Diethanolamine Modified Perovskite-Substrate Interface for Realizing Efficient ESL-Free PSCs

The main fields of operation for Metallurgical and Materials Engineering are production of engineering materials, defining and improving their features, as well as developing new materials to meet the expectations at every aspect of life and the users from these aspects. Founded in 2004 and graduated its 10th-semester alumni in 2018, our Department also obtained MÜDEK accreditation in the latter year. Offering the opportunity to hold an internationally valid diploma through the accreditation in question, our Department has highly qualified and experienced Academic Staff. Many of the courses offered at our Department are supported with various practice sessions, and internship studies in summer. This way, we help our students become better-equipped engineers for their future professional lives. With the Cooperative Education curriculum that entered into effect in 2019, students may volunteer to work at contracted companies for a period of six months with no extensions to their period of study.

Abstract

Simplifying device layout, particularly avoiding the complex fabrication steps and multiple high-temperature treatment requirements for electron-selective layers (ESLs) have made ESL-free perovskite solar cells (PSCs) attractive. However, the poor perovskite/substrate interface and inadequate quality of solution-processed perovskite thin films induce inefficient interfacial-charge extraction, limiting the power conversion efficiency (PCEs) of ESL-free PSCs. A highly compact and homogenous perovskite thin film with large grains was formed here by inserting an interfacial monolayer of diethanolamine (DEA) molecules between the perovskite and ITO substrate. In addition, the DEA created a favorable dipole layer at the interface of perovskite and ITO substrate by molecular adsorption, which suppressed charge recombination. Comparatively, PSCs based on DEA-treated ITO substrates delivered PCEs of up to 20.77%, one of the highest among ESL-free PSCs. Additionally, this technique successfully elongates the lifespan of ESL-free PSCs as 80% of the initial PCE was maintained after 550 h under AM 1.5 G irradiation at ambient temperature.

Description

Sajid, Sajid/0000-0002-1165-1365; Park, Jongee/0000-0003-1415-6906; Ben Salem, Imen/0000-0002-3035-0402; Wei, Dong/0000-0002-6342-4658; Obaidat, Ihab M/0000-0002-7235-8998