Browsing by Author "Qasrawi, AF"
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Article Citation Count: 9Carrier scattering mechanisms in GaS0.5Se0.5 layered crystals(Wiley-v C H verlag Gmbh, 2002) Qasrawı, Atef Fayez Hasan; Gasanly, NM; Department of Electrical & Electronics EngineeringSystematic dark electrical resistivity and Hall mobility measurements have been carried out in the temperature range 150-400 K on n-type GaS0.5Se0.5 layered crystals. The analysis of temperature dependent electrical resistivity and carrier concentration reveals the extrinsic type of conduction with a donor impurity level located at 0.44 eV, donor and acceptor concentrations of 3.4x10(17) and 4.1x10(17) cm(-1), respectively, and an electron effective mass of 0.41 m(o). The Hall mobility is limited by the electron-phonon short-range interactions scattering at high temperatures combined with the ionized impurity scattering at low temperatures. The electron-phonon short-range interactions scattering mobility analysis reveals an electron-phonon coupling constant of 0.25 and conduction band deformation potential of 5.57 eV/Angstrom.Article Citation Count: 1Carrier transport properties of InS single crystals(Wiley-blackwell, 2003) Qasrawı, Atef Fayez Hasan; Gasanly, NM; Department of Electrical & Electronics EngineeringThe electrical resistivity and Hall effect of indium sulfide single crystals are measured in the temperature range from 25 to 350 K. The donor energy levels located at 500, 40 and 10 meV below the conduction band are identified from both measurements. The data analysis of the temperature-dependent Hall effect measurements revealed a carrier effective mass of 0.95 m(0), a carrier compensation ratio of 0.9 and an acoustic deformation potential of 6 eV. The Hall mobility data are analyzed assuming the carrier scattering by acoustic and polar optical phonons, and ionized impurities.Article Citation Count: 12Cd-doping effects on the properties of polycrystalline α-In2Se3 thin films(Wiley-v C H verlag Gmbh, 2002) Qasrawı, Atef Fayez Hasan; Department of Electrical & Electronics EngineeringThe X-ray diffraction has revealed that the polycrystalline hexagonal structured alpha-In2Se3 thin films grown at substrate temperature of 200degreesC with the unit cell parameters a=4.03degreesA and c=19.23degreesA becomes polycrystalline hexagonal structured InSe with a unit cell parameters of a=4.00degreesA and c=16.63degreesA by Cd-doping. The analysis of the conductivity temperature dependence in the range 300-40 K revealed that the thermionic emission of charged carriers and the variable range hopping are the predominant conduction mechanism above and below 100 K, respectively. Hall measurements revealed that the mobility is limited by the scattering of charged carriers through the grain boundaries above 200 K and 120 K for the undoped and Cd-doped samples, respectively. The photocurrent (I-ph) increases with increasing illumination intensity (T) and decreasing temperature up to a maximum temperature of similar to100 K, below which I-ph is temperature invariant. It is found to have the monomolecular and bimolccular recombination characters at low and high illumination intensities, respectively. The Cd-doping increases the density of trapping states that changes the position of the dark Fermi level leading to the deviation from linearity in the dependence of I-ph on F at low illumination intensities.Article Citation Count: 20Characterization of p-In2Se3 thin films(Kluwer Academic Publ, 2001) Qasrawı, Atef Fayez Hasan; Parlak, M; Erçelebi, Ç; Günal, I; Department of Electrical & Electronics EngineeringIndium selenide thin films were deposited onto glass substrates kept at 150 degreesC by thermal evaporation of alpha -In2Se3. Some of the films were annealed at 150 degreesC and 200 degreesC and they all were found to exhibit p-type conductivity without intentional doping. Scanning electron microscopy (SEM) established that the films have an atomic content of In51Se49. X-ray diffraction (XRD) indicated that the as-grown films were amorphous in nature and became polycrystalline \beta-In2Se3 films after annealing. The analysis of conductivity temperature-dependence measurements in the range 320-100 K revealed that thermal excitation and thermionic emission of the carriers are the predominant conduction mechanisms above 200 K in the amorphous and polycrystalline samples, respectively. The