Electrochemical Synthesis of New Conducting Copolymers Containing Pseudo-Polyether Cages With Pyrrole

dc.authorscopusid 55925768200
dc.authorwosid Cihaner, Atilla/AAC-9468-2021
dc.contributor.author Cihaner, Atilla
dc.contributor.other Chemical Engineering
dc.date.accessioned 2024-07-05T14:33:12Z
dc.date.available 2024-07-05T14:33:12Z
dc.date.issued 2007
dc.department Atılım University en_US
dc.department-temp Atilim Univ, Chem Grp, TR-06836 Ankara, Turkey en_US
dc.description.abstract Conducting copolymers have been synthesized via electrochemical oxidation of pyrrole (Py) in the presence of monomer 1, 11 -bis(1,1-pyrrole)-3,6,9-trioxaundecane (I) in an electrolytic solution containing 0.1 M tetrabutylammonium hexafluorophosphate (TBAPF(6)) dissolved in acetonitrile. It is observed that reversible redox behavior of poly(I-co-Py)s shifts to more positive potentials with the increasing amount of I in the comonomer mixture, indicating formation of a copolymer. It is also found that increasing the ratio of I in the comonomer mixture decreases the conductivity of the obtained polymer films. The dark electrical conductivity measurements in the temperature range of 300-100 K revealed the extrinsic type of conduction with activation energy values being in the range of 82.3-16.9 meV. (c) 2007 Elsevier B.V. All rights reserved. en_US
dc.identifier.citationcount 12
dc.identifier.doi 10.1016/j.jelechem.2007.03.006
dc.identifier.endpage 14 en_US
dc.identifier.issn 0022-0728
dc.identifier.issue 1 en_US
dc.identifier.scopus 2-s2.0-34249279811
dc.identifier.startpage 8 en_US
dc.identifier.uri https://doi.org/10.1016/j.jelechem.2007.03.006
dc.identifier.uri https://hdl.handle.net/20.500.14411/900
dc.identifier.volume 605 en_US
dc.identifier.wos WOS:000247298200002
dc.institutionauthor Cihaner, Atilla
dc.language.iso en en_US
dc.publisher Elsevier Science Sa en_US
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.scopus.citedbyCount 14
dc.subject electrochemical polymerization en_US
dc.subject spectroelectrochemistry en_US
dc.subject conductivity en_US
dc.subject copolymer containing pseudo-polyether cages en_US
dc.subject polypyrrole en_US
dc.title Electrochemical Synthesis of New Conducting Copolymers Containing Pseudo-Polyether Cages With Pyrrole en_US
dc.type Article en_US
dc.wos.citedbyCount 11
dspace.entity.type Publication
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relation.isAuthorOfPublication.latestForDiscovery e90eb435-04d3-4309-8e68-ee4590ad536c
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relation.isOrgUnitOfPublication.latestForDiscovery bebae599-17cc-4f0b-997b-a4164a19b94b

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