Chromium based metal-organic framework MIL-101 decorated palladium nanoparticles for the methanolysis of ammonia-borane

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2020

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Royal Soc Chemistry

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Chemical Engineering
(2010)
Established in 2010, and aiming to train the students with the capacity to meet the demands of the 21st Century, the Chemical Engineering Department provides a sound chemistry background through intense coursework and laboratory practices, along with fundamental courses such as Physics and Mathematics within the freshman and sophomore years, following preparatory English courses.In the final two years of the program, engineering courses are offered with laboratory practice and state-of-the-art simulation programs, combining theory with practice.

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Abstract

Palladium nanoparticles stabilized by an MIL-101 metal-organic framework (Pd@MIL-101) are synthesized by a novel synthesis approach. A Pd@MIL-101 catalyst facilitates H(2)generation from the methanolysis of ammonia-borane with record catalytic activity (TOF = 1080 min(-1)) at room temperature. Moreover, the exceptional stability of Pd@MIL-101 makes it a reusable heterogeneous catalyst in this catalytic transformation.

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Yurderi, Mehmet/0000-0002-0233-8940; Kaya, Murat/0000-0002-2458-8924; Bulut, ahmet/0000-0002-1697-8623
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Yurderi, Mehmet ORCID logo
Kaya, Murat ORCID logo
Bulut, ahmet ORCID logo

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8

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44

Issue

29

Start Page

12435

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12439

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https://doi.org/10.1039/d0nj01931c
 https://hdl.handle.net/20.500.14411/3234

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