İnger, Erk

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https://hdl.handle.net/20.500.14411/7012
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E., Inger
Erk, Inger
E.,Inger
Inger,E.
INGER, E
Inger, Erk
I.,Erk
Inger E.
I., Erk
Erk, İnger
Inger, E.
E., İnger
Erk, İnger
E.,İnger
İnger,E.
İnger, Erk
İnger, E.
Erk İnger
İnger, Erk
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Doçent Doktor
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erk.inger@atilim.edu.tr
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Airframe and Powerplant Maintenance
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0000-0002-1857-8180
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6507947540
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AGA-8800-2022

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Author: Inger, ErkSubject: adsorption

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    Article
    Citation - WoS: 4
    Citation - Scopus: 3
    Crosslinked Polyethyleneimine-Based Structures in Different Morphologies as Promising Co2 Adsorption Systems: a Comprehensive Study
    (Wiley, 2024) Demirci, Sahin; Inger, Erk; Bhethanabotla, Venkat; Sahiner, Nurettin
    Although there are many studies on CO2 adsorption via PEI-modified carbon particles, metal-organic frameworks, zeolitic imidazolate frameworks, and silica-based porous structures, only a limited number of studies on solely cross-linked PEI-based structures. Here, the CO2 adsorption capacities of PEI-based microgels and cryogels were investigated. The effects of various parameters influencing the CO2 adsorption capacity of PEI-based structures, for example, crosslinker types, PEI types (branched [bPEI] or linear [lPEI]), adsorbent types (microgel or cryogel), chemical-modification including their complexes were examined. NaOH-treated glycerol diglycidyl ether (GDE) crosslinked lPEI microgels exhibited higher CO2 adsorption capacity among other microgels with 0.094 +/- 0.006 mmol CO2/g at 900 mm Hg, 25 degrees C with 2- and 7.5-fold increase upon pentaethylenehexamine (PEHA) modification and Ba(II) metal ion complexing, respectively. The CO2 adsorption capacity of bPEI and lPEI-based cryogels were compared and found that lPEI-GDE cryogels had higher adsorption capacity than bPEI-GDE cryogels with 0.188 +/- 0.01 mmol CO2/g at 900 mm Hg and 25 degrees C. The reuse studies revealed that NaOH-treated GDE crosslinked bPEI and lPEI microgels and cryogels showed promising potential, for example, after 10-times repeated use >50% CO2 adsorption capacity was retained. The results affirmed that PEI-based microgels and cryogels are encouraging materials for CO2 capture and reuse applications.