Electrochromic performance and ion sensitivity of a terthienyl based fluorescent polymer

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Date

2010

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Elsevier

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Chemical Engineering
(2010)
Established in 2010, and aiming to train the students with the capacity to meet the demands of the 21st Century, the Chemical Engineering Department provides a sound chemistry background through intense coursework and laboratory practices, along with fundamental courses such as Physics and Mathematics within the freshman and sophomore years, following preparatory English courses.In the final two years of the program, engineering courses are offered with laboratory practice and state-of-the-art simulation programs, combining theory with practice.
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Industrial Engineering
(1998)
Industrial Engineering is a field of engineering that develops and applies methods and techniques to design, implement, develop and improve systems comprising of humans, materials, machines, energy and funding. Our department was founded in 1998, and since then, has graduated hundreds of individuals who may compete nationally and internationally into professional life. Accredited by MÜDEK in 2014, our student-centered education continues. In addition to acquiring the knowledge necessary for every Industrial engineer, our students are able to gain professional experience in their desired fields of expertise with a wide array of elective courses, such as E-commerce and ERP, Reliability, Tabulation, or Industrial Engineering Applications in the Energy Sector. With dissertation projects fictionalized on solving real problems at real companies, our students gain experience in the sector, and a wide network of contacts. Our education is supported with ERASMUS programs. With the scientific studies of our competent academic staff published in internationally-renowned magazines, our department ranks with the bests among other universities. IESC, one of the most active student networks at our university, continues to organize extensive, and productive events every year.

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Abstract

A novel terthienyl based fluorescent polymer bearing strong electron-withdrawing substituents directly attached to the 3,4-positions of the central thiophene ring was synthesized by electrochemical polymerization of diethyl 2,5-di(3,4-ethylenedioxythiophen-2-yl)thiophene-3,4-dicarboxylate. The corresponding polymer was characterized by cyclic voltammetry, FT-IR and UV-vis spectroscopy. The polymer has a well-defined redox process (E-p,E-1/2 = 0.74 V) and demonstrates a reversible electrochromic behavior; lilac in the neutral state and transparent sky blue in the oxidized state. Also, the polymer had low band gap (E-g = 1.82 eV) and high redox stability (retaining 94.0% of its electro-activity after 500th switch). Moreover, the sensitivity of both the monomer and its polymer towards metal cations was investigated by monitoring the change in the fluorescence intensity. Among various common ions both the monomer and its polymer were found to be selective towards Cu2+ and Cu+ ions by quenching the fluorescence efficiency with a Stern-Volmer constant (K-sv) of (1.4-1.6 x 10(3) M-1) and (1.5-1.8 x 10(2) M-1) for monomer and polymer solutions, respectively. (c) 2010 Elsevier Ltd. All rights reserved.

Description

Onal, ahmet muhtar/0000-0003-0644-7180

Keywords

Electrochemical polymerization, Fluorescent polymer, Electrochromics, Ion sensitivity, Polythiophene

Turkish CoHE Thesis Center URL

Citation

26

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Q1

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Q1

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Volume

70

Issue

4

Start Page

244

End Page

250

URI

https://doi.org/10.1016/j.reactfunctpolym.2009.12.006
 https://hdl.handle.net/20.500.14411/1475

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