Spectroelectrochemical Investigation of Nuclease Active Pt(II) Complexes Containing Pyrrole Oxime
| dc.contributor.author | Erdogan, Deniz Altunoz | |
| dc.contributor.author | Kayi, Hakan | |
| dc.contributor.author | Ozalp-Yaman, Seniz | |
| dc.contributor.other | Chemical Engineering | |
| dc.contributor.other | 06. School Of Engineering | |
| dc.contributor.other | 01. Atılım University | |
| dc.date.accessioned | 2024-07-05T14:31:34Z | |
| dc.date.available | 2024-07-05T14:31:34Z | |
| dc.date.issued | 2015 | |
| dc.description | Kayi, Hakan/0000-0001-7300-0325; Altunoz Erdogan, Deniz/0000-0003-1071-4173; Ozalp Yaman, Seniz/0000-0002-4166-0529 | en_US |
| dc.description.abstract | In this paper, the electrochemical oxidation of three Pt(II) complexes containing pyrrole oxime (HL) having a general formula of [Pt(NH3)Cl(L)] (1), [Pt(L)(2)] (2), and K[PtCl2(L)] (3) has been investigated by in-situ spectroelectrochemistry in dimethylformamide (DMF). An irreversible metal-based oxidation process occurs during the anodic scan for each of the three complexes. The electronic absorption spectral changes indicate that all the three complexes generate similar Pt(IV) compounds and free ligand. Our experimental data is supported by quantum chemistry calculations utilizing density functional theory. In addition, the frontier orbital energy distributions indicate that electron densities are localized on mainly platinum atom. (C) 2015 Elsevier Ltd. All rights reserved. | en_US |
| dc.description.sponsorship | Scientific and Technological Research Council of Turkey (TUBITAK); European Cooperation in Science and Technology [COST 109T548]; Atilim University [ATU BAP 2009-03] | en_US |
| dc.description.sponsorship | The authors gratefully acknowledge the support of this work by the Scientific and Technological Research Council of Turkey (TUBITAK) collaboration with the European Cooperation in Science and Technology (COST 109T548) and Atilim University (ATU BAP 2009-03). | en_US |
| dc.identifier.doi | 10.1016/j.electacta.2015.01.148 | |
| dc.identifier.issn | 0013-4686 | |
| dc.identifier.issn | 1873-3859 | |
| dc.identifier.scopus | 2-s2.0-84922496608 | |
| dc.identifier.uri | https://doi.org/10.1016/j.electacta.2015.01.148 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14411/707 | |
| dc.language.iso | en | en_US |
| dc.publisher | Pergamon-elsevier Science Ltd | en_US |
| dc.relation.ispartof | Electrochimica Acta | |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Platinum | en_US |
| dc.subject | electrochemistry | en_US |
| dc.subject | UV-Vis spectroelectrochemistry | en_US |
| dc.subject | oxime | en_US |
| dc.subject | DFT calculations | en_US |
| dc.title | Spectroelectrochemical Investigation of Nuclease Active Pt(II) Complexes Containing Pyrrole Oxime | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| gdc.author.id | Kayi, Hakan/0000-0001-7300-0325 | |
| gdc.author.id | Altunoz Erdogan, Deniz/0000-0003-1071-4173 | |
| gdc.author.id | Ozalp Yaman, Seniz/0000-0002-4166-0529 | |
| gdc.author.institutional | Kayı, Hakan | |
| gdc.author.institutional | Özalp Yaman, Şeniz | |
| gdc.author.scopusid | 56059422300 | |
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| gdc.author.wosid | Yaman, Şeniz Özalp/AAK-1854-2021 | |
| gdc.author.wosid | Erdogan, Deniz Altunoz/B-3268-2016 | |
| gdc.author.wosid | Kayi, Hakan/C-7300-2009 | |
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| gdc.description.department | Atılım University | en_US |
| gdc.description.departmenttemp | [Erdogan, Deniz Altunoz; Kayi, Hakan; Ozalp-Yaman, Seniz] Atilim Univ, Dept Chem Engn & Appl Chem, TR-06836 Incek Ankara, Turkey | en_US |
| gdc.description.endpage | 341 | en_US |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| gdc.description.startpage | 333 | en_US |
| gdc.description.volume | 158 | en_US |
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