Performance analysis of CuSbSe2 thin-film solar cells with Cd-free window layers

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2024

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Elsevier

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Electrical-Electronics Engineering
The Department of Electrical and Electronics Engineering covers communications, signal processing, high voltage, electrical machines, power distribution systems, radar and electronic warfare, RF, electromagnetic and photonics topics. Most of the theoretical courses in our department are supported by qualified laboratory facilities. Our department has been accredited by MÜDEK since 2013. Within the scope of joint training (COOP), in-company training opportunities are offered to our students. 9 different companies train our students for one semester within the scope of joint education and provide them with work experience. The number of students participating in joint education (COOP) is increasing every year. Our students successfully completed the joint education program that started in the 2019-2020 academic year and started work after graduation. Our department, which provides pre-graduation opportunities to its students with Erasmus, joint education (COOP) and undergraduate research projects, has made an agreement with Upper Austria University of Applied Sciences (Austria) starting from this year and offers its students undergraduate (Atılım University) and master's (Upper Austria) degrees with 3+2 education program. Our department, which has the only European Remote Radio Laboratory in Foundation Universities, has a pioneering position in research (publication, project, patent).

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Abstract

This study investigates novel thin-film solar cells featuring CuSbSe2 (CASe) with ZnSnO and ZnMgO windows in the layer superstrate structure. For glass/ITO/ZnMgO/CASe/Cu + Au, the J-V measurements reveal a shortcircuit current density (Jsc) of 19.4 mA/cm2, an open-circuit voltage (Voc) of 0.28 Volts, a fill factor (FF) of 39.14 %, and a power conversion efficiency (eta) of 2.13 %. Similarly, glass/ITO/ZnSnO/CASe/Cu + Au exhibits Jsc around 19.6 mA/cm2, Voc around 0.31 Volts, FF around 40 %, and eta of 2.43 %. This paper is a pioneering contribution, introducing novel thin-film solar cells with a distinctive superstrate structure utilizing CASe in conjunction with ZnSnO and ZnMgO windows. The comprehensive study presents the first-ever characterization and performance evaluation of these innovative configurations, shedding light on their unique potential in advancing sustainable solar energy technology.

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SURUCU, Gokhan/0000-0002-3910-8575; SURUCU, Özge/0000-0002-8478-1267

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Thin Films, Physical vapor deposition, Energy storage and conversion

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363

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