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Author: Akar, Alinda OykuWoS Q: Q2

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    Article
    Citation - WoS: 14
    Citation - Scopus: 17
    Hybrid Nanocomposites of Elastomeric Polyurethane Containing Halloysite Nanotubes and Poss Nanoparticles: Tensile, Hardness, Damping and Abrasion Performance
    (Cambridge Univ Press, 2020) Mohamed, Salma Taher; Tirkes, Seha; Akar, Alinda Oyku; Tayfun, Umit
    Thermoplastic polyurethane (TPU) matrix was reinforced with polyhedral oligomeric silsesquioxane (POSS) and halloysite nanotubes (HNT), both separately and combined. Composite samples were fabricated using a melt-compounding method. Characterization of the composites obtained was performed via tensile and hardness tests, melt-flow index measurements (MFI), abrasion tests, dynamic mechanical analysis (DMA) and scanning electron microscopy (SEM) to investigate the mechanical performance, flow behaviour, tribological characteristics, thermo-mechanical response and morphological properties. The greatest tensile strength value was obtained for the smallest HNT content. Further addition of HNT resulted in agglomerations for both POSS and HNT particles. The shore hardness of TPU was enhanced by filler inclusions. The TPU/POSS composites displayed significant improvement in terms of abrasion resistance compared to TPU at lower loading levels. The DMA study showed that composites containing 0.5% POSS and 1.0% HNT displayed the greatest storage modulus. The glass-transition temperature of TPU shifted to smaller values with the addition of both nanoparticles. The HNT inclusions increased the MFI value of TPU because of their large aspect ratio. Homogeneous mixing of nanoparticles in the TPU matrix was confirmed by a SEM study of the composites. Their dispersion decreased as the concentrations of POSS and HNT increased. An adjuvant effect of POSS with HNT was achieved in their hybrid composites.
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    Conference Object
    Citation - WoS: 33
    Citation - Scopus: 35
    Enhancement of Mechanical, Thermal and Water Uptake Performance of Tpu/Jute Fiber Green Composites Via Chemical Treatments on Fiber Surface
    (Walter de Gruyter Gmbh, 2020) Salem, Tuffaha Fathe; Tirkes, Seha; Akar, Alinda Oyku; Tayfun, Umit
    Chopped jute fiber (JF) surfaces were modified using alkaline, silane and eco-grade epoxy resin. Surface characteristics of jute fibers were confirmed by FTIR and EDX analyses. JF filled polyurethane elastomer (TPU) composites were prepared via extrusion process. The effect of surface modifications of JF on mechanical, thermo-mechanical, melt-flow, water uptake and morphological properties of TPU-based eco-composites were investigated by tensile and hardness tests, dynamic mechanical analysis (DMA), melt flow index (MFI) test, water absorption measurements and scanning electron microscopy (SEM) techniques, respectively. Mechanical test results showed that silane and epoxy treated JF additions led to increase in tensile strength, modulus and hardness of TPU. Glass transition temperature (T-g) of TPU rose up to higher values after JF inclusions regardless of treatment type. Si-JF filled TPU exhibited the lowest water absorption among composites. Surface treated JFs displayed homogeneous dispersion into TPU and their surface were covered by TPU according to SEM micro-photographs.