Nanocrystalline Metal Organic Framework (mil-101) Stabilized Copper Nanoparticles: Highly Efficient Nanocatalyst for the Hydrolytic Dehydrogenation of Methylamine Borane

dc.authorid Bulut, ahmet/0000-0002-1697-8623
dc.authorid Ertas, Ilknur Efecan/0000-0003-0997-7523
dc.authorid Yurderi, Mehmet/0000-0002-0233-8940
dc.authorid Kaya, Murat/0000-0002-2458-8924
dc.authorscopusid 57200578192
dc.authorscopusid 22834502900
dc.authorscopusid 56226173500
dc.authorscopusid 56226100100
dc.authorscopusid 14521641300
dc.authorscopusid 57206407342
dc.authorwosid Bulut, ahmet/G-7667-2018
dc.authorwosid Ertas, Ilknur Efecan/P-5616-2019
dc.authorwosid Zahmakiran, Mehmet/F-7120-2014
dc.authorwosid Yurderi, Mehmet/I-5456-2019
dc.contributor.author Baguc, Ismail Burak
dc.contributor.author Ertas, Ilknur Efecan
dc.contributor.author Yurderi, Mehmet
dc.contributor.author Bulut, Ahmet
dc.contributor.author Zahmakiran, Mehmet
dc.contributor.author Kaya, Murat
dc.contributor.other Chemical Engineering
dc.date.accessioned 2024-07-05T15:27:06Z
dc.date.available 2024-07-05T15:27:06Z
dc.date.issued 2018
dc.department Atılım University en_US
dc.department-temp [Baguc, Ismail Burak; Ertas, Ilknur Efecan; Yurderi, Mehmet; Bulut, Ahmet; Zahmakiran, Mehmet] Yuzuncu Yil Univ, Dept Chem, Nanomat & Catalysis Res Grp, TR-65080 Van, Turkey; [Kaya, Murat] Atilim Univ, Dept Chem Engn & Appl Chem, TR-06836 Ankara, Turkey en_US
dc.description Bulut, ahmet/0000-0002-1697-8623; Ertas, Ilknur Efecan/0000-0003-0997-7523; Yurderi, Mehmet/0000-0002-0233-8940; Kaya, Murat/0000-0002-2458-8924 en_US
dc.description.abstract The copper nanoparticles stabilized by nanocrystalline MIL-101 framework (Cu/nano-MIL-101) was reproducibly prepared by following double solvent method combined with liquid phase chemical reduction technique. The characterization of the resulting new material was done by using various analytical techniques including ICP-OES, P-XRD, N-2-adsorption-desorption, XPS, FE-SEM, SEM-EDX, BFTEM and HAADF-STEM; the summation of their results reveals that the formation of well-dispersed and very small sized (0.8 nm) copper nanoparticles within nanocrystalline MIL-101 framework. The catalytic performance of Cu/nano-MIL-101 in terms of activity and stability was tested in the hydrolytic dehydrogenation of methylamine borane (CH3NH2BH3), which has been considered as one of the attractive materials for the efficient chemical hydrogen storage. Cu/nano-MIL-101 catalyzes the hydrolytic dehydrogenation of methylamine borane with high activity (turnover frequency; TOF = 257 mot H-2/mol Cu x h) and conversion ( > 99%) under air at room temperature. Moreover, these nano-MIL-101 framework stabilized copper nanoparticles show great durability against to sintering and leaching, which make Cu/nano-MIL-101 reusable nanocatalyst in the hydrolytic dehydrogenation of methylamine-borane. Cu/nano-MIL-101 nanocatalyst retains 83% of its inherent activity at complete conversion even at 10th recycle in the hydrolytic dehydrogenation of methylamine borane. en_US
dc.description.sponsorship Research Fund of Yuzuncu Yil University Office of Scientific Research Project [FOA-2016-5376]; Fevzi Akkaya Scientific Activities Support Fund (FABED); Science Academy, and Turkish Academy of Sciences (TUBA) en_US
dc.description.sponsorship Authors thanks to the Research Fund of Yuzuncu Yil University Office of Scientific Research Project (FOA-2016-5376). Additionally, the partial supports by Fevzi Akkaya Scientific Activities Support Fund (FABED), Science Academy, and Turkish Academy of Sciences (TUBA) are gratefully acknowledged. en_US
dc.identifier.citationcount 23
dc.identifier.doi 10.1016/j.ica.2018.08.056
dc.identifier.endpage 439 en_US
dc.identifier.issn 0020-1693
dc.identifier.issn 1873-3255
dc.identifier.scopus 2-s2.0-85052893687
dc.identifier.startpage 431 en_US
dc.identifier.uri https://doi.org/10.1016/j.ica.2018.08.056
dc.identifier.uri https://hdl.handle.net/20.500.14411/2639
dc.identifier.volume 483 en_US
dc.identifier.wos WOS:000445543100055
dc.identifier.wosquality Q2
dc.institutionauthor Kaya, Murat
dc.language.iso en en_US
dc.publisher Elsevier Science Sa en_US
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.scopus.citedbyCount 27
dc.subject Methylamine borane en_US
dc.subject Metal organic framework en_US
dc.subject Copper en_US
dc.subject Dehydrogenation en_US
dc.subject Hydrogen en_US
dc.title Nanocrystalline Metal Organic Framework (mil-101) Stabilized Copper Nanoparticles: Highly Efficient Nanocatalyst for the Hydrolytic Dehydrogenation of Methylamine Borane en_US
dc.type Article en_US
dc.wos.citedbyCount 23
dspace.entity.type Publication
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