEG;C. Additionally, g' phase precipitated within the matrix after all solution heat treatment conditions, which led to increase in the microhardness values. According to electron backscatter diffraction (EBSD) analyses, both as-fabricated and solution heat-treated samples had intense texture with {001} plane normal parallel to the building direction. The first recrystallized grains began to appear when the samples were subjected to the solution heat treatment at 1160 & DEG;C and the fraction of the recrystallized grains increased with increasing temperature, as supported by kernel average misorientation (KAM) and grain spread orientation (GOS) analyses.& COPY; 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).Article Citation - WoS: 5Citation - Scopus: 6Clinic-Oriented Injectable Smart Material for the Treatment of Diabetic Wounds: Coordinating the Release of Gm-Csf and Vegf(Elsevier, 2024) Kinali, Hurmet; Kalaycioglu, Gokce Dicle; Boyacioglu, Ozge; Korkusuz, Petek; Aydogan, Nihal; Vargel, IbrahimChronic wounds are often caused by diabetes and present a challenging clinical problem due to vascular problems leading to ischemia. This inhibits proper wound healing by delaying inflammatory responses and angiogenesis. To address this problem, we have developed injectable particle-loaded hydrogels which sequentially release Granulocyte-macrophage- colony-stimulating-factor (GM-CSF) and Vascular endothelial growth factor (VEGF) encapsulated in polycaprolactone-lecithin-geleol mono-diglyceride hybrid particles. GM-CSF promotes inflammation, while VEGF facilitates angiogenesis. The hybrid particles (200 -1000 nm) designed within the scope of the study can encapsulate the model proteins Bovine Serum Albumin 65 +/- 5 % and Lysozyme 77 +/- 10 % and can release stably for 21 days. In vivo tests and histological findings revealed that in the hydrogels containing GM-CSF/VEGF-loaded hybrid particles, wound depth decreased, inflammation phase increased, and fibrotic scar tissue decreased, while mature granulation tissue was formed on day 10. These findings confirm that the hybrid particles first initiate the inflammation phase by delivering GM-CSF, followed by VEGF, increasing the number of vascularization and thus increasing the healing rate of wounds. We emphasize the importance of multi-component and sequential release in wound healing and propose a unifying therapeutic strategy to sequentially deliver ligands targeting wound healing stages, which is very important in the treatment of the diabetic wounds.Article Citation - WoS: 28Citation - Scopus: 31A Model for the Prediction of Thermal Runaway in Lithium-Ion Batteries(Elsevier, 2024) Azuaje-Berbeci, Bernardo J.; Ertan, H. BulentThe increasing popularity of electric vehicles is driving research into lithium -ion batteries (LIBs). Thermal runaway (TR) in LIBs is a serious concern for the safe operation of these high-energy-density batteries that is yet to be overcome. A reliable model is needed to predict voltage variation, heat generation, temperature rise, and the process leading to TR of a LIB battery under its operating conditions (charging-discharging). Such a model can be used to design battery packs more resilient to thermal runaway or assess how a battery pack would perform under hazardous conditions. Furthermore, it can be used for generating a warning signal if there is a possibility of the battery going towards TR. This paper presents an approach to solving this problem, which is not currently well addressed in the literature. The approach adopted in this paper is based on a numerical analysis of a multilayered electrochemical-thermal model of LIB. Tuning the parameters of a LIB for accurate results from this numerical model is presented, as well as the details of the approach in the paper. Experiments are performed under several LIBs, and their voltage and surface temperature variations are measured under various operating conditions, including thermal runaway. The results of the experiments are compared with the predictions of the numerical simulations. An excellent agreement is observed with the experimental results, proving the accuracy of the proposed approach. This approach can be configured to give results in a few minutes. The paper also discusses how the developed approach can be used to create a TR warning during operating conditions or to change the mode of operation of a LIB before a hazard occurs.Article Citation - WoS: 113Citation - Scopus: 147Experiments and Finite Element Simulations on Micro-Milling of Ti-6al Alloy With Uncoated and Cbn Coated Micro-Tools(Elsevier, 2011) Oezel, T.; Thepsonthi, T.; Ulutan, D.; Kaftanoglu, B.This paper presents experimental investigations and finite element simulations on micro-milling of Ti-6Al-4V alloy with fine grain uncoated and cBN coated micro-end mills. Micro-milling of Ti-6Al-4V using uncoated and cBN coated tungsten carbide micro-end mills are conducted; surface roughness, burr formation and tool wear are measured. Effects of machining parameters on surface roughness, burr formation, and tool wear for uncoated and cBN coated micro-tools are investigated. Finite element modelling is utilized to predict forces, temperatures, and wear rate for uncoated and cBN coated micro-tools. Predicted temperature and tool wear contours for uncoated and cBN coated micro-tool edges reveal