Flame Retarded Plasticized Poly(lactic Acid) Using Phosphorus-Based Additives

dc.authorscopusid12781090400
dc.authorscopusid58411217300
dc.authorscopusid59452529000
dc.authorwosidYesil, Sertan/H-8544-2013
dc.contributor.authorYesil, Sertan
dc.contributor.authorAytac, Ayse
dc.contributor.authorSelim, Fatma
dc.date.accessioned2025-01-05T18:26:03Z
dc.date.available2025-01-05T18:26:03Z
dc.date.issued2024
dc.departmentAtılım Universityen_US
dc.department-temp[Yesil, Sertan] Atilim Univ, Dept Chem Engn, TR-06830 Ankara, Turkiye; [Aytac, Ayse; Selim, Fatma] Kocaeli Univ, Engn Fac, Dept Chem Engn, Kocaeli, Turkiye; [Aytac, Ayse] Kocaeli Univ, Dept Polymer Sci & Technol, Kocaeli, Turkiyeen_US
dc.description.abstractIn this study, the synergistic effect of the flame-retardant additives on the properties of poly(lactic acid) (PLA) was investigated and at the same time, it was tried to increase the toughness of PLA by adding small amounts of phosphate-based additives to plasticized PLA as binary and ternary mixtures. Poly(ethylene glycol) (PEG) was used as a plasticizer. As flame retardant additives, ammonium polyphosphate (APP), tri-phenyl phosphate (TPP), and boron phosphate (BP) were used. Characterization of the composites was carried out by tensile test, impact test, differential scanning calorimetry (DSC), thermal gravimetric analyses (TGA), scanning electron microscopy (SEM), limiting oxygen index (LOI), and UL-94 horizontal burning tests. In addition, TGA-FTIR analyses were carried out to understand the thermal degradation mechanism of composites during combustion. According to the SEM micrographs of the burnt surfaces of the samples, a smooth and flat structure is observed in PLA/PEG/5TPP-5BP sample, while a porous structure and branching formations are observed in other composite samples. Among the composite samples, the best flame retardancy features were observed in the composite containing PLA/PEG/5APP-2.5TPP-2.5BP sample, and the highest impact strength and elongation at break values were obtained in the composite containing PLA/PEG/5APP-5TPP sample.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkiye (TUBITAK) [213M396]en_US
dc.description.sponsorshipThe author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: Sertan Yesil reports financial support was provided by The Scientific and Technological Research Council of Turkiye (TUBITAK) (Project No: 213M396).en_US
dc.description.woscitationindexScience Citation Index Expanded
dc.identifier.citation0
dc.identifier.doi10.1177/08927057241305539
dc.identifier.issn0892-7057
dc.identifier.issn1530-7980
dc.identifier.scopus2-s2.0-85210755191
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1177/08927057241305539
dc.identifier.urihttps://hdl.handle.net/20.500.14411/10375
dc.identifier.wosWOS:001366603900001
dc.identifier.wosqualityQ2
dc.language.isoenen_US
dc.publisherSage Publications Ltden_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPolymer-Matrix Composites (Pmcs)en_US
dc.subjectFlame/Fire Retardancyen_US
dc.subjectMechanical Testingen_US
dc.subjectThermal Analysisen_US
dc.titleFlame Retarded Plasticized Poly(lactic Acid) Using Phosphorus-Based Additivesen_US
dc.typeArticleen_US
dspace.entity.typePublication

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