Spectroelectrochemical investigation of the anodic oxidation of dibenzo-18-crown-6

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Date

2004

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Elsevier Science Sa

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Chemical Engineering
(2010)
Established in 2010, and aiming to train the students with the capacity to meet the demands of the 21st Century, the Chemical Engineering Department provides a sound chemistry background through intense coursework and laboratory practices, along with fundamental courses such as Physics and Mathematics within the freshman and sophomore years, following preparatory English courses.In the final two years of the program, engineering courses are offered with laboratory practice and state-of-the-art simulation programs, combining theory with practice.

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Abstract

Poly(dibenzo-18-crown-6) (poly-DB18C6) was synthesized by electrochemical oxidation of dibenzo-18-crown-6 (DB18C6) using a mixture of acetonitrile and dichloromethane as the solvent and tetrabutylammonium tetrafluoroborate (TBABF(4)) or tetrabutylammonium hexafluorophosphate (TBAPF(6)) as supporting electrolyte. The anodic polymerization of DB18C6 was investigated using in situ ESR and in situ UV-Vis spectroscopic techniques. Spectroelectrochemical (SPEL), properties and thermal analysis of the resulting polymers have been investigated using UV-Vis spectroscopy, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). (C) 2004 Elsevier B.V. All rights reserved.

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Onal, ahmet muhtar/0000-0003-0644-7180

Keywords

electrochemical polymerization, spectroelectrochemical properties, thermal analysis, ESR, poly(dibenzo-18-crown-6)

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1

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Volume

571

Issue

2

Start Page

159

End Page

167

URI

https://doi.org/10.1016/j.jelechem.2004.05.005
 https://hdl.handle.net/20.500.14411/1109

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