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Article Citation - WoS: 52Citation - Scopus: 60Comparative Study of Pv/Pem Fuel Cell Hybrid Energy System Based on Methanol and Water Electrolysis(Pergamon-elsevier Science Ltd, 2019) Budak, Yagmur; Devrim, YilserIn this study, we investigated the comparative analysis of a solar-fuel cell hybrid system based on water and methanol electrolysis. The proposed system comprises PV, electrolyzer and proton exchange membrane fuel cell (PEMFC). The hybrid system is designed to supply the hydrogen (H-2) needed of the PEMFC system and also to fulfill the H-2 requirement of other applications. The actual data of solar irradiation of Izmir, Turkey are used in the simulation. The methanol and water electrolyzers were designed for 1.2 kW PEMFC H-2 demand which were met a house-hold energy requirement. Analyzes show that the use of the methanol electrolyzer can produce 27% more H-2 than the water electrolyzer. According to the study, it was determined that the methanol-based hybrid system offered a viable option for self-sustaining in household application.Article Citation - WoS: 7Citation - Scopus: 9Development and Performance Analysis of Polybenzimidazole/Boron Nitride Composite Membranes for High-Temperature Pem Fuel Cells(Wiley, 2022) Hussin, Dedar Emad; Budak, Yagmur; Devrim, YilserIn this research, polybenzimidazole/boron nitride (PBI/BN) based composite membranes have been prepared for high-temperature PEM fuel cell (HT-PEMFC). BN was preferred because of its superior thermal robustness, high chemical stability, non-conductor property, and high plasticizer characteristic. The loading of BN in the composite membrane was studied between 2.5 to 10 wt%. The composite membranes were characterized using TGA, DSC, XRD, SEM, mechanical tests, acid doping/leaching, and proton conductivity measurements. The highest conductivity of 0.260 S/cm was found for PBI/BN-2.5 membrane at 180 degrees C. It has been determined that the PBI/BN-2.5 membrane has higher performance than the PBI membrane according to the HT-PEMFC tests performed with Hydrogen and dry air. The heightened HT-PEMFC performance can be ascribed to interactive effects between BN particles and the PBI polymer matrix. PBI/BN composite membranes show a good perspective in the high-temperature PEMFC applications.
