Spectroelectrochemical Investigation of Nuclease Active Pt(II) Complexes Containing Pyrrole Oxime

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dc.authoridKayi, Hakan/0000-0001-7300-0325
dc.authoridAltunoz Erdogan, Deniz/0000-0003-1071-4173
dc.authoridOzalp Yaman, Seniz/0000-0002-4166-0529
dc.authorscopusid56059422300
dc.authorscopusid22938517300
dc.authorscopusid56054555600
dc.authorwosidYaman, Şeniz Özalp/AAK-1854-2021
dc.authorwosidErdogan, Deniz Altunoz/B-3268-2016
dc.authorwosidKayi, Hakan/C-7300-2009
dc.contributor.authorKayı, Hakan
dc.contributor.authorKayi, Hakan
dc.contributor.authorÖzalp Yaman, Şeniz
dc.contributor.otherChemical Engineering
dc.date.accessioned2024-07-05T14:31:34Z
dc.date.available2024-07-05T14:31:34Z
dc.date.issued2015
dc.departmentAtılım Universityen_US
dc.department-temp[Erdogan, Deniz Altunoz; Kayi, Hakan; Ozalp-Yaman, Seniz] Atilim Univ, Dept Chem Engn & Appl Chem, TR-06836 Incek Ankara, Turkeyen_US
dc.descriptionKayi, Hakan/0000-0001-7300-0325; Altunoz Erdogan, Deniz/0000-0003-1071-4173; Ozalp Yaman, Seniz/0000-0002-4166-0529en_US
dc.description.abstractIn this paper, the electrochemical oxidation of three Pt(II) complexes containing pyrrole oxime (HL) having a general formula of [Pt(NH3)Cl(L)] (1), [Pt(L)(2)] (2), and K[PtCl2(L)] (3) has been investigated by in-situ spectroelectrochemistry in dimethylformamide (DMF). An irreversible metal-based oxidation process occurs during the anodic scan for each of the three complexes. The electronic absorption spectral changes indicate that all the three complexes generate similar Pt(IV) compounds and free ligand. Our experimental data is supported by quantum chemistry calculations utilizing density functional theory. In addition, the frontier orbital energy distributions indicate that electron densities are localized on mainly platinum atom. (C) 2015 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK); European Cooperation in Science and Technology [COST 109T548]; Atilim University [ATU BAP 2009-03]en_US
dc.description.sponsorshipThe authors gratefully acknowledge the support of this work by the Scientific and Technological Research Council of Turkey (TUBITAK) collaboration with the European Cooperation in Science and Technology (COST 109T548) and Atilim University (ATU BAP 2009-03).en_US
dc.identifier.citation3
dc.identifier.doi10.1016/j.electacta.2015.01.148
dc.identifier.endpage341en_US
dc.identifier.issn0013-4686
dc.identifier.issn1873-3859
dc.identifier.scopus2-s2.0-84922496608
dc.identifier.startpage333en_US
dc.identifier.urihttps://doi.org/10.1016/j.electacta.2015.01.148
dc.identifier.urihttps://hdl.handle.net/20.500.14411/707
dc.identifier.volume158en_US
dc.identifier.wosWOS:000350446000043
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherPergamon-elsevier Science Ltden_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPlatinumen_US
dc.subjectelectrochemistryen_US
dc.subjectUV-Vis spectroelectrochemistryen_US
dc.subjectoximeen_US
dc.subjectDFT calculationsen_US
dc.titleSpectroelectrochemical Investigation of Nuclease Active Pt(II) Complexes Containing Pyrrole Oximeen_US
dc.typeArticleen_US
dspace.entity.typePublication
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relation.isAuthorOfPublicationf3a864db-9deb-4073-bcf2-7569cbfd9610
relation.isAuthorOfPublication.latestForDiscovery69d01b2f-0b8f-4160-a212-2f64b670e7af
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