carrier transport below 200 K is due to variable range hopping in all the samples. Hall measurements revealed that the mobility of the polycrystalline films is limited by the scattering of the charged carriers through the grain boundaries above 200 K. (C) 2001 Kluwer Academic Publishers.Article Citation Count: 25Crystal data, electrical resistivity, and Hall mobility of n-type AgIn5S8 single crystals(Wiley-v C H verlag Gmbh, 2001) Qasrawı, Atef Fayez Hasan; Gasanly, NM; Department of Electrical & Electronics EngineeringThe X-ray diffraction has revealed that AgIn5S8 is a single phase crystal of cubic spinel structure. The value of the unit cell parameter for this crystal is 1.08286 nm. The electrical resistivity and Hall effect of n-type AgIn5S8 crystals are measured in the temperature range of 50-400 K. A carrier effective mass of 0.20 m(0), an acceptor to donor concentration ratio of 0.8 and an acoustic phonons deformation potential of 20 eV are identified from the Hall effect measurement. The Hall mobility data art: analyzed assuming the carrier scattering by acoustic and polar optical phonons, and ionized impurities.Article Citation Count: 19Crystal data, photoconductivity and carrier scattering mechanisms in CuIn5S8 single crystals(Wiley-v C H verlag Gmbh, 2001) Qasrawı, Atef Fayez Hasan; Gasanly, NM; Department of Electrical & Electronics EngineeringThe X-ray diffraction has revealed that CuIn5S8 is a single phase crystal of cubic spinet structure. The value of the unit cell parameter for this crystal is 1.06736 nm. The crystal is assigned to the conventional space group Fd3m. The photocurrent is found to have the characteristic of monomolecular and bimolecular recombination at low and high illumination intensities, respectively. The electrical resistivity and Hall effect of CuIn5S8 crystals are measured in the temperature range of 50-400 K. The crystals are found to be intrinsic and extrinsic above and below 300 K, respectively. An energy band gap of similar to1.35 eV at 0 K, a carrier effective mass of 0.2 m(0), an acceptor to donor concentration ratio of 0.9, an acoustic phonon deformation potential of 10 eV and a nonpolar optical phonon deformation potential of 15 eV are identified from the resistivity and Hall measurements. The Hall mobility data are analyzed assuming the carrier scattering by polar optical phonons, acoustic combined with nonpolar optical phonons, and ionized impurities.Article Citation Count: 10Dispersive optical constants and temperature-dependent band gap of cadmium-doped indium selenide thin films(Iop Publishing Ltd, 2005) Qasrawı, Atef Fayez Hasan; Department of Electrical & Electronics Engineering; Department of Electrical & Electronics EngineeringPolycrystalline cadmium-doped indium selenide thin films were obtained by the thermal co-evaporation of alpha-In2Se3 crystals and Cd onto glass substrates kept at a temperature of 200 degrees C. The temperature dependence of the optical band gap in the temperature region of 300-450 K and the room temperature refractive index, n(lambda), of these films have been investigated. The absorption edge shifts to lower energy as temperature increases. The fundamental absorption edge corresponds to a direct energy gap that exhibits a temperature coefficient of -6.14 x 10(-4) eV K-1. The room temperature n(lambda) which was calculated from the transmittance data allowed the identification of the oscillator strength and energy, static and lattice dielectric constants and static refractive index as 20.06 and 3.07 eV, 7.43 and 10.52 and 2.74, respectively.Article Citation Count: 28Electrical conductivity and Hall mobility in p-type TlGaSe2 crystals(Pergamon-elsevier Science Ltd, 2004) Qasrawı, Atef Fayez Hasan; Gasanly, NM; Department of Electrical & Electronics EngineeringSystematic dark electrical conductivity and Hall mobility measurements have been carried out in the temperature range of 200-350 K on p-type TlGaSe2 crystals. The analysis of the temperature-dependent electrical conductivity and carrier concentration reveals the extrinsic type of conduction with an acceptor impurity level located at 0.33 eV, and donor and acceptor concentrations of 9.0 x 10(15) and 1.3 x 10(16) cm(-3), respectively. A hole and electron effective masses of 0.520m(0) and 0.325m(0), respectively, with a donor to acceptor compensating ratio of 0.69 are also being identified. The Hall mobility is found to be limited