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Conference Object Citation - WoS: 134Citation - Scopus: 148Polybenzimidazole/Sio2< Hybrid Membranes for High Temperature Proton Exchange Membrane Fuel Cells(Pergamon-elsevier Science Ltd, 2016) Devrim, Yilser; Devrim, Huseyin; Eroglu, InciPolybenzimidazole/Silicon dioxide (PBI/SiO2) hybrid membranes were prepared and characterized as alternative materials for high temperature proton exchange membrane fuel cell (HT-PEMFC). The PBI/SiO2 membranes were cast from a PBI polymer synthesized in the laboratory and contained 5 wt. % SiO2 as inorganic filler. Scanning electron microscopy (SEM) analysis showed that the uniform and homogeneous distribution of SiO2 particles in the hybrid membrane. The existence SiO2 has improved the acid retention and proton conductivity properties. A maximum conductivity of 0.1027 S/cm at 180 degrees C was obtained for the PBI/SiO2 hybrid membrane. Gas diffusion electrodes (GDE) were fabricated by ultrasonic coating technique with 1 mg Pt/cm(2) catalyst loading for both anode and cathode. The membranes were tested in a single HT-PEMFC with a 5 cm(2) active area operating at the temperature range of 140 degrees C-180 degrees C. Single HT-PEMFC tests indicated that PBI/SiO2 hybrid membrane was more stable and also performed better than pristine PBI membrane. Maximum current density was observed for PBI/SiO2 membrane at 165 degrees C and cell voltage of 0.6 V as 0.24 A/cm(2). The results suggested that PBI/SiO2 hybrid membrane is promising electrolytes for HT-PEMFC with improved fuel cell performance. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Conference Object Citation - WoS: 98Citation - Scopus: 101Experimental Investigation of Co Tolerance in High Temperature Pem Fuel Cells(Pergamon-elsevier Science Ltd, 2018) Devrim, Yilser; Albostan, Ayhan; Devrim, HuseyinIn the present work, the effect of operating a high temperature proton exchange membrane fuel cell (HT-PEMFC) with different reactant gases has been investigated throughout performance tests. Also, the effects of temperature on the performance of a HT-PEMFC were analyzed at varying temperatures, ranging from 140 degrees C to 200 degrees C. Increasing the operating temperature of the cell increases the performance of the HT-PEMFC. The optimum operating temperature was determined to be 160 degrees C due to the deformations occurring in the cell components at high working temperatures. To investigate the effects of CO on the performance of HT-PEMFC, the CO concentration ranged from 1 to 5 vol %. The current density at 0.6 V decreases from 0.33 A/cm(2) for H-2 to 0.31 A/cm(2) for H-2 containing 1 vol % CO, to 0.29 A/cm(2) for 3 vol % CO, and 0.25 A/cm(2) for 5 vol % CO, respectively. The experimental results show that the presence of 25 vol % CO2 or N-2 has only a dilution effect and therefore, there is a minor impact on the HT-PEMFC performance. However, the addition of CO to H-2/N-2 or H-2/CO2 mixtures increased the performance loss. After longterm performance test for 500 h, the observed voltage drop at constant current density was obtained as similar to 14.8% for H-2/CO2/CO (75/22/3) mixture. The overall results suggest that the anode side gas mixture with up to 5 vol % CO can be supplied to the HT-PEMFC stack directly from the reformer. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
