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Article Citation - WoS: 5Citation - Scopus: 5Electrochemical Polymerization of 4-Allylanisole(Pergamon-elsevier Science Ltd, 2001) Cihaner, A; Testereci, HN; Önal, AMElectrochemical polymerization of 3-allylanisole (4AA). via constant potential electrolysis, has been investigated in acetonitrile using two different supporting electrolytes. Redox behavior of the monomer was also studied in the same solvent-electrolyte couples at room temperature. Electrochemical polymerization of the monomer yielded insoluble polymer films on the electrode surface, which bears a very low conductivity, together with the low molecular weight polymers in the bulk of the solution. The decrease in the monomer concentration, during the electrochemical polymerization. was monitored by taking the cyclic voltammogram of the electrolysis solution. The effect of temperature on the rate of electrochemical polymerization was: also studied. The polymers were characterized by taking the H-1-NMR and FTIR spectra. Molecular weight of the soluble polymer was determined by vapor pressure osmometry. Thermal analysis of the polymer film and soluble polymer were done by DSC. (C) 2001 Elsevier Science Ltd. All rights reserved.Article Citation - WoS: 34Synthesis and Characterization of Fluorine-Substituted Polyanilines(Pergamon-elsevier Science Ltd, 2001) Cihaner, A; Önal, AMPoly(2-fluoroaniline), P2FAN, poly(3-fluoroaniline). P3FAN. and poly(4-fluoroaniline), P4FAN, have been synthesized from fluorine substituted aniline monomers in aqueous acidic medium using potassium dichromate as oxidizing agent. Characterization of polymer products has been carried out using FTIR, and NMR spectroscopic techniques. Thermal analysis of polyfluoroaniline powders was also investigated using differential scanning calorimetry and thermogravimetric analysis. To compare the structural properties of the polymers, polyfluoroanilines were also synthesized using ammonium peroxydisulfate as oxidizing agent. Polyfluoroanilines synthesized by chemical oxidation were doped by using iodine and the change in the paramagnetic behavior was monitored by electron spin resonance spectroscopy. (C) 2001 Elsevier Science Ltd. All rights reserved.