by the hole-phonon short-range interactions scattering with a hole-phonon coupling constant of 0.17. (C) 2004 Elsevier Ltd. All rights reserved.Article Citation Count: 3Electrical, optical and photoconductive properties of poly(dibenzo-18-crown-6)(Wiley-v C H verlag Gmbh, 2004) Qasrawı, Atef Fayez Hasan; Cihaner, A; Cihaner, Atilla; Department of Electrical & Electronics Engineering; Chemical EngineeringTo investigate the energy levels, absorption bands, band gap, dominant transport mechanisms, recombination mechanisms and the free carrier life time behavior of poly-dibenzo-18-crown-6, poly-DB18C6, films, the dark electrical conductivity in the temperature range of 200-550 K, the absorbance and photocurrent spectra, the photocurrent -illumination intensity and time dependence at 300 K were studied. The dark electrical conductivity measurements revealed the existence of three energy levels located at 0.93, 0.32 and 0.76 eV below the tails of the conduction band. The main transport mechanism in the dark was found to be due to the thermal excitation of charge carriers and the variable range hopping above and below 260 K, respectively. The photocurrent and absorbance spectra reflect a band gap of 3.9 eV. The photocurrent -illumination intensity dependence reflects the sublinear, linear and supralinear characters indicating the decrease, remaining constant and increase in the free electron life time that in turn show the bimolecular, strong and very strong recombination characters at the surface under the application of low, moderate and high illumination intensity, respectively. A response time of 25.6 s was calculated from the decay Of I-ph-time dependence. (C) 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.Article Citation Count: 25Etectron-phonon short-range interactions mobility and p- to n-type conversion in TlGaS2 crystal(Wiley-v C H verlag Gmbh, 2006) Qasrawı, Atef Fayez Hasan; Gasanly, NM; Department of Electrical & Electronics EngineeringThe conductivity type conversion from p- to n-type at a critical temperature of 315 K in TlGaS2 crystals is observed through the Hall effect measurements in the temperature range of 200-350 K. The analysis of the temperature-dependent electrical resistivity, Hall coefficient and carrier concentration data reveals the extrinsic type of conduction with donor impurity levels that behave as acceptor levels when are empty. The data analysis allowed the calculation of hole and electron effective masses of 0.36m(0) and 0.23m(0), respectively. In addition, the temperature-dependent Hall mobility is found to decrease with temperature following a logarithmic slope of similar to 1.6. The Hall mobility in the n-region is limited by the electron-phonon short-range interactions scattering with an electron-phonon coupling constant of 0.21. (c) 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.Article Citation Count: 11Fabrication and characterization of TO/GaSe/(Ag, Au) Schottky diodes(Iop Publishing Ltd, 2006) Qasrawı, Atef Fayez Hasan; Department of Electrical & Electronics Engineering; Department of Electrical & Electronics EngineeringThe optical properties of amorphous GaSe thin films deposited onto tin oxide (TO) coated glass substrates are presented for the purpose of using this material for the fabrication of metal-semiconductor devices. Specifically, the room temperature direct allowed and forbidden transition energy band gaps of glass/TO and glass/TO/GaSe films are estimated and found to exhibit values of 3.95 and 1.95 eV, respectively. The temperature dependence of the energy band gap of the glass/TO/GaSe is also studied in the temperature range of 295 - 450 K by means of optical transmittance and reflectance spectra. This study allowed the identification of the rate of change of the band gap with temperature as -5.0 x 10(-4) eV K-1 and the 0 K energy band gap as 2.1 eV. The above reported optical parameters of the glass/TO/GaSe structure seem to be suitable for semiconductor device production such as solar cell converters, metal - insulator - semiconductor (MIS), metal-oxide-semiconductor (MOS), MOSFET, etc devices. As an application, we have used the glass/TO/GaSe substrate for fabricating Schottky diodes using Ag and Au point contacts. The diodes are characterized by measuring the current (I) - voltage (V) characteristics at room temperature. The I - V curves exhibit rectifying properties. The I-V data analysis