Innovative Carbon Dioxide-Capturing Organic Solvent: Reaction Mechanism and Kinetics

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dc.authoridKayi, Hakan/0000-0001-7300-0325
dc.authorscopusid56154378400
dc.authorscopusid57188695736
dc.authorscopusid22938517300
dc.authorscopusid7006827671
dc.authorwosidKayi, Hakan/C-7300-2009
dc.authorwosidYÜKSEL, ÖZGE/G-6106-2013
dc.contributor.authorKayı, Hakan
dc.contributor.authorTankal, Hilal
dc.contributor.authorKayi, Hakan
dc.contributor.authorAlper, Erdogan
dc.contributor.otherChemical Engineering
dc.date.accessioned2024-07-05T15:29:18Z
dc.date.available2024-07-05T15:29:18Z
dc.date.issued2017
dc.departmentAtılım Universityen_US
dc.department-temp[Orhan, Ozge Yuksel; Alper, Erdogan] Hacettepe Univ, Dept Chem Engn, TR-06800 Beytepe, Turkey; [Tankal, Hilal] Amasya Univ, Dept Phys, Akbilek Mah Muhsin Yazicioglu Cad 7, TR-05100 Amasya, Turkey; [Kayi, Hakan] Atilim Univ, Computat Chem Lab, Chem Engn & Appl Chem Dept, Kizilcasar Mahallesi, TR-06836 Incek Ankara, Turkeyen_US
dc.descriptionKayi, Hakan/0000-0001-7300-0325;en_US
dc.description.abstractThe reaction rates of CO2 with an innovative CO2-capturing organic solvent (CO2COS), consisting of blends of 2-tert-butyl-1,1,3,3-tetramethylguanidine (BTMG) and 1-propanol, were obtained as function of BTMG concentration and temperature. A stopped-flow apparatus with conductivity detection was used. The reaction was modeled by means of a modified termolecular reaction mechanism which resulted in a second-order rate constant, and activation energies were calculated for a defined temperature range. Quantum chemical calculations at the B3LYP/6-31G(d) level also produced the activation energy of this reaction system which strongly supports the experimental findings.en_US
dc.description.sponsorshipTurkish Scientific and Technological Research Council (TUBITAK) [213M390]en_US
dc.description.sponsorshipFinancial support of his work by the Turkish Scientific and Technological Research Council (TUBITAK) through research project No. 213M390 is gratefully acknowledged.en_US
dc.identifier.citation7
dc.identifier.doi10.1002/ceat.201600206
dc.identifier.endpage744en_US
dc.identifier.issn0930-7516
dc.identifier.issn1521-4125
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-85014327252
dc.identifier.startpage737en_US
dc.identifier.urihttps://doi.org/10.1002/ceat.201600206
dc.identifier.urihttps://hdl.handle.net/20.500.14411/2907
dc.identifier.volume40en_US
dc.identifier.wosWOS:000397575600014
dc.identifier.wosqualityQ3
dc.language.isoenen_US
dc.publisherWiley-v C H verlag Gmbhen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCO2-binding organic liquiden_US
dc.subjectDesorberless CO2 captureen_US
dc.subjectGuanidineen_US
dc.subjectTermolecular reactionen_US
dc.titleInnovative Carbon Dioxide-Capturing Organic Solvent: Reaction Mechanism and Kineticsen_US
dc.typeArticleen_US
dspace.entity.typePublication
relation.isAuthorOfPublication69d01b2f-0b8f-4160-a212-2f64b670e7af
relation.isAuthorOfPublication.latestForDiscovery69d01b2f-0b8f-4160-a212-2f64b670e7af
relation.isOrgUnitOfPublicationbebae599-17cc-4f0b-997b-a4164a19b94b
relation.isOrgUnitOfPublication.latestForDiscoverybebae599-17cc-4f0b-997b-a4164a19b94b

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