GROUP 12 ELEMENTS AND THEIR SMALL CLUSTERS: ELECTRIC DIPOLE POLARIZABILITY OF Zn, Cd AND H<sub>g</sub>, Zn<sub>2</sub> DIMER AND HIGHER Zn<i><sub>n</sub></i> MICROCLUSTERS AND NEUTRAL, CATIONIC AND ANIONIC ZINC OXIDE MOLECULES (ZnO, ZnO<SUP>+</SUP> AND ZnO<SUP>-</SUP>)

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2012

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World Scientific Publ Co Pte Ltd

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Electrical-Electronics Engineering
The Department of Electrical and Electronics Engineering covers communications, signal processing, high voltage, electrical machines, power distribution systems, radar and electronic warfare, RF, electromagnetic and photonics topics. Most of the theoretical courses in our department are supported by qualified laboratory facilities. Our department has been accredited by MÜDEK since 2013. Within the scope of joint training (COOP), in-company training opportunities are offered to our students. 9 different companies train our students for one semester within the scope of joint education and provide them with work experience. The number of students participating in joint education (COOP) is increasing every year. Our students successfully completed the joint education program that started in the 2019-2020 academic year and started work after graduation. Our department, which provides pre-graduation opportunities to its students with Erasmus, joint education (COOP) and undergraduate research projects, has made an agreement with Upper Austria University of Applied Sciences (Austria) starting from this year and offers its students undergraduate (Atılım University) and master's (Upper Austria) degrees with 3+2 education program. Our department, which has the only European Remote Radio Laboratory in Foundation Universities, has a pioneering position in research (publication, project, patent).

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Abstract

This review is in general about group 12 elements and their small microclusters. In this part, after presenting an extensive literature survey of the electric dipole polarizability studies of the Zn, Cd and Hg atoms, we specifically target zinc-containing small clusters, beginning with the Zn-2 dimer, the Zn-3 trimer, higher Zn-n clusters and the neutral, cationic and anionic zinc oxide clusters: ZnO, ZnO+ and ZnO-. We tabulated experimental and theoretical results for the spectroscopic constants (dissociation energy D-e or D-0, bond length r(e), fundamental frequency w(e), anharmonicity constant w(e)x(e) and dipole moment mu(e)) of the diatomic clusters and the first and second ionization potentials IP1 and IP2 and electron affinity EA of the species reviewed.

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Zinc, cadmium, mercury, zinc oxide, clusters, dipole polarizability, spectroscopic constants, ionization potential, electron affinity, Zn-2, Zn-n, ZnO, ZnO+, ZnO-

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7

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26

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8

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https://doi.org/10.1142/S0217979212300034
 https://hdl.handle.net/20.500.14411/1378

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