in the Schottky region (below 1.0 V) revealed barrier heights of 0.60 and 0.73 eV for Ag and Au point contacts, respectively.Article Citation Count: 25Fabrication and some physical properties of AgIn5S8 thin films(Elsevier Science Sa, 2004) Qasrawı, Atef Fayez Hasan; Kayed, TS; Kayed, Tarek Said; Erhan, İnci; Department of Electrical & Electronics Engineering; MathematicsAgIn5S8 thin films are deposited on glass substrates, kept at 300 K, by thermal evaporation of AgIn5S8 single crystals under the pressure of 10-5 Torr. The X-ray fluorescence analysis revealed that the films have a weight percentage of similar to11.5% Ag, 61.17% In, and 27.33% S which corresponds to 1:5:8 stoichiometric composition. X-ray analysis of the films reveals the polycrystalline nature of the films. The lattice parameter (a) of the films was calculated to be 10.784(5) Angstrom. The dark n-type electrical conductivity of the films was measured in the temperature range of 30-350 K. The conductivity data analysis shows that the thermionic emission of the charge carriers having activation energies of 147 and 224 meV in the temperature ranges of 130-230 and 240-350 K, respectively, are the dominant transport mechanism in the films. The variable range hopping transport mechanism is dominant below 130 K. The room temperature photocurrent-photon energy dependency predicts a band gap of 1.91 eV of the films. The illumination intensity-photocurrent dependency measured in the intensity range of 13-235 W cm(-2) reveals monomolecular recombination (linear) in the films and bimolecular recombination (sublinear) at the film surface corresponding to low and high applied illumination intensities, respectively. The time-dependant photocurrent measured at fixed illumination intensity reveals a response time of 0.85, 2.66 and 10.0 s in the time periods of 0-0.5, 0.5-1.0, and 1.0-10.0 s, respectively. (C) 2004 Elsevier B.V. All rights reserved.Article Citation Count: 15Growth, electrical and structural characterization of β-GaSe thin films(Springer, 2003) Qasrawı, Atef Fayez Hasan; Qasrawi, AF; Erçelebi, Ç; Department of Electrical & Electronics EngineeringGaSe thin films were deposited onto the glass substrates kept at 200degrees and 300degreesC by the thermal evaporation of GaSe crystals under the pressure of 10(-5) Torr. X-ray analysis of the films revealed that films grown at 200. C are amorphous in nature while the films grown at 300degreesC are polycrystalline beta-GaSe. The temperature dependent electrical conductivity measurements in the region of 320-100 K for the films grown at 300degreesC showed that the transport mechanisms are the thermionic emission of charged carriers and the variable range hopping above and below 180 K, respectively. Space charge limited current (SCLC) studies have also been performed on these films through the current-voltage measurements at different temperatures and a dominant hole trap at 0.233 eV from the top of the valance band with a trap density of similar to1.6 x 10(11) cm(-3) is identified. (C) 2003 Kluwer Academic Publishers.Article Citation Count: 31Hall effect, space-charge limited current and photoconductivity measurements on TlGaSe2 layered crystals(Iop Publishing Ltd, 2004) Qasrawı, Atef Fayez Hasan; Gasanly, NM; Department of Electrical & Electronics EngineeringTlGaSe2 layered crystals are studied through dark electrical conductivity, Hall mobility, space-charge limited current and illumination- and temperature-dependent photoconductivity in the temperature ranges 120-350 K, 220-350 K, 260-350 K and 120-350 K, respectively. The Hall effect measurements revealed the extrinsic p-type conduction. The Hall mobility increase with decreasing temperature is limited by the thermal lattice scattering. The space-charge limited current and dark conductivity measurements predicted the existence of a single discrete trapping level located at 330 meV with a trap concentration of (1.4-2.2) x 10(13) cm(-3). The dark electrical conductivity and photoconductivity measurements reflect the existence of three other energy levels located at 95, 46 and 26 meV at high, moderate and low temperatures, respectively. The photocurrent is observed to increase with increasing temperature up to a maximum temperature of 320 K. The illumination dependence of photoconductivity is found to exhibit sublinear, linear and supralinear recombinations at high, moderate and low temperatures, respectively. The