Synthesis and Electrochemical Polymerization of Dithienosilole-Based Monomers Bearing Different Donor Units
dc.authorid | Cansu-Ergun, Emine/0000-0002-3941-4345 | |
dc.authorid | Onal, ahmet muhtar/0000-0003-0644-7180 | |
dc.authorscopusid | 57519822700 | |
dc.authorscopusid | 55860005200 | |
dc.authorscopusid | 7004825485 | |
dc.authorwosid | Cansu-Ergun, Emine/I-7385-2017 | |
dc.authorwosid | Onal, ahmet muhtar/AAS-5007-2020 | |
dc.contributor.author | Cansu, Emine Gül | |
dc.contributor.author | Ergun, E. G. Cansu | |
dc.contributor.author | Onal, A. M. | |
dc.contributor.other | Chemical Engineering | |
dc.date.accessioned | 2024-07-05T14:30:30Z | |
dc.date.available | 2024-07-05T14:30:30Z | |
dc.date.issued | 2016 | |
dc.department | Atılım University | en_US |
dc.department-temp | [Eken, S.; Onal, A. M.] Middle E Tech Univ, Dept Chem, TR-06800 Ankara, Turkey; [Ergun, E. G. Cansu] Atilim Univ, Chem Engn & Appl Chem, TR-06836 Ankara, Turkey | en_US |
dc.description | Cansu-Ergun, Emine/0000-0002-3941-4345; Onal, ahmet muhtar/0000-0003-0644-7180 | en_US |
dc.description.abstract | Three new donor-acceptor-donor (DAD) type monomers containing five membered heteroaromatic rings as the donor units and the silicon-bridged bithiophene as the acceptor unit were synthesized via Stille cross-coupling reaction. The monomers, 2,6-di(furan-2-yl)-4,4-dioctyl-4H-silolo[3,2-b:4,5-b'] dithiophene (FSiF), 4,4-dioctyl-2,6-di(thiophen-2-yl)-4H-silolo[3,2-b:4,5-b']dithiophene (TSiT) and 4,4-dioctyl-2,6-di(selenophen-2-yl)-4H-silolo[3,2-b:4,5-b'] dithiophene (SeSiSe) were polymerized electrochemically via potential cycling in acetonitrile-tetrabutylammonium perchlorate electrolytic medium. Optical and electrochemical properties of the monomers and their corresponding polymers were investigated and it was found that oxidation potentials of the monomers and optical properties of both monomers and their polymers showed slight variations depending on the heteroatom present in the donor unit. (C) 2016 The Electrochemical Society. | en_US |
dc.description.sponsorship | Middle East Technical University Research Fund; TUBITAK [214Z204] | en_US |
dc.description.sponsorship | The authors express their gratitude to the Middle East Technical University Research Fund and TUBITAK 214Z204 for financial support. | en_US |
dc.identifier.citation | 7 | |
dc.identifier.doi | 10.1149/2.0521606jes | |
dc.identifier.endpage | G74 | en_US |
dc.identifier.issn | 0013-4651 | |
dc.identifier.issn | 1945-7111 | |
dc.identifier.issue | 6 | en_US |
dc.identifier.scopus | 2-s2.0-84963575920 | |
dc.identifier.startpage | G69 | en_US |
dc.identifier.uri | https://doi.org/10.1149/2.0521606jes | |
dc.identifier.uri | https://hdl.handle.net/20.500.14411/550 | |
dc.identifier.volume | 163 | en_US |
dc.identifier.wos | WOS:000373985300023 | |
dc.identifier.wosquality | Q2 | |
dc.language.iso | en | en_US |
dc.publisher | Electrochemical Soc inc | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | [No Keyword Available] | en_US |
dc.title | Synthesis and Electrochemical Polymerization of Dithienosilole-Based Monomers Bearing Different Donor Units | en_US |
dc.type | Article | en_US |
dspace.entity.type | Publication | |
relation.isAuthorOfPublication | 8501dca6-773f-44fc-8c20-7666f6696dd4 | |
relation.isAuthorOfPublication.latestForDiscovery | 8501dca6-773f-44fc-8c20-7666f6696dd4 | |
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