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Article Citation - WoS: 10Citation - Scopus: 10Reinforcing Effect of Polyurethane Sizing on Properties of Acrylonitrile-Butadiene Composites Involving Short Carbon Fiber(Springer international Publishing Ag, 2020) Ahmed, Shan Abdulalaziz; Tirkes, Seha; Tayfun, UmitIn this study, we present the influence of sizing layer of short carbon fiber (CF) to the basic properties of CF reinforced acrylonitrile-butadiene-styrene (ABS) composites. Composite samples are prepared with four different loading ratio of 5, 10, 15 and 20% by weight using melt-compounding. Surface topography, elemental analysis and surface functionality of CF samples are confirmed by atomic force microscopy (AFM), energy-dispersive X-ray (EDX) and infrared (FTIR) spectroscopy techniques, respectively. Characterizations of composites are performed based on mechanical, thermo-mechanical, melt-flow (MFI) and morphological performances of composites. According to test results, mechanical properties of ABS are enhanced with CF additions. Polyurethane (PU) sized CF containing composites display higher tensile strength, modulus and hardness compared to desized ones. CF additions lead to increase in glass transition temperature of ABS copolymer. MFI values of composites are found to be in narrow range, hence CF additions cause no effect for processing conditions of ABS. According to SEM analysis, CF surfaces are covered by polymer matrix thanks to PU sizing layer of CF, whereas debondings are formed for desized CF-filled ABS matrix. Results indicate that PU-sizing is suitable for ABS/CF composite system. [GRAPHICS] .Article Citation - WoS: 4Citation - Scopus: 4Performance Improvement of Carbon Fiber-Reinforced Abs Composites by Introducing Fullerene Nanoparticles(John Wiley and Sons Ltd, 2025) Akar, A.Ö.; Yıldız, Ü.H.; Tirkeş, S.; Tayfun, Ü.; Hacivelioglu, F.Recently, polymer composites have been extensively researched in industrial fields such as electrical conductance, ohmic heating, electromagnetic shielding and electrostatic discharge, particularly in engineering polymers reinforced with carbonaceous additions. Herein, fullerene (C60) and short carbon fiber (CF) were incorporated with acrylonitrile–butadiene–styrene copolymer (ABS) using melt-compounding followed by an injection-molding process. Composite samples were produced with contents of 20 wt% of CF besides 0.1, 0.5 and 1.0 wt% of C60. Tensile, impact, hardness and wear tests, conductive atomic force microscopy, dynamic mechanical analysis, thermogravimetric analysis, melt flow index tests and scanning electron microscopy (SEM) were performed to characterize mechanical, electrical, thermomechanical, thermal, melt-flow and structural behaviors of ABS-based composites involving CF and C60. Based on the mechanical test findings obtained for the developed composites, comprising tensile and impact test results, C60 additions contributed to a significant rise in tensile strength and impact resistance of CF-reinforced ABS composites, with a 20% increase in tensile resistance being achieved by introduction C60 into the ABS/CF structure. C60 addition enhanced efficiency by 50% in terms of tensile modulus. Electrical conductivity measurements confirmed that C60 nanoparticles and CF exhibited a synergy. The optimum synergistic ratio of C60/CF was obtained as 0.5/20. The conductive path in the ABS/CF composite system was established by incorporating C60 with different loading amounts. SEM micrographs of composites demonstrated that C60 nanoparticles were dispersed homogeneously into the ABS matrix involving lower amounts of C60. © 2025 The Author(s). Polymer International published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry. © 2025 The Author(s). Polymer International published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.Article Citation - WoS: 14Citation - Scopus: 19Influence of Carbon Nanotube Inclusions To Electrical, Thermal, Physical and Mechanical Behaviors of Carbon-Fiber Abs Composites(Springer Japan Kk, 2022) Akar, Alinda Oyku; Yildiz, Umit Hakan; Tirkes, Seha; Tayfun, Umit; Hacivelioglu, FerdaAcrylonitrile-butadiene-styrene (ABS) terpolymer was compounded with short carbon fiber (CF) and carbon nanotube (CNT) using a micro-extruder followed by the injection molding process. Composite samples were fabricated with loading ratios of 20 wt.% CF and 0.1, 0.5 and 1.0 wt.% of CNT. Mechanical, electrical, thermo-mechanical, thermal, melt-flow, and structural investigations of ABS-based composites were conducted by performing tensile, impact, hardness, and wear tests, conductive atomic force microscopy (AFM), dynamic mechanical analysis (DMA), thermal gravimetric analysis (TGA), melt flow rate test (MFR), scanning electron microscopy (SEM) characterization techniques, respectively. According to mechanical test data of resultant composites including tensile and impact test findings, CNT additions led to the remarkable increase in tensile strength and impact resistance for CF reinforced ABS composites. The formation of synergy between CNT nanoparticles and CF was confirmed by electrical conduction results. The conductive path in ABS/CF composite system was achieved by the incorporation of CNT with different loading levels. SEM micrographs of composites proved that CNT nanoparticles exhibited homogeneous dispersion into ABS matrix for lower loadings. [GRAPHICS] .Article Citation - WoS: 23Citation - Scopus: 22Evaluation of flammability, thermal stability and mechanical behavior of expandable graphite-reinforced acrylonitrile-butadiene-styrene terpolymer(Springer, 2022) Cirmad, Hussam; Tirkes, Seha; Tayfun, UmitAcrylonitrile-butadiene-styrene (ABS) terpolymer was loaded with expandable graphite (EG) at four different concentrations of 5%, 10%, 15% and 20% using micro-compounder followed by injection molding process. Mechanical, thermomechanical, thermal, flame retardancy, melt flow and morphological characterizations of composites were done by tensile, hardness and impact tests, dynamic mechanical analysis (DMA), thermogravimetric analysis (TGA), melt flow index (MFI) test and scanning electron microscopy (SEM), respectively. According to test results, tensile strength and storage modulus of ABS were improved with the increase in EG content. Storage modulus and glass transition temperature of ABS yielded enhancement with the inclusion of EG. However, percent elongation and impact strength values showed decreasing trend with EG additions. ABS/EG composites gave higher fire performance relative to ABS including enhancement in LOI and reduction in heat release rate. MFI test revealed that incorporation of EG with the lowest amount displayed no dramatic change for MFI value of neat ABS. EG flakes exhibited well-dispersion and exfoliated structure for all of the filling ratios as the SEM microimages of composites were examined. 15% and 20% EG containing ABS composites were remarked as the most suitable candidates among prepared composites. [GRAPHICS] .