change in recombination mechanism is attributed to the exchange in the behaviour of sensitizing and recombination centres.Article Citation Count: 20Investigation of carrier scattering mechanisms in TIInS2 single crystals by Hall effect measurements(Wiley-v C H verlag Gmbh, 2004) Qasrawı, Atef Fayez Hasan; Gasanly, NM; Department of Electrical & Electronics EngineeringTlInS2 single crystals are studied through the conductivity and Hall effect measurements in the temperature regions of 100-400 and 170-400 K, respectively. An anomalous behavior of Hall voltage, which changes sign below 315 K, is interpreted through the existence of deep donor impurity levels that behave as acceptor levels when are empty. The hole and electron mobility are limited by the hole- and electron-phonon short range interactions scattering above and below 315 K, respectively. An energy level of 35 meV and a set of donor energy levels located at 360, 280, 220 and 170/152 meV are determined from the temperature dependencies of the carrier concentration and conductivity. A hole, electron, hole-electron pair effective masses of 0.24 in,, 0.14 m(o) and 0.09 m(o) and hole- and electron-phonon coupling constants of 0.50 and 0.64, respectively, are obtained from the Hall effect measurements. The theoretical fit of the Hall coefficient reveals a hole to electron mobility ratio of 0.8. (C) 2004 WILEY-VCH Verlag Gmbh & Co. KGaA, Weinheim.Article Citation Count: 17Investigation of localized levels in GaS0.5Se0.5 layered crystals by means of electrical, space-charge limited current and photoconductivity measurements(Wiley-v C H verlag Gmbh, 2002) Qasrawı, Atef Fayez Hasan; Gasanly, NM; Department of Electrical & Electronics EngineeringTo identify the localized levels in GaS0.5Se0.5 single crystals, the dark electrical conductivity, current-voltage characteristics and photoconductivity measurements were carried out in the temperature range of 250-400 K. Temperature dependence of dark electrical conductivity and the space-charge limited current studies indicate the presence of a single discrete trapping level located at 0.31 eV below the conduction band with a density of about 1.3 x 10(15) cm(-3). The conductivity data above 320 K reveal an additional donor level with activation energy of 0.40 eV indicating the extrinsic nature of conduction. The spectral distribution of photocurrent in the photon energy range of 0.65-5.9 eV reveals an indirect band gap of 2.26 eV. The photocurrent-illumination intensity dependence follows the law I-ph proportional to F-gamma, with gamma being 1.0, 0.65, and 0.5 at low, moderate and high illumination intensities, respectively. The corresponding behavior indicates the domination of monomolecular recombination, near equal densities of trapped and recombination centers and bimolecular recombination. It is observed that the photocurrent increases in the temperature range from 250 K up to T-m = 360 K and decreases for T > T-m. The temperature dependence of the photocurrent reveals two additional impurity levels with activation energies of 0.14 and 0.10 eV below and above Tm, respectively.Article Citation Count: 12Light illumination effect on the electrical and photovoltaic properties of In6S7 crystals(Iop Publishing Ltd, 2006) Qasrawı, Atef Fayez Hasan; Gasanly, NM; Department of Electrical & Electronics EngineeringThe electrical and photoelectrical properties of In6S7 crystals have been investigated in the temperature regions of 170-300 K and 150-300 K, respectively. The dark electrical analysis revealed the intrinsic type of conduction. The energy band gap obtained from the temperature-dependent dark current is found to be 0.75 eV. It is observed that the photocurrent increases in the temperature range of 150 K up to T-m = 230 K and decreases at T > T-m. Two photoconductivity activation energies of 0.21 and 0.10 eV were determined for the temperature ranges below and above Tm, respectively. The photocurrent (I-ph)-illumination intensity (F) dependence follows the law I-ph alpha F-gamma. The value of. decreases when the temperature is raised to T-m, then it starts increasing. The change in the value. with temperature is attributed to the exchange in role between the recombination and trapping centres in the crystal. The crystals are found to exhibit photovoltaic properties. The photovoltage is recorded as a function of illumination intensity at room temperature. The