Electrosynthesis of Polyfuran in Acetonitrile-Boron Trifluoride-Ethyl Ether Mixture and Its Device Application
| dc.authorid | Onal, ahmet muhtar/0000-0003-0644-7180 | |
| dc.authorscopusid | 7801644024 | |
| dc.authorscopusid | 7004825485 | |
| dc.authorwosid | Onal, ahmet muhtar/AAS-5007-2020 | |
| dc.contributor.author | Tirkes, Seha | |
| dc.contributor.author | Onal, Ahmet M. | |
| dc.contributor.other | Chemical Engineering | |
| dc.date.accessioned | 2024-07-05T14:33:49Z | |
| dc.date.available | 2024-07-05T14:33:49Z | |
| dc.date.issued | 2007 | |
| dc.department | Atılım University | en_US |
| dc.department-temp | Middle E Tech Univ, Dept Chem, TR-06521 Ankara, Turkey; Atilim Univ, Dept Mat Engn, TR-06836 Ankara, Turkey | en_US |
| dc.description | Onal, ahmet muhtar/0000-0003-0644-7180 | en_US |
| dc.description.abstract | Electrochemical polymerization of furan was achieved in acetonitrile/boron trifluoride/ethyl ether (CH3 CN/BF3/EE) mixture in the presence of tetrabutylammonium tetrafluoroborate via constant potential electrolysis at 1.4 V versus Ag/AgCl. Electrochemical behavior of furan was investigated in the same solvent mixture of varying ratios, utilizing cyclic voltammetry. Free-standing polyfuran (PFu) films were obtained in CH3CN/BF3/EE mixture (2/4/4; v/v/v) and characterized using FTIR spectroscopic technique. Spectroelectrochemical behavior of the PFu film was investigated by recording the electronic absorption spectra, in sitn, in monomer-free solution. It is observed that PFu film can be reversibly cycled between -0.1 V (gray) and + 0.6 V versus Ag-wire (gray color); however, this behavior diminishes in the presence of water. Electrochromic device application of PFu film with poly(ethylene dioxythiophene) was also studied. (c) 2006 Wiley Periodicals, Inc. | en_US |
| dc.identifier.citationcount | 13 | |
| dc.identifier.doi | 10.1002/app.25220 | |
| dc.identifier.endpage | 876 | en_US |
| dc.identifier.issn | 0021-8995 | |
| dc.identifier.issue | 2 | en_US |
| dc.identifier.scopus | 2-s2.0-33845979790 | |
| dc.identifier.startpage | 871 | en_US |
| dc.identifier.uri | https://doi.org/10.1002/app.25220 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14411/963 | |
| dc.identifier.volume | 103 | en_US |
| dc.identifier.wos | WOS:000242468700028 | |
| dc.identifier.wosquality | Q2 | |
| dc.institutionauthor | Tirkeş, Seha | |
| dc.language.iso | en | en_US |
| dc.publisher | John Wiley & Sons inc | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.scopus.citedbyCount | 16 | |
| dc.subject | polyfuran | en_US |
| dc.subject | electrochemistry | en_US |
| dc.subject | electrochromic properties | en_US |
| dc.subject | device application | en_US |
| dc.subject | spectroelectrochemistry | en_US |
| dc.subject | cyclic voltammetry | en_US |
| dc.title | Electrosynthesis of Polyfuran in Acetonitrile-Boron Trifluoride-Ethyl Ether Mixture and Its Device Application | en_US |
| dc.type | Article | en_US |
| dc.wos.citedbyCount | 14 | |
| dspace.entity.type | Publication | |
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