Innovative Carbon Dioxide-Capturing Organic Solvent: Reaction Mechanism and Kinetics
| dc.authorid | Kayi, Hakan/0000-0001-7300-0325 | |
| dc.authorscopusid | 56154378400 | |
| dc.authorscopusid | 57188695736 | |
| dc.authorscopusid | 22938517300 | |
| dc.authorscopusid | 7006827671 | |
| dc.authorwosid | Kayi, Hakan/C-7300-2009 | |
| dc.authorwosid | YÜKSEL, ÖZGE/G-6106-2013 | |
| dc.contributor.author | Orhan, Ozge Yuksel | |
| dc.contributor.author | Tankal, Hilal | |
| dc.contributor.author | Kayi, Hakan | |
| dc.contributor.author | Alper, Erdogan | |
| dc.contributor.other | Chemical Engineering | |
| dc.date.accessioned | 2024-07-05T15:29:18Z | |
| dc.date.available | 2024-07-05T15:29:18Z | |
| dc.date.issued | 2017 | |
| dc.department | Atılım University | en_US |
| dc.department-temp | [Orhan, Ozge Yuksel; Alper, Erdogan] Hacettepe Univ, Dept Chem Engn, TR-06800 Beytepe, Turkey; [Tankal, Hilal] Amasya Univ, Dept Phys, Akbilek Mah Muhsin Yazicioglu Cad 7, TR-05100 Amasya, Turkey; [Kayi, Hakan] Atilim Univ, Computat Chem Lab, Chem Engn & Appl Chem Dept, Kizilcasar Mahallesi, TR-06836 Incek Ankara, Turkey | en_US |
| dc.description | Kayi, Hakan/0000-0001-7300-0325; | en_US |
| dc.description.abstract | The reaction rates of CO2 with an innovative CO2-capturing organic solvent (CO2COS), consisting of blends of 2-tert-butyl-1,1,3,3-tetramethylguanidine (BTMG) and 1-propanol, were obtained as function of BTMG concentration and temperature. A stopped-flow apparatus with conductivity detection was used. The reaction was modeled by means of a modified termolecular reaction mechanism which resulted in a second-order rate constant, and activation energies were calculated for a defined temperature range. Quantum chemical calculations at the B3LYP/6-31G(d) level also produced the activation energy of this reaction system which strongly supports the experimental findings. | en_US |
| dc.description.sponsorship | Turkish Scientific and Technological Research Council (TUBITAK) [213M390] | en_US |
| dc.description.sponsorship | Financial support of his work by the Turkish Scientific and Technological Research Council (TUBITAK) through research project No. 213M390 is gratefully acknowledged. | en_US |
| dc.identifier.citationcount | 7 | |
| dc.identifier.doi | 10.1002/ceat.201600206 | |
| dc.identifier.endpage | 744 | en_US |
| dc.identifier.issn | 0930-7516 | |
| dc.identifier.issn | 1521-4125 | |
| dc.identifier.issue | 4 | en_US |
| dc.identifier.scopus | 2-s2.0-85014327252 | |
| dc.identifier.startpage | 737 | en_US |
| dc.identifier.uri | https://doi.org/10.1002/ceat.201600206 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14411/2907 | |
| dc.identifier.volume | 40 | en_US |
| dc.identifier.wos | WOS:000397575600014 | |
| dc.identifier.wosquality | Q3 | |
| dc.institutionauthor | Kayı, Hakan | |
| dc.language.iso | en | en_US |
| dc.publisher | Wiley-v C H verlag Gmbh | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.scopus.citedbyCount | 9 | |
| dc.subject | CO2-binding organic liquid | en_US |
| dc.subject | Desorberless CO2 capture | en_US |
| dc.subject | Guanidine | en_US |
| dc.subject | Termolecular reaction | en_US |
| dc.title | Innovative Carbon Dioxide-Capturing Organic Solvent: Reaction Mechanism and Kinetics | en_US |
| dc.type | Article | en_US |
| dc.wos.citedbyCount | 7 | |
| dspace.entity.type | Publication | |
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