maximum open-circuit voltage and short-circuit photocurrent density, which are related to an illumination intensity equivalent to one sun, are 0.12 V and 0.38 mA cm(-2), respectively.Article Citation Count: 27Optoelectronic and electrical properties of TlGaS2 single crystal(Wiley-v C H verlag Gmbh, 2005) Qasrawı, Atef Fayez Hasan; Gasanly, NM; Department of Electrical & Electronics EngineeringThe optoelectronic and electrical properties of TIGaS2 single crystals have been investigated by means of room temperature transmittance and reflectance spectral analysis, Hall coefficient, dark electrical resistivity and photocurrent measurements in the temperature range of 200-350 K. The optical data have revealed an indirect and direct allowed transition band gaps of 2.45 and 2.51 eV, an oscillator and dispersion energy of 5.04 and 26.45 eV, respectively, a static dielectric constant of 6.25 and static refractive index of 2.50. The dark Hall coefficient measurements have shown that the crystals exhibit a conductivity type conversion from p-type to n-type at a critical temperature of 315 K. Deep donor and acceptor energy levels of 0.37/0.36 eV and 0.66 eV has been calculated from the temperature dependence of Hall coefficient and resistivity, and photocurrent measurements, respectively. The photocurrent decreases with decreasing temperature. The analysis of the photocurrent data have revealed that, the recombination mechanism is linear and supralinear above and below 290 K, respectively. (c) 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.Article Citation Count: 28Optoelectronical properties of polycrystalline β-GaSe thin films(Wiley-v C H verlag Gmbh, 2006) Qasrawı, Atef Fayez Hasan; Ahmad, MMS; Department of Electrical & Electronics EngineeringPolycrystalline beta-GaSe thin films were obtained by the thermal evaporation of GaSe crystals onto glass substrates kept at 300 degrees C under a pressure of 10(-5) Torr. The transmittance and reflectance of these films was measured in the incident photon energy range of 1.1-3.70 eV. The absorption coefficient spectral analysis in the sharp absorption region revealed a direct allowed transitions band gap of 1.83 eV. The data analysis allowed the identification of the dispersive optical parameters by calculating the refractive index in the wavelength region of 620-1100 nm. In addition, the photocurrent of the samples was studied as function of incident illumination-intensity and temperature. The photocurrent is found to exhibit sublinear and supralinear character above and below 270 K, respectively. The temperature dependent photocurrent data analysis allowed the calculation of photocurrent activation energies as 603, 119 and 45 meV being dominant in the temperature regions of 250-300 K, 180-240 K and 80-160 K, respectively. (c) 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.Article Citation Count: 26Photoelectronic and electrical properties of CuIn5S8 single crystals(Wiley-v C H verlag Gmbh, 2003) Qasrawı, Atef Fayez Hasan; Gasanly, NM; Department of Electrical & Electronics EngineeringTo identify the impurity levels in CuIn5S8 single crystals, the dark electrical conductivity and photoconductivity measurements were carried out in the temperature range of 50-460 K. The data reflect the intrinsic and extrinsic nature of the crystals above and below 300 K, respectively. Energy band gaps of 1.35 and 1.31 eV at 0 K and 300 K, were defined from the dark conductivity measurements and the photocurrent spectra, respectively. The dark and photoconductivity data in the extrinsic temperature region reflect the existence of two independent donor energy levels located at 130 and 16 meV. The photocurrent-illumination intensity dependence (F) follows the law I(ph)alphaF(gamma), with gamma being 1.0, 0.5 and 1.0 at low, moderate and high intensities indicating the domination of monomolecular, bimolecular and strong recombination at the surface, respectively. In the intrinsic region and in the temperature region where the shallow donor energy level 16 meV is dominant, the free electron life time, tau(n), is found to be constant with increasing F. In the temperature region 140 K < T < 210 K, the free electron life time increases with increasing illumination intensity showing the supralinear character. Below 140 K, tau(n) decrease with decreasing illumination intensity. (C) 2003 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.