Synthesis and Electropolymerization of a Selenophene Based Chemiluminescent Monomer and Its Use in Blood Detection

dc.authorid Cakal, Deniz/0000-0003-1656-2430
dc.authorscopusid 57204794975
dc.authorscopusid 57200397516
dc.authorscopusid 55925768200
dc.authorwosid Cihaner, Atilla/AAC-9468-2021
dc.contributor.author Balci, Burcu
dc.contributor.author Cakal, Deniz
dc.contributor.author Cihaner, Atilla
dc.contributor.other Chemical Engineering
dc.date.accessioned 2024-10-06T11:17:08Z
dc.date.available 2024-10-06T11:17:08Z
dc.date.issued 2025
dc.department Atılım University en_US
dc.department-temp [Balci, Burcu; Cihaner, Atilla] Atilim Univ, Dept Chem Engn, Atilim Optoelect Mat & Solar Energy Lab ATOMSEL, TR-06830 Ankara, Turkiye; [Balci, Burcu] Atilim Univ, Grad Sch Nat & Appl Sci, TR-06830 Ankara, Turkiye; [Cakal, Deniz] Middle East Tech Univ, Dept Chem, TR-06800 Ankara, Turkiye en_US
dc.description Cakal, Deniz/0000-0003-1656-2430 en_US
dc.description.abstract A new selenophene based trimeric chemiluminescent compound, namely 5,7-di(selenophen-2-yl)-2,3-dihydrothieno[3,4-d]pyridazine-1,4-dione (S2T-Lum), was synthesized in two steps via electron donor-acceptor-donor approach. Its chemiluminescent reaction with hydrogen peroxide was investigated in an alkaline solution in the presence of various catalysts such as different metal ions, hemin and blood samples and the results were compared with its thiophene analogue (T2T-Lum) and luminol. It was found that S2T-Lum was very sensitive to copper(II) and iron(III) ions, and blood samples. Also, it can be easily concluded that S2T-Lum as a new member of luminol type compounds is a potential candidate for the detection of blood findings in forensic science. Furthermore, S2T-Lum has an irreversible oxidation peak at 1.28 V vs Ag/AgCl, which is responsible from its electropolymerization. S2T-Lum was successfully polymerized electrochemically via potentiodynamic electrolysis without cleavage of its chemiluminescent active appendage. To the best of our knowledge, its corresponding polymer PS2T-Lum film is the first member of selenophene based luminol type electroactive polymers. en_US
dc.description.sponsorship Scientific and Technological Research Council of Turkey (TUBITAK) [118Z067] en_US
dc.description.sponsorship We would like to thank the Scientific and Technological Research Council of Turkey (TUBITAK, Grand number: 118Z067) for its financial support. en_US
dc.description.woscitationindex Science Citation Index Expanded
dc.identifier.citationcount 0
dc.identifier.doi 10.1016/j.dyepig.2024.112471
dc.identifier.issn 0143-7208
dc.identifier.issn 1873-3743
dc.identifier.scopus 2-s2.0-85204911506
dc.identifier.scopusquality Q2
dc.identifier.uri https://doi.org/10.1016/j.dyepig.2024.112471
dc.identifier.volume 232 en_US
dc.identifier.wos WOS:001327836200001
dc.identifier.wosquality Q1
dc.institutionauthor Cihaner, Atilla
dc.institutionauthor Cihaner, Atilla
dc.language.iso en en_US
dc.publisher Elsevier Sci Ltd en_US
dc.relation.ispartof Dyes and Pigments en_US
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.scopus.citedbyCount 0
dc.subject Chemiluminescence en_US
dc.subject Electropolymerization en_US
dc.subject Selenophene en_US
dc.subject Blood detection en_US
dc.title Synthesis and Electropolymerization of a Selenophene Based Chemiluminescent Monomer and Its Use in Blood Detection en_US
dc.type Article en_US
dc.wos.citedbyCount 0
dspace.entity.type Publication
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