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Article Polysulfur Copolymer as a Support Material for the Preparation of a Novel Multifunctional Photocatalytic Composite Material(Springer, 2025) Kesimal, Busra; Guner, Zuhal Vanli; Cihaner, Atilla; Kaya, MuratOne-step addition of magnetic nanoparticles and titanium dioxide nanoparticles into polysulfur copolymer as cheap and available support was reported for the first time to prepare the magnetically separable heterogeneous catalyst, PolyS-MNP-TiO2. The photocatalytic activities of the PolyS-MNP-TiO2 composite material and its constituents were examined in the methylene blue (MB) degradation, textile-based wastewater simulant, exposed to solar light. Detailed characterization of the catalysts was performed with SEM, TEM, and EDX measurements. The photocatalytic activity of the resulting composite was figured out in the removal of methylene blue dye by using a solar simulator. Significantly, the as-prepared PolyS-MNP-TiO2 exhibits exceptional photocatalytic activity and total degradation of dye molecules was achieved in 60 min. Additionally, the prepared novel photocatalyst showed enhanced stability and reusability due to the magnetic behavior of the composite material and the same portion of catalyst was used in five successive tries without apparent loss in catalytic activity by eliminating long and work-loaded processes like filtration and centrifugation.Article Citation - WoS: 8Citation - Scopus: 7Preparation and Photocatalytic Activity of Apatite-Precipitated Tio2(Korean Assoc Crystal Growth, inc, 2011) Soysal, K.; Park, J.; You, S. H.; Shin, D. W.; Bae, W. T.; Ozturk, A.; Metallurgical and Materials Engineering; English Translation and InterpretationApatite was precipitated on the surface of titanium dioxide (TiO2) powder by a biomimetic process. The precipitation was accomplished by immersing TiO2 powder in simulated body fluid (SBF) for 1, 3, 6, 12 and 24 h. Photocatalytic activity of the apatite-precipitated TiO2 (HAp-TiO2) powders was investigated to assess the decomposition of methylene blue (MB) in aqueous solution and the removal of acetaldehyde gas under UV irradiation. Hydroxyapatite precipitation enhanced the photocatalytic activity of the TiO2 powder. The time required for the complete degradation of MB decreased from 3.5 to 2 h with the immersion of TiO2 powders in SBF for 3 h. In terms of acetaldehyde gas decomposition, less than 1 h was sufficient to achieve complete removal for HAp-TiO2 powder but at least 2 h were required for the bare TiO2 powder. HAp-TiO2 powders could therefore be a promising candidate photocatalyst for environmental purification.
