A novel terthienyl based polymer electrochrome with peripheral BODIPY

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2012

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Elsevier Sci Ltd

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Chemical Engineering
(2010)
Established in 2010, and aiming to train the students with the capacity to meet the demands of the 21st Century, the Chemical Engineering Department provides a sound chemistry background through intense coursework and laboratory practices, along with fundamental courses such as Physics and Mathematics within the freshman and sophomore years, following preparatory English courses.In the final two years of the program, engineering courses are offered with laboratory practice and state-of-the-art simulation programs, combining theory with practice.

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Abstract

Design, synthesis and electropolymerization of a new hybrid material based on terthienyl system bearing BODIPY appendage are reported. This electrochemically polymerized unique combination readily gives an electrochromic polymer with a narrow optical band gap (1.71 eV). The electrochrome exhibits purple color when neutralized and sky blue color when oxidized in a monomer-free electrolyte solution containing 0.1 M tetrabutylammonium tetrafluoroborate dissolved in acetonitrile. Spectroscopic and electrochemical features of the electroactive polymer electrochrome indicate that it is a promising candidate for electrochromic device and display applications. (C) 2012 Elsevier Ltd. All rights reserved.

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Algi, Fatih/0000-0001-9376-1770;
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Bodipy, Terthienyl, Electrochromic

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Volume

53

Issue

16

Start Page

3469

End Page

3475

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https://doi.org/10.1016/j.polymer.2012.06.007
 https://hdl.handle.net/20.500.14411/464

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