Synthesis of Polyacrylamide-Based Redox Active Cryogel Using Click Chemistry and Investigation of Its Electrochemical Properties
dc.authorid | sahin, zeynep munteha (M)/0000-0003-1009-9043 | |
dc.authorscopusid | 57192005820 | |
dc.authorscopusid | 57555717800 | |
dc.authorscopusid | 55925768200 | |
dc.authorscopusid | 57908384000 | |
dc.authorscopusid | 35561603700 | |
dc.authorwosid | sahin, zeynep munteha (M)/GYU-4310-2022 | |
dc.authorwosid | Şahin, Zeynep/KCJ-7170-2024 | |
dc.contributor.author | Cihaner, Atilla | |
dc.contributor.author | Sahin, Zeynep M. | |
dc.contributor.author | Cihaner, Atilla | |
dc.contributor.author | Yilmaz, Faruk | |
dc.contributor.author | Gurek, Aysegul | |
dc.contributor.other | Chemical Engineering | |
dc.date.accessioned | 2024-07-05T15:17:04Z | |
dc.date.available | 2024-07-05T15:17:04Z | |
dc.date.issued | 2021 | |
dc.department | Atılım University | en_US |
dc.department-temp | [Tonta, Magdalena M.; Sahin, Zeynep M.; Gurek, Aysegul] Gebze Tech Univ, Dept Chem, TR-41400 Kocaeli, Turkey; [Cihaner, Atilla] Atilim Univ, Dept Chem Engn & Appl Chem, TR-06836 Ankara, Turkey; [Yilmaz, Faruk] Mutlukent, TR-41400 Kocaeli, Turkey | en_US |
dc.description | sahin, zeynep munteha (M)/0000-0003-1009-9043; | en_US |
dc.description.abstract | Ferrocene (Fc) functionalization of macroporous polyacrylamide-based cryogel (PAAm-Epx) is achieved by click chemistry. For this purpose, firstly, PAAm-Epx cryogel with azide functionality (PAAm-N-3) is prepared by using acryalmide (AAm) as the monomer and allyl glycidyl ether (AGE) as the co-monomer followed by subsequent ring opening reaction of epoxide ring of AGE in acidic medium. Azide groups of PAAm-N-3 is then modified with ethynyl ferrocene, leading to the redox active cryogel (PAAm-Fc) together with preserving the unique characteristic properties of the virgin PAAm-Epx cryogel. Swelling, mechanical and morphological behaviours of PAAm-Epx, PAAm-N-3 and PAAm-Fc are investigated. Detailed characterization of the PAAm-Fc is carried out by several techniques such as FTIR (Fourier Transform Infrared Spectroscopy), Scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX), Inductively Coupled Plasma Optical Emmision Spectrometry (ICP-OES, Cyclic (CV), and Differential Pulse Voltammetry (DPV). Electrochemical analysis confirms the electroactivity and the presence of chemically linked ferrocene unit to the cryogel. | en_US |
dc.description.sponsorship | Scientific and Technical Research Council of Turkey (TUBITAK) [114Z286] | en_US |
dc.description.sponsorship | This work was financially supported by the Scientific and Technical Research Council of Turkey (TUBITAK, Project No. 114Z286). | en_US |
dc.identifier.citation | 2 | |
dc.identifier.doi | 10.1002/slct.202103212 | |
dc.identifier.endpage | 12651 | en_US |
dc.identifier.issn | 2365-6549 | |
dc.identifier.issue | 45 | en_US |
dc.identifier.scopus | 2-s2.0-85120887173 | |
dc.identifier.startpage | 12644 | en_US |
dc.identifier.uri | https://doi.org/10.1002/slct.202103212 | |
dc.identifier.uri | https://hdl.handle.net/20.500.14411/1715 | |
dc.identifier.volume | 6 | en_US |
dc.identifier.wos | WOS:000726827000013 | |
dc.identifier.wosquality | Q3 | |
dc.language.iso | en | en_US |
dc.publisher | Wiley-v C H verlag Gmbh | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Cryogel | en_US |
dc.subject | click chemistry | en_US |
dc.subject | electrochemistry | en_US |
dc.subject | ferrocene | en_US |
dc.subject | porous materials | en_US |
dc.subject | voltammetry | en_US |
dc.title | Synthesis of Polyacrylamide-Based Redox Active Cryogel Using Click Chemistry and Investigation of Its Electrochemical Properties | en_US |
dc.type | Article | en_US |
dspace.entity.type | Publication | |
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