advantages of cBN coatings. Optimization studies on the experimental results are also conducted to identify the optimum process parameters which minimize both surface roughness and burr formation concurrently. (C) 2011 CIRP.Article Citation - WoS: 25Citation - Scopus: 39Optimization and Thermal Analysis of Radial Ventilated Brake Disc To Enhance the Cooling Performance(Elsevier, 2022) Jafari, Rahim; Akyuz, RecepVentilated brake discs are preferable to automobile application because of their higher heat dissipation ability than solid discs. The shape, geometry and number of the cooling fins are interested parameters to be investigated to improve the cooling performance of the discs. In the present study, the optimum design of the brake disc with radial vanes is investigated numerically using the Taguchi design of experiments with taking into account nine design parameters. Finite element method is employed to simulate the detailed airflow and temperature distribution in the disc considering adjoined components as pads, rim, tire and dust shield. It has been found that the ventilation gap width has the highest impact on the brake disc cooling. The cooling time of the disc decreases 21% as the ventilation gap increases from 8 mm to 14 mm. In addition, it reduces about 10% with the increment of the channel width between two adjacent vanes (inverse of vane numbers from 43 to 30) and the twist point from 225 mm to 266 mm. In a decreasing order of importance, fin angle, inner and outer diameters of fin, dust shield, bell link and disc material affect the cooling performance of the ventilated disc.Article Citation - WoS: 20Citation - Scopus: 23A Novel Comfort Temperature Determination Model Based on Psychology of the Participants for Educational Buildings in a Temperate Climate Zone(Elsevier, 2023) Ozbey, Mehmet Furkan; Turhan, CihanMaintaining thermal comfort in the educational buildings is vital due to the impacts on learning effectiveness of students. Therefore, development of a proper comfort temperature in educational buildings is a must. In naturally ventilated and mixed-mode buildings, the adaptive thermal comfort model, which considers additively psychological, and behavioural factors to the Fanger's PMV/PPD model, is commonly applied based on regression analyses. However, the psychological adjustments based on current mood state are very limited in these adaptive thermal comfort models. Therefore, this study focuses on the psychological adjustments in terms of Profile of Mood States in order to predict comfort temperature of students in a case building. The experiments are conducted in a university on a temperate climate zone for a long period-data including both heating and cooling seasons. In this study, the comfort temperatures for each student are determined via Griffith method for the case building. Moreover, the current mood states of students are assessed utilizing the Profile of Mood States survey, which are collected via a developed mobile application. As a conclusion, the relation between the current mood state of the students and comfort temperature are statistically investigated. The results show that a Griffith constant are found as 0.332/K and mean annual comfort temperature is found as 21.32 degrees C in the case building. Additionally, a significant difference is found in the comfort temperatures among the students who have more, or fewer concerns than typically reported. The novelty of the study is to present a comfort temperature determination model which considers human psychology as a starter study in the literature.Article Citation - WoS: 136Citation - Scopus: 148Palladium(0) Nanoparticles Supported on Silica-Coated Cobalt Ferrite: a Highly Active, Magnetically Isolable and Reusable Catalyst for Hydrolytic Dehydrogenation of Ammonia Borane(Elsevier, 2014) Akbayrak, Serdar; Kaya, Murat; Volkan, Murvet; Ozkar, SaimPalladium(0) nanoparticles supported on silica-coated cobalt ferrite (Pd(0)/SiO2-CoFe2O4) were in situ generated during the hydrolysis of ammonia borane, isolated from the reaction solution by using a permanent magnet and characterized by ICP-OES, XRD, TEM, TEM-EDX, XPS and the N-2 adsorption-desorption techniques. All the results reveal that well dispersed palladium(0) nanoparticles were successfully supported on silica coated cobalt ferrite and the resulting Pd(0)/SiO2-CoFe2O4 are highly active, magnetically isolable, and recyclable catalysts in hydrogen generation from the hydrolysis of ammonia borane with an unprecedented turnover frequency (TOF, calculated on the basis of the total amount of Pd) of 254 mol H-2 (mol Pd min)(-1) at 25 +/- 0.1 degrees C. The reusability tests reveal that Pd(0)/SiO2-CoFe2O4 are still active in the subsequent runs of hydrolysis of ammonia borane providing 100% conversion. Pd(0)/SiO2-CoFe2O4 provide the highest catalytic activity with a TOF value of 198 mol H-2 (mol Pd min)(-1) in the 10th use in hydrogen generation from the hydrolysis of ammonia borane as compared to the other palladium catalysts. The work reported here also includes the kinetic studies depending on the temperature to determine the activation energy of the reaction (E-a = 52 +/- 2 kJ/mol) and the effect of catalyst concentration on the rate of hydrolytic dehydrogenation of ammonia borane, respectively. (C) 2013 Elsevier B.V. All rights reserved.
