Electrochemical Polymerization of 9-Fluorenone

No Thumbnail Available

Date

2004

Authors

Journal Title

Journal ISSN

Volume Title

Publisher

Elsevier Science Sa

Open Access Color

OpenAIRE Downloads

OpenAIRE Views

Research Projects

Organizational Units

Thumbnail Image
Organizational Unit
Chemical Engineering
(2010)
Established in 2010, and aiming to train the students with the capacity to meet the demands of the 21st Century, the Chemical Engineering Department provides a sound chemistry background through intense coursework and laboratory practices, along with fundamental courses such as Physics and Mathematics within the freshman and sophomore years, following preparatory English courses.In the final two years of the program, engineering courses are offered with laboratory practice and state-of-the-art simulation programs, combining theory with practice.

Journal Issue

Events

Abstract

Electrochemical polymerization of 9-fluorenone, FO, was studied in CH2Cl2 solution with tetrabutylammonium tetrafluoroborate, TBABF(4), as the electrolyte, via constant potential electrolysis, CPE. Prior to CPE, the redox behavior of FO was investigated in the same solvent/electrolytic medium using cyclic voltammetry, CV. CPE of FO yielded an insoluble polymer deposit on the electrode surface. The product was characterized by FTIR spectroscopy techniques. The redox and spectroelectrochernical, SPEL, behavior of the polymer were studied by CV and in situ UV-Vis spectrophotometric techniques at various potentials, respectively. The conductivity was measured using a two-probe technique and the paramagnetic behavior of the polymer was monitored using in situ ESR spectroscopy. (C) 2004 Elsevier B.V. All rights reserved.

Description

Onal, ahmet muhtar/0000-0003-0644-7180;
ORCID
Onal, ahmet muhtar ORCID logo

Keywords

polyfluorenone, electrochemical polymerization, SPEL, ESR

Turkish CoHE Thesis Center URL

Fields of Science

Citation

WoS Q

Q1

Scopus Q

Q2

Source

Volume

568

Issue

1-2

Start Page

151

End Page

156

URI

https://doi.org/10.1016/j.jelechem.2004.01.027
 https://hdl.handle.net/20.500.14411/1087

Collections

WOS
Scopus