Electrochemical copolymerization of thiophene containing pseudo-polyether cages with pyrrole

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Date

2006

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Tubitak Scientific & Technological Research Council Turkey

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Chemical Engineering
(2010)
Established in 2010, and aiming to train the students with the capacity to meet the demands of the 21st Century, the Chemical Engineering Department provides a sound chemistry background through intense coursework and laboratory practices, along with fundamental courses such as Physics and Mathematics within the freshman and sophomore years, following preparatory English courses.In the final two years of the program, engineering courses are offered with laboratory practice and state-of-the-art simulation programs, combining theory with practice.

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Abstract

Conducting copolymers were synthesized via the electrochemical oxidation of pyrrole (Py) in the presence of the monomer 1,12-bis(2-thienyl)-2,5,8,11-tetraoxadodecane (1). The presence of monomer I in the electrolytic solution greatly changed the CV behavior of Py during its potensiodynamic polymerization. The electroactivity of poly(I-co-Py) increased with the increasing amount of I in the comonomer mixture. Copolymer films were prepared via constant potential electrolysis in an electrolytic solution containing 0.1 M tetrabutylammonium hexafluorophosphate (TBAPF(6)) dissolved in acetonitrile. The spectroelectrochemical properties of the films were investigated using UV-VIS spectroscopy.

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Onal, Ahmet M./0000-0003-0644-7180
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Onal, Ahmet M. ORCID logo

Keywords

electrochemical polymerization, spectroelectrochemistry, polymer containing pseudopolyether cages

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0

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Volume

30

Issue

5

Start Page

629

End Page

634

URI

https://search.trdizin.gov.tr/en/yayin/detay/64324/electrochemical-copolymerization-of-thiophene-containing-pseudo-polyether-cages-with-pyrrole
 https://hdl.handle.net/20.500.14411/8742

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