Spectroelectrochemical Investigation of Pentacarbonyl(pyrazine)metal(0) (metal = Cr, Mo, W) Complexes of Group 6 Elements
| dc.authorid | Onal, Ahmet M./0000-0003-0644-7180 | |
| dc.authorwosid | Yaman, Şeniz/AAK-1854-2021 | |
| dc.authorwosid | Onal, ahmet/AAS-5007-2020 | |
| dc.contributor.author | Yaman, SO | |
| dc.contributor.author | Esentürk, E | |
| dc.contributor.author | Kayran, C | |
| dc.contributor.author | Önal, AM | |
| dc.date.accessioned | 2024-10-06T10:57:31Z | |
| dc.date.available | 2024-10-06T10:57:31Z | |
| dc.date.issued | 2002 | |
| dc.department | Atılım University | en_US |
| dc.department-temp | Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey; Atilim Univ, Fac Engn, TR-06836 Ankara, Turkey | en_US |
| dc.description | Onal, Ahmet M./0000-0003-0644-7180 | en_US |
| dc.description.abstract | The electrochemical behaviour of pentacarbony l(pyrazine) metal (0) complexes of the group 6 elements was studied by cyclic voltammetry in dichloromethane-(n-Bu)(4)NBF4 solvent-electrolyte couple at -20 degreesC vs. Ag/Ag+ or SCE reference electrode. Constant potential electrolyses of the complexes were carried out at their first oxidation peak potentials and monitored in situ by UV-Vis spectrometry. Electrolysis of W(CO)(5)pz produces [W(CO)(5)pz](+) and a similar electrochemical mechanism is expected both for Cr(CO)(5)pz and Mo(CO)(5)pz complexes. In situ low temperature constant current ESR electrolysis also confirmed the production of [W(CO)(5)pz](+) after the electron transfer. | en_US |
| dc.description.woscitationindex | Science Citation Index Expanded | |
| dc.identifier.citationcount | 1 | |
| dc.identifier.endpage | 98 | en_US |
| dc.identifier.issn | 0932-0776 | |
| dc.identifier.issn | 1865-7117 | |
| dc.identifier.issue | 1 | en_US |
| dc.identifier.scopusquality | Q3 | |
| dc.identifier.startpage | 92 | en_US |
| dc.identifier.uri | https://hdl.handle.net/20.500.14411/8733 | |
| dc.identifier.volume | 57 | en_US |
| dc.identifier.wos | WOS:000174273300011 | |
| dc.identifier.wosquality | Q4 | |
| dc.language.iso | en | en_US |
| dc.publisher | Walter de Gruyter Gmbh | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | pyrazine | en_US |
| dc.subject | metal carbonyls | en_US |
| dc.subject | cyclic voltammetry | en_US |
| dc.title | Spectroelectrochemical Investigation of Pentacarbonyl(pyrazine)metal(0) (metal = Cr, Mo, W) Complexes of Group 6 Elements | en_US |
| dc.type | Article | en_US |
| dc.wos.citedbyCount | 1 | |
| dspace.entity.type | Publication |